Preparation method of polyethylene glycol monomethyl ether-dl-polylactic acid block copolymer
A technology of polyethylene glycol monomethyl ether and block copolymer, which is applied in the field of preparation of polyethylene glycol monomethyl ether-dl-polylactic acid block copolymer, can solve problems such as reaction temperature limitation, and achieves simple operation. Convenience, production conditions are not harsh, and the effect of dispersion is soft
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Embodiment 1
[0018] 1. Add one of cumene, xylene, anisole, dimethylformamide and dimethyl sulfoxide to a dry reactor according to Table 1. For example, add anisole three to five times the total amount of raw materials input in advance, then add the catalyst stannous octoate, and polyethylene glycol monomethyl ether 2000 and dl-lactide in a certain proportion according to Table 1. Stir to dissolve evenly. Nitrogen gas was passed through, and the air was removed. Then heat to react. The heating temperature is limited between 110°C and 180°C depending on the solvent used. The reaction time is then set between 4 hours and 12 hours. Then the reaction stops.
[0019] 2. Slowly pour the viscous reactants into the pasty mixture of petroleum ether-carbon dioxide dry ice while vigorously stirring. Place and filter to obtain a white solid. Dry in a vacuum oven at 40°C for 24 hours. A white solid of polyethylene glycol monomethyl ether-dl-polylactic acid block copolymer was obtained.
[0020] ...
Embodiment 2
[0037] 1. Add one of cumene, xylene, anisole, dimethylformamide and dimethyl sulfoxide to the dry reactor respectively according to Table 1, such as the amount according to the preset ratio 3 to 5 times the cumene, add polyethylene glycol monomethyl ether 2000 and dl-lactide in a certain proportion according to Table 1 in sequence. Stir to dissolve evenly. After raising the temperature to 120°C, a catalytic amount of stannous octoate was added, and nitrogen gas was introduced to remove the air. Then heat to react. The heating temperature is limited between 120°C and 180°C depending on the solvent used. The reaction time is then set between 4 hours and 12 hours. Then the reaction stops.
[0038] 2. Distill under reduced pressure to remove the solvent under reduced pressure as much as possible. Add 2 to 8 times the amount of polyethylene glycol monomethyl ether-dl-polylactic acid block copolymer as a good solvent such as dichloromethane or methanol, and stir to help it diss...
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