Adsorption regeneration-photocatalysis advanced oxidation water treatment equipment

A treatment equipment and water oxidation technology, applied in water/sewage multi-stage treatment, water/sludge/sewage treatment, chemical instruments and methods, etc., can solve the problem of smaller specific surface area of ​​catalysts, lower pollutant degradation efficiency, and lower operating costs Improvement and other issues, to achieve the effect of good catalytic reaction, large effective specific surface area, and thorough regeneration

Inactive Publication Date: 2012-12-05
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In practical applications, in order to facilitate the separation and recovery of the catalyst and prevent its loss, the catalyst is generally made into particles, fibers, sheets or fixed on the carrier, so the specific surface area of ​​the catalyst becomes smaller and the degradation efficiency of pollutants decreases. Some advantages of photocatalytic oxidation are lost
However, in order to maximize the specific surface area of ​​the catalyst, the use of powdered catalysts will bring difficulties in separation and recovery, resulting in increased operating costs

Method used

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  • Adsorption regeneration-photocatalysis advanced oxidation water treatment equipment
  • Adsorption regeneration-photocatalysis advanced oxidation water treatment equipment
  • Adsorption regeneration-photocatalysis advanced oxidation water treatment equipment

Examples

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Effect test

Embodiment 1

[0032] Embodiment 1: the working principle of the present invention is as figure 2 shown. The aeration tube 3, the ultraviolet light source 4 and the membrane module 5 are installed in the air-lift internal circulation reactor 8 to constitute the main part of the equipment of the present invention. The middle of the air-lift internal circulation reactor 8 is an upward circulation flow channel, and both sides are downward circulation flow channels, and the bottom of the downward circulation flow channel is connected to the front of the pipeline static mixer 1 through a pipeline. The membrane module 5 is connected to the water outlet pipe through a hose, and then the water is pumped out by the water outlet pump 7, and the vacuum gauge 6 is connected in series on the water outlet pipe. The powder photocatalyst 9 is suspended in the air-lift internal circulation reactor 8 . The spiral turbulence sheet 10 is placed in the water inlet pipe to form the pipeline static mixer 1 . T...

Embodiment 2

[0040] The invention is applied to the treatment of certain coking wastewater. The residence time of the reactor is 20h, the membrane module is made of polyvinylidene fluoride (PVDF), in the form of a flat membrane, and the operating flux of the membrane is 5~7 L / m 2 h, powder photocatalyst adopts Fe 2 o 3 , the dosage is 5g / L, and ozone aeration is supplemented. The influent COD concentration is 3031±571.2 mg / L, the effluent COD concentration is 303±47.2 mg / L, and the removal rate reaches 90%.

Embodiment 3

[0042] The invention is applied to the treatment of certain dye wastewater. The residence time of the reactor is 15h, the membrane module is made of polyvinylidene fluoride (PVDF), in the form of a flat membrane, and the operating flux of the membrane is 8~10 L / m 2 ·h, the powder photocatalyst uses ZnO, the dosage is 3g / L, supplemented with ozone aeration. The influent COD concentration is 1241±63.5 mg / L, the chromaticity is 230 degrees, the effluent COD concentration is 93±17.3 mg / L, the chromaticity is <20 degrees, and the removal rate reaches over 90%.

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PUM

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Abstract

The invention relates to adsorption regeneration-photocatalysis advanced oxidation water treatment equipment, which consists of a pipeline static mixer, a water distributor, an aeration pipe, an ultraviolet light source, a membrane component, a vacuum meter, a water outlet pump, an air lift internal circulation reactor and a powder photocatalyst, wherein the aeration pipe, the ultraviolet light source and the membrane component are positioned in the air lift internal circulation reactor; the middle of the air lift internal circulation reactor is provided with an upward circulating flow channel; both sides of the air lift internal circulation reactor are provided with downward circulating pipelines; the bottom of the upward circulating flow channel is connected with the water distributor; the water distributor is connected with the pipeline static mixer; the membrane component is connected with the water outlet pipe through a hose to form a water outlet pipeline; the water outlet pipe is connected with the water outlet pump; water is sucked by the water outlet pump; the vacuum meter is connected in series to the water outlet pipeline; the bottom of each downward circulating pipeline is connected with a return pipe; the return pipe is connected to the front part of the pipeline static mixer; and the powder photocatalyst is suspended in the air lift internal circulation reactor. The water treatment equipment has the advantages of compact structure, mild reaction condition, high reaction efficiency, easiness of maintenance, high drained water quality and strong economic competition, and is suitable for treating various kinds of non-degradable organic matter waste water and hospital sewage and removing non-degradable organic matters remaining in water drained from sewage plants.

Description

technical field [0001] The invention relates to an adsorption regeneration-photocatalytic advanced oxidation water treatment equipment. Background technique [0002] At present, commonly used sewage treatment technologies include activated sludge method, biofilm method, coagulation sedimentation method and other biochemical and physical and chemical treatment methods. However, for substances with poor biodegradability and a relative molecular mass ranging from several thousand to tens of thousands, such as aromatic substances in coking wastewater, antibiotic substances in hospital sewage, dye wastewater, pesticide wastewater, etc., conventional treatment processes are difficult. A large amount of refractory toxic and harmful organic substances remain in the effluent, which will still cause long-term adverse effects on the environment. [0003] The advanced oxidation method uses hydroxyl radicals as the main oxidant to react with organic matter until it is oxidized and decom...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/08
Inventor 宋晨怡朱宇峰尹大强
Owner TONGJI UNIV
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