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Aminocarbazole/aniline copolymer and synthesis method thereof

A technology of aniline copolymer and aminocarbazole is applied in the field of preparation of novel organic conjugated polymers, which can solve the problems of high price, poor solubility of polyaniline, poor fluorescence performance of polyaniline, etc. Blue-emitting, highly fluorescent effect

Inactive Publication Date: 2012-08-15
UNIV OF SHANGHAI FOR SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the solubility of polyaniline itself is poor, only soluble in very strong polar N -methyl-pyrrolidone, and the solvent is very expensive
In addition, the fluorescence performance of polyaniline itself is also poor.

Method used

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  • Aminocarbazole/aniline copolymer and synthesis method thereof
  • Aminocarbazole/aniline copolymer and synthesis method thereof
  • Aminocarbazole/aniline copolymer and synthesis method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0077] Synthesis of Pure Polyaniline Namely Aminocarbazole / Aniline (0 / 100) Copolymer

[0078] The aminocarbazole / aniline copolymerization molar ratio is 0 / 100, that is, accurately weigh 186mg (2mmol) aniline and dissolve it in 13mL ethanol to form a monomer solution;

[0079] According to the molar ratio of oxidizing agent and aniline monomer being 2 / 1, weigh 912 mg (4 mmol) of oxidizing agent ammonium persulfate and dissolve it in 10 mL of 1.0 mol / L hydrochloric acid solution to form an oxidizing agent solution.

[0080] Pour the oxidant solution into the aniline monomer solution, shake vigorously for 10 seconds, control the temperature at 25°C, and let it stand for 24 hours to react. After the reaction is finished, the reaction solution is taken out and centrifugally settled to obtain a solid product, and the product is washed with deionized water; the solid product is washed with 8 times of deionized water, centrifugally settled, and repeated washing-centrifugation three ti...

Embodiment 2

[0083] Synthesis of aminocarbazole / aniline (10 / 90) copolymer

[0084] The molar ratio of aminocarbazole / aniline copolymerization is 10 / 90, that is, accurately weigh 42mg (0.2mmol) of aminocarbazole and 168mg (1.8mmol) of aniline and dissolve them in 13mL of ethanol to form a comonomer solution;

[0085] According to the molar ratio of oxidizing agent and comonomer being 2 / 1, 912 mg (4 mmol) of oxidizing agent ammonium persulfate was weighed and dissolved in 10 mL of 1.0 mol / L hydrochloric acid solution to form an oxidizing agent solution.

[0086] Pour the oxidizing agent solution into the aminocarbazole / aniline comonomer solution, shake vigorously for 10 seconds, control the temperature at 25°C, and let it stand for 24 hours to react. After the reaction is finished, the reaction solution is taken out and centrifugally settled to obtain a solid product, and the product is washed with deionized water; the solid product is washed with 8 times of deionized water, centrifugally se...

Embodiment 3

[0089] Synthesis of aminocarbazole / aniline (30 / 70) copolymer

[0090] The molar ratio of aminocarbazole / aniline copolymerization is 30 / 70, that is, accurately weigh 126mg (0.6mmol) aminocarbazole and 130mg (1.4mmol) aniline and dissolve them in 13mL ethanol to form a comonomer solution;

[0091] According to the molar ratio of oxidizing agent and comonomer being 2 / 1, 912 mg (4 mmol) of oxidizing agent ammonium persulfate was weighed and dissolved in 10 mL of 1.0 mol / L hydrochloric acid solution to form an oxidizing agent solution.

[0092] Pour the oxidizing agent solution into the aminocarbazole / aniline comonomer solution, shake vigorously for 10 seconds, control the temperature at 25°C, and let it stand for 24 hours to react. After the reaction is finished, the reaction solution is taken out and centrifugally settled to obtain a solid product, and the product is washed with deionized water; the solid product is washed with 8 times of deionized water, centrifugally settle...

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Abstract

The invention discloses an aminocarbazole / aniline copolymer and a synthesis method thereof. The synthesis method comprises the following steps: dissolving 3-amino-9-ethylcarbazole and aniline in different mol ratios in a first solvent to form a comonomer solution; dissolving a certain amount of oxidant in a second solvent to form an oxidant solution; and after blending the oxidant solution and the comonomer solution, shaking intensely for some time, standing, and reacting completely to obtain the aminocarbazole / aniline copolymer. The invention has the advantages of simple synthesis steps, high efficiency and high controllability; and the obtained carbazole / aniline conducting polymer can be used in the fields of electrodes, electron screening, electrostatic prevention, electrochromic materials, fluoroscopic examination and the like.

Description

technical field [0001] The invention belongs to the technical field of preparation of novel organic conjugated polymers, in particular to an aminocarbazole / benzene [0002] Amine copolymers and methods for their synthesis. Background technique [0003] As a new type of functional material, organic conjugated polymers have not only the electronic properties of metals and semiconductors, but also the mechanical properties of easy processing and flexibility of polymers. The quasi-one-dimensional macromolecular structure of organic conjugated polymers endows them with unique optical, electrical, and magnetic properties, so it has become a hot spot in applied research in recent years. [0004] Polyaniline has become one of the most widely studied organic conjugated polymers because of its cheap, easy synthesis, high conductivity, good environmental stability, and specific acid-doping / base-dedoping effects. (Tran H D, Li D, Kaner R B. One-dimensional conducting polymer nanostru...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G73/06C08G73/02C07D209/88C09K11/06
Inventor 廖耀祖蔡思思王霞
Owner UNIV OF SHANGHAI FOR SCI & TECH
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