Auto-rust converting rust-containing corrosion resistant emulsion and preparation method thereof

A rust-proof, self-rotating rust technology, applied in the field of materials, can solve the problems of poor anti-rust and anti-re-rust ability, a large number of manual removal, endangering human health, etc. Good anti-rust effect and effect of reducing water absorption

Active Publication Date: 2012-04-11
佛山保立佳化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, most of the rusty paints used in China are solvent-based paints. Ordinary solvent-based rusty paints contain a large amount of organic solvents, which are toxic, harmful, not environmentally friendly, pollute the environment, endanger human health, and have the risk of fire; The metal antirust paint prepared by acrylic emulsion or tertiary acrylic emulsion cannot be painted with rust, and a large amount of manual rust removal is required, and the anti-rust and anti-rust capabilities are very poor. One of the important varieties that need to be developed urgently

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The raw materials are: (1) Vinyl monomers: 2.0 kg of methyl methacrylate, 22.0 kg of styrene, and 16.0 kg of butyl acrylate;

[0028] (2) Functional monomers: methacrylate phosphate 1.5kg, glycidyl methacrylate 1.0kg, vinyl trimethoxysilane 0.6kg,

[0029] (3) Functional monomer: 0.8kg of acrylic acid, 0.7kg of acrylamide;

[0030] (4) Emulsifier: nonylphenol polyoxyethylene ether 0.4kg, sulfosuccinic acid ethoxylated nonylphenol half ester disodium 0.3kg, polyethylene glycol phosphate 0.6kg, Allyl alkylphenol polyoxyethylene ether ammonium sulfate 0.3kg, alkylphenol polyoxyethylene ether ammonium sulfate 0.4kg;

[0031] (5) Initiator sodium persulfate 0.25 kg, pH adjuster sodium bicarbonate 0.1 kg, water 53.05 kg.

[0032] The process steps are:

[0033] (1) Sodium persulfate is dissolved in 5kg of water; sodium bicarbonate is dissolved in 0.05kg of water; after mixing the emulsifier, take 20%-45% and the remaining water into the reactor, start stirring and mixing; The monomer,...

Embodiment 2

[0038] The raw materials are: (1) Vinyl monomers: styrene 16.0, butyl acrylate 16.0, methyl methacrylate 8.0kg;

[0039] (2) Functional monomers: methacrylate phosphate 1.5kg, glycidyl methacrylate 1.0kg, vinyl trimethoxysilane 0.6kg,

[0040] (3) Functional monomer: methacrylate phosphate 1.5, glycidyl methacrylate 1.5, vinyl trimethoxysilane 1.0 kg;

[0041] (4) Emulsifier: nonylphenol polyoxyethylene ether 0.4, sulfosuccinic acid ethoxylated nonylphenol half ester disodium 0.3, polyethylene glycol phosphate 1.0, Allyl alkylphenol polyoxyethylene ether ammonium sulfate 0.4, alkylphenol polyoxyethylene ether ammonium sulfate 0.4kg;

[0042] (5) Initiator sodium persulfate 0.25 kg, pH adjuster 25wt% ammonia water 0.1 kg, water 51.65 kg.

[0043] The process steps are:

[0044] (1) After mixing the emulsifier, take 20%-45% and 45kg of water into the reactor, start stirring and mixing; mix all the vinyl monomers, functional monomers, functional monomers and other emulsifiers for pre-emuls...

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PUM

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Abstract

The invention relates to the field of materials and discloses an auto-rust converting rust-containing corrosion resistant emulsion and preparation method thereof. The auto-rust converting rust-covering corrosion resistant emulsion is prepared as follows: a mixture of at least one from metacrylic acid ester or acrylic ester and styrene is selected as an allyl monomer; methacrylic acid phosphate, methacrylic acid glycidyl ester and vinyl tri-methoxysilane are selected as functional monomers; a mixture diester of at least one from acrylic acid, or methacrylic acid and acrylamide is selected as a functional monomer; poly (ethylene glycol) phosphate, allyl alkylphenol polyoxyethylene ammonium sulfate, and the like, are selected as emulsifying agents. The emulsion prepared has the auto-rust converting function, does not a huge amount of manual work to eliminate rusts during coating and can be coated by containing rust. Moreover, the emulsion has good corrosion resistant capacity, is safe and environmental friendly, is innocuous, can not cause fire, and reduces the working intensity and harmfulness of constructors.

Description

Technical field [0001] The invention belongs to the field of materials, and relates to a self-rotating rust belt rust antirust emulsion, which is an acrylic ester copolymer emulsion. Background technique [0002] Rusty paint is a kind of primer that protects metals. It can be directly painted on the metal surface with residual rust to passivate the rust and stabilize or transform it. It only needs to remove the floating rust on the rusty surface during use, which can improve working conditions, reduce the workload of rust removal, and improve production efficiency. [0003] The rust-turning anti-rust coating can be directly used on the metal surface without pretreatment, which has anti-corrosion effect; it eliminates the complicated pre-treatment procedures such as sanding, pickling and water washing, which can reduce costs and improve work efficiency. At the same time, the rust layer on the metal surface can be converted into a hydrophobic passivation layer, which provides longer...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F212/08C08F220/14C08F220/18C08F230/02C08F220/32C08F230/08C08F220/06C08F220/56C08F2/30C08F2/26C09D125/14C09D5/08C09D133/08
Inventor 王邦宪
Owner 佛山保立佳化工有限公司
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