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Preparation method of composite conductive fabric with spray polymerization

A technology of composite conduction and spray polymerization, which is applied in the field of textiles, can solve the problems that the polypyrrole layer of the composite conductive fabric is not uniform and dense, the wear resistance and solvent resistance need to be improved, and it is unfavorable for large-scale industrial production, and the probability of achieving the reaction is high. , Stable conductivity, good conductivity effect

Inactive Publication Date: 2012-01-11
WUHAN TEXTILE UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the pyrrole layer prepared by gas-phase polymerization of polypyrrole is uniform and dense, the experimental operation is cumbersome and the reaction time is long, which is not conducive to large-scale industrial production.
Ordinary liquid-phase chemical polymerization method, first of all, soak the fabric in a certain concentration of dopant solution for 1 to 2 hours, take it out after fully soaking, put it in a certain concentration of oxidant solution for about 2 hours, and take out the fabric Let it dry at room temperature, but the polypyrrole layer of the composite conductive fabric prepared is not uniform and compact, and the abrasion resistance and solvent resistance need to be improved

Method used

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  • Preparation method of composite conductive fabric with spray polymerization
  • Preparation method of composite conductive fabric with spray polymerization

Examples

Experimental program
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Effect test

Embodiment 1

[0030]According to the above-mentioned preparation method, under room temperature, prepare an oxidation initiation system solution composed of ferric chloride and deionized water, wherein the concentration of ferric chloride is 0.2mol / L, and the bath ratio of cotton fabric is 1:40 Put it into the prepared oxidation initiating system solution, soak the fabric for 1 hour, take it out and dry it in the air, and soak it repeatedly for 30 minutes. Mix sodium dodecylbenzenesulfonate and deionized water into a beaker, stir well to form a monomer solution, wherein the concentration of pyrrole monomer is 0.1mol / L, and the concentration of sodium dodecylbenzenesulfonate is 0.60mol / L, put the prepared monomer solution into the reaction vessel A with a nebulizer, the upper port of the reaction vessel A is connected to the reaction vessel B and the nitrogen bottle through the pipeline, open the nitrogen bottle, and input into the reaction vessel A Nitrogen at a pressure of 0.5 MPa, adjust...

Embodiment 2

[0032] According to the above-mentioned preparation method, under room temperature, prepare an oxidation initiation system solution composed of ferric chloride and deionized water, wherein the concentration of ferric chloride is 0.5mol / L, and the bath ratio of silk fabric is 1:10 Put it into the prepared oxidation initiating system solution, soak the fabric for 1 hour, take it out to dry, and take it out after repeated soaking for 30 minutes. Mix body, sodium alkylnaphthalene sulfonate and deionized water into a beaker, stir well to form a monomer solution, wherein the concentration of pyrrole monomer is 0.5mol / L, and the concentration of sodium alkylnaphthalenesulfonate is 0.05mol / L , the prepared monomer solution is poured into the reaction vessel A with the atomizer, the upper port of the reaction vessel A is connected to the reaction vessel B and the nitrogen cylinder through the pipeline, the nitrogen cylinder is opened, and the input pressure in the reaction vessel A is ...

Embodiment 3

[0034] According to the above-mentioned preparation method, under room temperature conditions, prepare an oxidation initiation system solution composed of ferric chloride and deionized water, wherein the concentration of ferric chloride is 1.2mol / L, and the bath ratio of wool fabric is 1:20 Put it into the prepared oxidation initiating system solution, soak the fabric for 1 hour, take it out and dry it in the air, and soak it repeatedly for 30 minutes. Mix toluenesulfonic acid and deionized water into a beaker, stir fully to form a monomer solution, wherein the concentration of pyrrole monomer is 1.0mol / L, and the concentration of toluenesulfonic acid is 0.3mol / L. The prepared monomer solution, Pour it into the reaction vessel A with the nebulizer, the port of the reaction vessel A is connected to the reaction vessel B and the nitrogen bottle through the pipeline, open the nitrogen bottle, input the nitrogen gas with a pressure of 2.5MPa into the reaction vessel A, adjust the n...

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Abstract

The invention which relates to a preparation method of a composite conductive fabric with spray polymerization belongs to the technical field of textiles. An atomization mode is adopted in the invention to atomize a monomer solution into particles, and an in situ polymerization reaction is initiated on a monomer under the effect of an oxidant deposited in the fabric to prepare the composite conductive fabric. The preparation method of the invention which has the advantages of easy controlled condition, simple operation, low raw material cost, and less energy consumption is suitable for the large scale and industrial production. Compared with routine products prepared with a liquid-phase oxidation method, the adhesion between a conducting layer and a fabric matrix of the composite conductive fabric prepared in the invention is substantially improved, the conducting layer is more compacted, and protrude wear resistances and solvent resistances are possessed; the surface resistor of the preparative composite conductive fabric is 10-10<5>omega / cm<2>, the conductivity is good, the electromagnetic shielding property and the flexibility of a product (the composite conductive fabric) are good, and the surface resistor of the product in the invention is sensitive to the change of pressure, elasticity and the like, so the product can be widely applied to the sensor field, the antistaticfield, the anti-electromagnetic shielding field and the like.

Description

technical field [0001] The invention relates to a method for preparing composite conductive fabrics by spray polymerization, which belongs to the technical field of textiles. technical background [0002] In the 1970s, American scientist Hideki Shirakawa, American scientists Higel and McDiarmid discovered that polymer polyacetylene (PAC) has a conductive function. Before that, organic polymers were always regarded as insulating materials. For this reason, the three After winning the Nobel Prize, conductive polymers became a hot topic of research. In subsequent studies, it was found that the conductivity of polypyrrole, polyaniline and other conjugated polymers can reach the level of semiconductor or even metal conductor after doping. By controlling the reaction conditions, such as selecting appropriate solvents and oxidants, polypyrrole can be prepared by chemical oxidation. Its conductivity is as high as 220 s / cm, and it has good thermal, chemical oxidation, and light stab...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D06M11/28D06M15/37D06M13/256D06M23/00D06M101/06D06M101/12D06M101/32D06M101/34D06M101/28D06M101/24D06M101/20D06M101/38D06M101/22
Inventor 许杰王磊梁桂杰柏自奎谢伟徐卫林
Owner WUHAN TEXTILE UNIV
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