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Hydrocarbon catalytic conversion method for producing propylene and light aromatic hydrocarbon

A catalytic conversion method and technology for light aromatic hydrocarbons, which are applied in the fields of hydrocarbon cracking to produce hydrocarbons, production of bulk chemicals, preparation of liquid hydrocarbon mixtures, etc., can solve the problem that the increase of catalytically cracked propylene is limited and does not involve improving the yield of catalytically cracked light aromatics. and other problems, to achieve the effect of improving the conversion rate of heavy oil, the yield of light products, the high content of light aromatics, the yield of propylene and the yield of BTX

Active Publication Date: 2011-10-05
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] Although the above technologies have made significant progress in increasing the yield of catalytic cracking propylene, their limitations in increasing the selectivity and yield of catalytic cracking propylene are still relatively large, and they do not involve increasing the yield of catalytic cracking light aromatics

Method used

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  • Hydrocarbon catalytic conversion method for producing propylene and light aromatic hydrocarbon
  • Hydrocarbon catalytic conversion method for producing propylene and light aromatic hydrocarbon
  • Hydrocarbon catalytic conversion method for producing propylene and light aromatic hydrocarbon

Examples

Experimental program
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Effect test

Embodiment 1

[0064] The heavy oil raw material (the first raw material, whose properties are shown in Table 1) is introduced into the riser reactor 1, and after contacting and reacting with the hot catalyst from the regenerator, the oil and gas products are separated from the catalyst, and the oil and gas products leave the reactor and are introduced into the fractionation device, separated The coke catalyst that obtains introduces stripper 5, is transported to regenerator after stripping and regenerates; Catalytic cracking C4 hydrocarbon and light gasoline fraction (the second raw material, its composition is shown in Table 2, and this light gasoline distillation range is 35 ℃~ 85°C) into the riser reactor 2, contact with the hot catalyst from the regenerator for reaction, the reacted oil-gas mixture and catalyst are introduced into the fluidized bed reactor 3 to continue the reaction, and the oil and gas products obtained by the reaction of the fluidized bed reactor 3 are introduced into t...

Embodiment 2

[0066] The process flow of this embodiment is the same as that of Example 1, and the difference from Example 1 is that light gasoline (properties are shown in Table 2) is 4: 1 under the reaction temperature of 40 ° C, reaction pressure 0.5 MPa, hydrogen and olefin molar ratio, in the catalyst (The trade name is RDD-1, produced by Sinopec Changling Catalyst Branch Company) on the upper surface through selective hydrogenation reaction, convert diolefins and alkynes into olefins and then introduce them into riser reactor 2. The amount of heavy oil introduced into riser 1 is the same as that of The light gasoline weight ratio of the riser 2 is 100:20. The reaction conditions and reaction results are shown in Table 3.

Embodiment 3

[0068] The heavy oil raw material (its properties are shown in Table 1) is introduced into the riser reactor 1, and after contacting with the hot catalyst from the regenerator, the oil and gas products are separated from the catalyst, and the oil and gas products leave the reactor and are introduced into the fractionation device to separate the obtained carbon deposits Catalyst is introduced into stripper 5, is transported to regenerator after steam stripping and regenerates; The catalytic cracking C4 cut that fractionation device fractionation of the present invention obtains and light gasoline cut (light gasoline distillation range is 35 ℃~85 ℃, and C4 cut accounts for 50% by weight %, the light gasoline fraction accounts for 50% by weight) on the RDD-1 catalyst at a reaction temperature of 40°C, a reaction pressure of 0.5MPa, and a hydrogen-to-gasoline molar ratio of 4:1 for selective hydrogenation and then introduced into the riser reactor 2. Contact and react with the hot ...

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Abstract

A method for producing propylene and light aromatic hydrocarbon comprises the steps of contacting heavy hydrocarbons and / or grease with a cracking catalyst containing modified beta zeolite in a first reactor for catalytic cracking reaction, contacting C4 hydrocarbon fraction and / or light gasoline fraction with the cracking catalyst containing modified beta zeolite in a second reactor for catalytic cracking reaction, and then leading the reaction products into a third reactor for reaction. The hydrocarbon-gasoline conversion method provided by the invention has the advantages of higher propylene yield and light aromatic hydrocarbon yield.

Description

technical field [0001] The present invention relates to a method for producing propylene and light aromatics Background technique [0002] Light olefins and light aromatics (benzene, toluene and xylene, referred to as BTX) are basic chemical raw materials. At present, BTX mainly comes from light hydrocarbon reforming process and steam thermal cracking process, and light olefins mainly come from natural gas, light Steam thermal cracking of petroleum hydrocarbons and catalytic cracking of hydrocarbon oils. However, due to the increasingly heavy crude oil and the shortage of light hydrocarbon raw materials, the technical route of producing light olefins and light aromatics from heavy oil has gradually been paid attention to. [0003] US5670037 discloses a method for catalytic conversion of hydrocarbons to prepare low-carbon olefins. The raw materials are petroleum fractions, residues or crude oil with different boiling ranges, and a solid acid catalyst is used in a fluidized b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G55/08C10G3/00C07C11/06C07C4/06
CPCY02P20/52Y02P30/20
Inventor 谢朝钢朱根权鲁维民张执刚陈昀
Owner CHINA PETROLEUM & CHEM CORP
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