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Fluidized bed catalytic deoxidation method for oxygen-containing coal bed gas

A catalytic deoxidation and coalbed methane technology, applied in the direction of gas fuel, petroleum industry, fuel, etc., can solve the problems of high energy consumption, reduction of relative heat release, low production intensity, etc., and achieve simple equipment structure, good gas-solid contact effect, Strong ability to resist load fluctuations

Active Publication Date: 2014-04-16
SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patents CN101139239A and CN101613627A disclose an adiabatic fixed bed coalbed methane deoxygenation reactor, which adopts the method of circulating partially deoxygenated methane-rich gas to reduce the relative oxygen content in coalbed methane, thereby reducing the relative heat release, so as to control the reaction temperature of the catalyst bed at Within an appropriate range, prevent local overheating and overheating, causing catalyst deactivation and sintering, but this also results in high energy consumption and low production intensity of the process

Method used

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  • Fluidized bed catalytic deoxidation method for oxygen-containing coal bed gas

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Embodiment 1

[0034]The fluidized bed deoxygenation reactor is composed of a shell 19, an oxygen-containing coalbed gas inlet nozzle, a tube heat exchanger 2, a deoxidized coalbed gas outlet 16, a deoxidation catalyst particle inlet 17, a catalyst particle discharge port 18, a cooling water inlet 15 and The steam outlet 14 is formed, and the vertical tube heat exchanger 2 is arranged in the shell 19, and the tube diameter is 25 mm. The lower end of the tubes is connected in parallel with the cooling water inlet 15, the upper end of the tubes is connected in parallel with the steam outlet 14, the cooling water inlet 15 and the steam outlet 14 are connected with the steam drum 3, and the lower part of the shell 1 is a cone with an apex angle of 60 ° There are two rows of oxygen-containing coalbed methane upper layer air inlet nozzles 12 and oxygen-containing coalbed methane lower layer air inlet nozzles 13 on the cone, and the oxygen-containing coalbed methane upper layer air inlet nozzles 12 ...

Embodiment 2

[0039] The structure of the fluidized bed deoxygenation reactor is as described in Example 1. The tube diameter of the tube heat exchanger is 38 mm, and the cone angle at the bottom of the fluidized bed reactor is 90°.

[0040] The composition of oxygen-containing coalbed methane is (volume percentage): CH 4 Content 52.40%, O 2 Content 9.93%, N 2 The content is 37.36%, and the content of other gases is 0.23%. The deoxidation catalyst is a spherical cobalt-based catalyst (30% cobalt oxide content, 67% aluminum oxide content, and 3% other metal additive content), with a particle size of 40-200 μm and a bulk density of 0.65 g / cm 3 . The operating temperature of the fluidized bed deoxygenation reactor is 480-500°C, the pressure is 0.1MPa, the operating gas velocity is 0.4-0.6m / s, and the drum pressure is 1.2-1.5MPa. All the other are the same as example 1. After the oxygen-containing coalbed methane is deoxidized by fluidized bed catalyst, the oxygen content in the deoxidized...

Embodiment 3

[0044] The structure of the fluidized bed deoxygenation reactor is as described in Example 1. The composition of oxygen-containing coalbed methane is (volume percentage): CH 4 Content 68.27%, O 2 Content 6.58%, N 2 Content 24.80%, other gas content 0.35%. The deoxidation catalyst is a spherical copper-based catalyst (the content of copper oxide is 8%, the content of aluminum oxide is 87%, and the content of other metal additives is 5%), the particle size is 60-240μm, and the bulk density is 0.68g / cm 3 . The operating temperature of the fluidized bed deoxygenation reactor is 500-520°C, the pressure is normal pressure, the operating gas velocity is 0.7-0.8m / s, and the drum pressure is 1.0-1.2MPa. All the other are the same as example 1. After the oxygen-containing coalbed methane is deoxidized by fluidized bed catalyst, the oxygen content in the deoxidized coalbed methane is 0.32%. The gas compositions of the feed gas (oxygen-containing coalbed methane) and deoxygenated ga...

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Abstract

The invention relates to a fluidized bed catalytic deoxidation method for oxygen-containing coal bed gas. The fluidized bed catalytic deoxidation method comprises the following steps that: a fluidized bed deoxidation reactor is preheated to the temperature of 300-400 DEG C; the oxygen-containing coal bed gas is fed into the fluidized bed deoxidation reactor; deoxidation catalyst granules are loaded into a feed hopper and are added into the fluidized bed deoxidation reactor under the action of air blowing and supplying; methane and oxygen in the coal bed gas are subjected to low-temperature catalytic combustion reaction in the fluidized bed deoxidation reactor; the gas moves upwards with the carrying of part of solid catalyst granules and enters a one-stage cyclone separator and a two-stage cyclone separator from the top outlet of the fluidized bed deoxidation reactor, and the collected solid catalyst granules circularly enter the fluidized bed deoxidation reactor under the control of a feed back control valve and air blowing and supplying; and the deoxidated coal bed gas which is subjected to coarse dust removal by the cyclone separators is subjected to fine catalyst dust removal by a high-temperature filter, and then, is transferred to a follow-up system for use. The fluidized bed catalytic deoxidation method for the oxygen-containing coal bed gas has the advantages of good safety, low energy consumption, high deoxidation efficiency, long service life of catalyst and large processing capacity.

Description

technical field [0001] The invention relates to a fluidized bed catalytic deoxygenation method and equipment for oxygen-containing coal bed gas. Background technique [0002] my country is a big coal consumption country. In the process of coal mining, in order to ensure the safety of mine production, a large amount of low-concentration air-mixed coalbed methane is drained, the main component of which is methane (CH 4 ) and air. According to statistics, billions of cubic meters of coalbed methane are emitted from coal mining in my country every year, most of which are directly vented and burned, which not only wastes resources, but also aggravates the greenhouse effect of the atmosphere and causes environmental pollution. [0003] Low-concentration oxygen-containing coalbed methane contains 30-70% methane and 5-15% oxygen. It is flammable and explosive. The current main utilization methods are direct combustion and power generation, and its economic value has not been fully ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L3/10
Inventor 房倚天赵建涛王洋黄戒介方惠斌董立波王建国
Owner SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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