Method for testing wettability of electronic-grade glass fiber cloth

Abstract

The invention discloses a method for testing wettability of electronic-grade glass fiber cloth. The method comprises the following steps of: (1) preparing a mixed reagent, wherein the mixed reagent comprises the following components 60-99wt% of mixed solvent, 1-40wt% of indicating agent and 0-30wt% of auxiliary; (2) selecting the electronic-grade glass fiber cloth with qualified wettability, dripping a rated amount of mixed reagent in the step (1) at an appointed height on the surface of the electronic-grade glass fiber cloth, starting timing, measuring the dispersion length of the mixed reagent along a warp direction and a weft direction within unit time, recording, and taking the dispersion length as standard data; (3) selecting the electronic-grade glass fiber cloth to be tested, and testing the electronic-grade glass fiber cloth by the same method in the step (2) to obtain test data; and (4) comparing the test data with the standard data, so as to judge whether the wettability of the electronic-grade glass fiber cloth to be tested is normal. According to the test method, a test requirement for quick and continuous detection is met; and the test method is suitable for working occasions in which the wettability of a large amount of glass fiber cloth can be tested quickly and accurately.

Description

technical field [0001] The invention relates to a method for testing the wettability of electronic-grade glass fiber cloth, which can be used in the printed circuit board industry. Background technique [0002] Wettability is one of the key indicators of electronic grade glass fiber cloth, and its quality and stability are directly related to the quality level and quality consistency of CCL products. The molding process of glass fiber cloth reinforced copper clad laminate requires full infiltration between the glass fiber cloth and the resin matrix to ensure a good interface between the two, reducing or even eliminating base material voids and resin voids caused by poor impregnation. The occurrence of internal defects in the material. Prevent microcracks or cationic migration of the board due to poor bonding in high temperature and high humidity environments, resulting in delamination and blistering of the board or failure of insulation reliability. The glass fiber fabric ...

AI Technical Summary

Problems solved by technology

[0003] At present, there are mainly the following methods for testing and evaluating the wettability of glass fiber cloth in the electronic grade glass fiber cloth and copper clad laminate industry: (1) Sinking method: put a certain viscosity of resin or glue in the container, and put a glass fiber cloth of standard size Place the sample horizontally above the liquid surface, and record the time until the glass fiber cloth sample completely sinks; the disadvantage is that the solvent volatilizes continuously during the test, and the viscosity of the resin or glue increases gradually, resulting in a large change in the environmental conditions of the test. The end point of the test is judged by humans, and the error is large, which eventually leads to poor repeatability of the test results

(2) Bullseye method: Draw a line similar to a target with a pencil on a white paper, place a standard size glass fiber cloth sample flat on the paper, drop a certain amount of resin or glue on the bullseye, and record the appearance of the bullseye and the lines The time; its disadvantages: the transparency of the glass fiber cloth itself is different and the diffusion speed of the glue or resin is slow, and it is difficult to determine the uniform standard for the clarity of the displayed lines, resulting in inaccurate measurement results

Within the rated time, the more white stripes, the poorer the wettability; or the shorter the time required for complete wetting, that is, the white stripes disappear completely, the better the wettability; the disadvantage: the volatilization of the solvent during the experiment will affect The viscosity of the resin or glue affects the test results. The resin or glue is greatly affected by the environment, so it is difficult to configure standard test conditions and maintain fixed test conditions for a long time

The light transmittance of the incompletely soaked glass fiber cloth is poor, and the light transmittance of the fully soaked sample is good. The curve of the light transmittance changing with time during the soaking process of the test sample is obtained, and the data is converted into light transmittance data. Through testing and drawing This curve is used to analyze and compare the wettability characteristics of glass fiber cloth; its disadvantage: the wettability between resin and glass fiber cloth cannot fully represent the wettability after the glue is configured with this resin; at the same time, because of the volatility of the solvent, the configuration The glue with basically the same viscosity is relatively difficult and time-consuming, and it is not suitable for rapid and large-scale use in the occasion of testing the wettability of glass fiber cloth

(5) Luminance factor method of bonded sheet: In the Yxy system of the colorimeter, Y is the transparency factor, take the prepreg prepared after the glass fiber cloth is soaked in glue and baked, cut it into a standard test size, and measure it with the colorimeter Y value, for the same type of glass fiber cloth and the same resin content, the smaller the Y value, the smaller the bubbles in it, and the better the wettability; its disadvantages: the difference in the measurement results of this method is not obvious, and it is affected by other factors. large; at the same time, this method is only applicable to copper-clad laminate manufacturers, and does not take advantage of the sampling and testing of fiberglass cloth manufacturers

(6) Solvent penetration method: Cut the glass fiber cloth into standard long strip test size along the latitude and longitude direction, draw a line mark with a pencil along the width direction at the specified position at the lower end, and then clamp the two ends of the test strip with clips , hang vertically, immerse the lower end in a container filled with solvent until the liquid level is level with the mark, start timing, lift the sample from the liquid level after 1 minute and let it dry for 1 minute, immediately test and record the height of the solvent penetration; its Disadvantages: The solvent cannot replace or represent the wettability between the actual glue and the glass fiber cloth, the correspondence is not good, and the test requires high squareness of the glass fiber cloth sample, and the warp and weft cuts have a great influence on the test results

[0004] To sum up, the existing test methods for electronic grade glass fiber cloth can characterize the wettability of glass fiber cloth to a certain extent, but they cannot meet the occasions of large-scale and rapid detection, such as in the shipment inspection and inspection of glass fiber cloth manufacturers. On-line inspection before use by copper clad laminate manufacturers

In addition, the above test methods generally need to prepare the glass fiber cloth into a prepreg before making a judgment, and there will be various influencing factors in the process of preparing the prepreg, so the above measurement method cannot fully represent the wettability of the glass fiber cloth.

Images