Electrically conductive polymer composition and method for producing same

一种导电性高分子、高分子化合物的技术，应用在导电材料、导电材料、导体等方向，能够解决高溶解性、难以兼具、高电导率等问题，达到稳定性高的效果

Active Publication Date: 2012-05-23
SOKEN CHEM & ENG CO LTD
View PDF4 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Therefore, it is known that it is difficult to achieve both high electrical conductivity and high solubility (solubility by heat or solvent) in π-conjugated polymers

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Electrically conductive polymer composition and method for producing same
  • Electrically conductive polymer composition and method for producing same
  • Electrically conductive polymer composition and method for producing same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0126] Although the conductive polymer composition of the present invention was specifically described by showing examples, the present invention is not limited to these examples.

[0127] In the examples, the molecular weight and the surface resistance value were measured by the following methods.

[0128]

[0129] Measurement was carried out by GPC under the following conditions.

[0130] Device name: HLC-8120 (manufactured by Tosoh Co., Ltd.)

[0131] Column: GF-1G7B+GF-510H Q (Asahipak: registered trademark, manufactured by Showa Denko Co., Ltd.)

[0132] Standard material: polystyrene and sodium polystyrene sulfonate

[0133] Sample concentration: 1.0mg / ml

[0134] Eluent: 50 mmol lithium chloride aqueous solution / CH3CN=60 / 40wt

[0135] Flow: 0.6ml / min

[0136] Column temperature: 30°C

[0137] Detector: UV254nm

[0138]

[0139] Measurement was carried out by the four-terminal four-probe method using Low Resistivity Meter Loresta GP and PSP probes manufactured...

preparation example 1

[0141] With a mixer, nitrogen inlet tube, reflux condenser, inlet and thermometer, capacity 1000cm 3 In a four-necked flask, drop 24.3g of sodium methacrylate 2-ethanesulfonate (MS-2N) (25% by mole), 25.7g of acetoacetoxyethyl methacrylate (AAEM) (25% by mole) 15%), 42.8g of benzyl methacrylate (BzMA) (30% by mole), 48.2g of 2-ethylhexyl methacrylate (2EHMA) (30% by mole), 150g of ion-exchanged water, 300 g of isopropyl alcohol (IPA). While introducing nitrogen into the flask, the temperature of the mixture in the flask was raised to 70°C. Then, 0.7 g of azobisisobutyronitrile was charged into the flask, and a polymer solution (A-1) containing a polymer compound (A) was obtained by performing a polymerization reaction at 70° C. for 18 hours.

[0142] Move the whole amount of the resulting polymer solution (A-1) to 2000cm 3 500 g of hexane was added while being stirred by a stirrer, and then left to stand for 1 hour to remove the oil layer containing impurities. The solutio...

preparation example 2～11

[0145] Polymer compounds (AP-2) to (AP-11) were obtained in the same manner as in Preparation Example 1 except that the monomers were replaced with those shown in Table 1-1. In addition, Mw of polymer compounds (AP-2) to (AP-11) is shown in Table 1-1. In addition, Preparation Example 1 is also shown in Table 1-1.

[0146] 【Table 1-1】

[0147]

[0148] The abbreviations in Table 1-1 are as follows.

[0149] MS-2N: Sodium 2-ethanesulfonate methacrylate

[0150] NaSS: sodium styrene sulfonate

[0151] AAEM: Acetoacetoxyethyl methacrylate

[0152] PME-100: Methoxydiethylene glycol methacrylate

[0153] BzMA: benzyl methacrylate

[0154] 2EHMA: 2-Ethylhexyl methacrylate

[0155] CHMA: Cyclohexyl methacrylate

[0156] HEMA: 2-Hydroxyethyl methacrylate

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
weight-average molecular weightaaaaaaaaaa
number average molecular weightaaaaaaaaaa
Login to view more

Abstract

Disclosed is an electrically conductive polymer composition comprising a dopant and a p-conjugated polymer, which can be uniformly dissolved in a solvent and form a smooth film. Specifically disclosed is an electrically conductive polymer composition comprising a polymer compound (A) and a p-conjugated polymer (ss), wherein said polymer compound (A) is obtained by polymerizing 10-50 mol% of a monomer (a-1) having a sulfonic acid group or a sulfonate group, 10-90 mol% of a monomer (a-2) having a chelating ability and 0-70 mol% of another monomer (a-3), and said p-conjugated polymer (ss) is obtained by polymerizing at least one kind of a monomer selected from among monomers represented by formulae (I) to (III).

Description

technical field [0001] The invention relates to a conductive polymer composition and a preparation method thereof. More specifically, it relates to a conductive polymer composition containing a π-conjugated polymer and a preparation method thereof. Background technique [0002] In order to impart higher conductivity to the π-conjugated polymer, doping with a dopant is performed. [0003] However, in a polymer originally developed in π-conjugation, the planarity of the polymer chain is high, and the crystallinity (stacking property) between the polymer chains due to the affinity of the π bond is high. When such a π-conjugated polymer is doped with a dopant, the above-mentioned planarity and crystallinity will be further improved. Therefore, the solubility (solubility by heat or solvent) of the π-conjugated polymer doped with the dopant generally decreases. [0004] Therefore, it is known that it is difficult to achieve both high electrical conductivity and high solubility ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L101/02C08G61/12C08G73/02C08L65/00C08L79/00
CPCC08L101/12C08G2261/3221C08L65/00C08G61/124C08G73/0266C08G2261/43C08G2261/3223C09D179/02C08G61/126C08G2261/91C08L2203/20C08G2261/51H01B1/124C08G61/12C08G73/02C08L101/02
Inventor 冈本秀二小林文明
Owner SOKEN CHEM & ENG CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap