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Concrete admixture and preparation method thereof

A concrete admixture and monomer technology, which is applied in sustainable waste treatment, solid waste management, climate sustainability, etc., can solve the problems of high cost and mass use, unsatisfactory performance, and inability to meet the technical requirements of filling mining production. , to achieve the effect of low cost, short production cycle and good environmental effect

Inactive Publication Date: 2011-10-12
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, due to the limitation of materials, the new concrete produced by using production waste often cannot meet the technical requirements of filling method mining production, so the research and development of new concrete and the addition of concrete modification have become an important bottleneck restricting the application of this technology
Because the existing admixtures are only for ordinary building concrete, the performance cannot meet the requirements of this kind of concrete for installation, or because the cost is too high, it is not suitable for large-scale use in mine production. This patent develops a special admixture for this demand. It is of great significance to improve the properties of waste rock concrete used for filling in mine production and to optimize the industrial production process.

Method used

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  • Concrete admixture and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A preparation method of concrete admixture, the method comprises the following steps:

[0040] (1) Prepare materials according to the following components and contents: methacrylic acid 3kg, polyethylene glycol monoether acrylate monomer 25kg, allyl sodium sulfonate 1kg, polyether acrylate monomer 0.5kg, ferrous sulfate 5kg , industrial salt 4kg, fly ash 5kg, 325 mesh calcium carbonate powder 8kg;

[0041] (2) Place methacrylic acid, polyethylene glycol monoether acrylate monomer, sodium allyl sulfonate and polyether acrylate monomer in a reactor for copolymerization reaction, control the reaction temperature to 55°C, and react The time is 3h, obtain copolymer, store separately;

[0042] (3) Control the reaction temperature to 30°C, mix and stir ferrous sulfate and industrial salt for 1 min, then add fly ash and calcium carbonate powder therein, continue stirring for 5 min to obtain the mixture, and store it separately;

[0043] (4) Mix the copolymer and the mixture a...

Embodiment 2

[0053] A preparation method of concrete admixture, the method comprises the following steps:

[0054] (1) Prepare materials according to the following components and contents: methacrylic acid 6kg, polyethylene glycol monoether acrylate monomer 12kg, allyl sodium sulfonate 2kg, polyether acrylate monomer 1kg, ferrous sulfate 25kg, Industrial salt 20kg, fly ash 1kg, 425 mesh calcium carbonate powder 15kg;

[0055] (2) Place methacrylic acid, polyethylene glycol monoether acrylate monomer, sodium allyl sulfonate and polyether acrylate monomer in a reactor for copolymerization reaction, control the reaction temperature to 90°C, and react The time is 0.5h to obtain the copolymer, which is stored separately;

[0056] (3) Control the reaction temperature to 15°C, mix and stir ferrous sulfate and industrial salt for 2 minutes, then add fly ash and calcium carbonate powder therein, continue stirring for 8 minutes to obtain the mixture, and store it separately;

[0057](4) Mix the co...

Embodiment 3

[0067] A preparation method of concrete admixture, the method comprises the following steps:

[0068] (1) Prepare materials according to the following components and contents: methacrylic acid 5kg, polyethylene glycol monoether acrylate monomer 20kg, allyl sodium sulfonate 2kg, polyether acrylate monomer 1kg, ferrous sulfate 20kg, Industrial salt 10kg, fly ash 3kg, 400 mesh calcium carbonate powder 10kg;

[0069] (2) Place methacrylic acid, polyethylene glycol monoether acrylate monomer, sodium allyl sulfonate and polyether acrylate monomer in a reactor for copolymerization reaction, control the reaction temperature to 80°C, and react Time is 2h, obtains copolymer;

[0070] (3) Control the reaction temperature to be 20° C., mix and stir ferrous sulfate and industrial salt for 2 minutes, then add fly ash and calcium carbonate powder therein, and continue stirring for 6 minutes to obtain a mixture;

[0071] (4) Mix the copolymer and the mixture at room temperature for 6 minute...

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Abstract

The invention relates to a concrete admixture and a preparation method thereof. The admixture comprises the following components in part by weight: 3 to 6 parts of methacrylic acid, 12 to 25 parts of polyethylene glycol mono-ether acrylate monomer, 1 to 2 parts of allyl sodium sulfonate, 0.5 to 1 part of polyether acrylate monomer, 5 to 25 parts of ferrous sulfate, 4 to 20 parts of industrial salt, 1 to 5 parts of fly ash and 8 to 15 parts of calcium carbonate powder. The calcium carbonate comprises the following steps of: preparing materials, performing copolymerization reaction on the methacrylic acid, the polyethylene glycol mono-ether acrylate monomer, the allyl sodium sulfonate and the polyether acrylate monomer to obtain a copolymer, stirring and mixing the ferrous sulfate, the industrial salt, the fly ash and the calcium carbonate powder, and mixing the mixture and the copolymer to obtain the concrete admixture. Compared with the prior art, the invention has the advantages that: on the premise that the liquidity of the slurry is not changed, the filling water quantity is reduced by 15 to 25 percent, and the early strength of concrete is increased by 15 to 40 percent; and the preparation method is simple, short in production period, low in cost and suitable for large scale production.

Description

technical field [0001] The invention relates to a special concrete admixture preparation technology, in particular to a concrete admixture and a preparation method thereof. Background technique [0002] With the development of non-ferrous metal mineral resources, the filling method is an important mining technology. The raw materials of filling concrete used in traditional filling mining technology are mainly natural primary raw materials (such as cement, gravel, river sand and clean water). Since the sustainable development strategy was established in the 1990s, developed industrialized countries have successively regarded circular economy as an important way to achieve sustainable development. The waste generated by mine production itself, such as mining waste rock, mining wastewater, beneficiation tailings, and slag and fly ash produced by smelting and power generation, can be used as filling concrete materials for resource utilization, which can not only reduce producti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/32B09B3/00C04B103/30
CPCC04B40/0039Y02W30/91C04B14/28C04B18/08C04B22/149C04B24/2647C04B28/02
Inventor 马利民孟得磊曾建峰
Owner TONGJI UNIV
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