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High temperature corrosion resistant ceramic coating for protecting float glass tin bath pendant and preparation method

A technology of high temperature corrosion resistance and float glass, which is applied in the field of making float glass tin bath pendants have high temperature corrosion resistance, can solve the problems of deterioration of the performance of the pendant base material, increase of the cost of float glass, loss of protective film effect, etc. Inhibition of intrusion of corrosive atmosphere, low cost, and high compactness

Active Publication Date: 2011-11-30
武汉长利新材料科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] Reaction (3) proceeds to the right, resulting in the oxidation protective layer Cr of the superalloy of the pendant substrate 2 o 3 are easily corroded
Loss of protective film effect, such as figure 1 As shown, the harmful gas directly corrodes the base of the hanger more rapidly, which leads to the deterioration of the material performance of the base of the hanger, the life is greatly reduced, and the cost in the production of float glass is increased.
[0013] There is no related technology to solve the above problems

Method used

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  • High temperature corrosion resistant ceramic coating for protecting float glass tin bath pendant and preparation method
  • High temperature corrosion resistant ceramic coating for protecting float glass tin bath pendant and preparation method
  • High temperature corrosion resistant ceramic coating for protecting float glass tin bath pendant and preparation method

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Effect test

Embodiment 1

[0034] Raw material mass ratio: SiO 2 : 46%, FeO: 12%, TiO 2 : 18%, Cr 2 o 3 : 18%, NiO: 2%, CoO: 3%; alkali metal gold compound 1%.

[0035] Among them, the alkali metal gold compound is composed of Na 2 O:K 2 O: CaO: MgO is mixed in a mass ratio of 1:1:1:1;

[0036] Elemental metal powder silicon powder, titanium powder, chromium powder, nickel powder in a mass ratio of 5:1.2:1.4:0.1;

Embodiment 2

[0038] Raw material mass ratio: SiO 2 : 48%, FeO: 10%, TiO 2 : 20%, Cr 2 o 3 : 14%, NiO: 3%, CoO: 3%; alkali metal gold compound 2%.

[0039] Among them, the alkali metal gold compound is composed of Na 2 O:K 2 O: CaO: MgO is mixed in a mass ratio of 1: 1: 1.5: 1.5;

[0040] Elemental metal powder silicon powder, titanium powder, chromium powder, nickel powder in a mass ratio of 5:1.4:1.5:0.2;

Embodiment 3

[0042] Raw material mass ratio: SiO2 : 53.0%, FeO: 10.0%, TiO 2 : 14%, Cr 2 o 3 : 16.0%, NiO: 2.4%, CoO: 3.2%; alkali metal gold compound 1.4%.

[0043] Among them, the alkali metal gold compound is composed of Na 2 O:K 2 O: CaO: MgO is mixed in a mass ratio of 1: 1: 1.5: 1.5;

[0044] Elemental metal powder silicon powder, titanium powder, chromium powder, nickel powder in a mass ratio of 5:1.4:1.6:0.2;

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Abstract

The invention discloses a ceramic coating capable of resisting high-temperature corrosion for protecting a hanging part in a tin bath of float glass and a preparation method thereof. The preparation method comprises: dispersing SiO2, FeO, TiO2, Cr2O3, NiO, CoO and alkali metal compounds in water to obtain slurry with a solid content of 50-70%, grinding the slurry with a ball milling method to obtain an abrasive, then applying the abrasive on the cleaned surface of the hanging part and then sintering the surface of the hanging part and the coating. The resulting high-temperature ceramic coating has high-temperature anti-oxidation capacity and can also effectively improve the corrosion resistance of the surface of a Ni-Cr high-temperature alloy; and in addition, the ceramic coating can act as a heat barrier coating, forms effective protection on the hanging part in the tin bath of the float glass, and has important practical significance in prolonging the service life of the hanging part in the tin bath of the float glass.

Description

technical field [0001] The invention belongs to the float glass tin bath hanger protection technology, and in particular relates to a technology for making the float glass tin bath hanger have high temperature corrosion resistance. Background technique [0002] In the production process of float glass, the float medium is extremely oxidized under the high temperature of the tin bath, which increases the loss of tin and causes various defects on the glass surface; therefore, it is necessary to pass protective gas nitrogen into the tin bath, and add 5-10% hydrogen, make the tin bath form a reducing atmosphere, and make the tin oxide re-reduce to tin. The supply of hydrogen often uses water electrolysis to produce high-purity hydrogen for use in tin baths. Hydrogen production by electrolysis of water has complex operation techniques; however, it has the advantages of less impurities, high purity, and no pollution. [0003] In order to solve this problem, a way of ammonia deco...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66C03B18/00
Inventor 易乔木黄齐文王桂荣胡树兵程乐志靳明照严晓莉
Owner 武汉长利新材料科技有限公司
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