High thermal conductivity membrane adhesive, adhesive composition and semiconductor package using the adhesive and manufacturing method thereof
A high thermal conductivity and adhesive technology, which is applied in semiconductor/solid-state device manufacturing, semiconductor devices, semiconductor/solid-state device components, etc., can solve problems such as insufficient adhesion of the attached body, and achieve excellent adhesion and wear rate. The effect of small size and excellent thermal conductivity
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Embodiment 1
[0121] First, weigh 55 parts by mass of triphenylmethane-type epoxy resin (trade name: EPPN-501H, weight average molecular weight: 1000, softening point: 55°C, solid, epoxy equivalent: 167, manufactured by Nippon Kayaku Co., Ltd.) , Bisphenol A type epoxy resin (trade name: YD-128, weight average molecular weight: 400, softening point: 25° C. or less, liquid, epoxy equivalent: 190, manufactured by Nichika Epoxy Co., Ltd.) 49 parts by mass , and 30 parts by mass of bisphenol A / F type phenoxy resin (trade name: YP-70, weight average molecular weight: 55000, Tg: 70°C, manufactured by Nichika Epoxy Co., Ltd.), and 91 parts by mass of formazan Using methyl isobutyl ketone (MIBK) as a solvent, heating and stirring at a temperature of 110° C. for 2 hours in a 500 ml separable flask was carried out to obtain a resin varnish. Then, 225 parts by mass of this resin varnish was moved to an 800ml planetary mixer, and aluminum nitride (trade name: H-Grade, average particle diameter 1.1 μm, ...
Embodiment 2
[0123] In addition to changing the amount of aluminum nitride (trade name: H-Grade, average particle size 1.1 μm, Mohs hardness 8, thermal conductivity 200W / (m·K), manufactured by Tokuyama Co., Ltd.) to 489 parts by mass, The rest were performed in the same manner as in Example 1 to obtain a film-like adhesive. The same measurement as in Example 1 was performed on the obtained film adhesive. The obtained results are shown in Table 1 together with the composition of the film adhesive.
Embodiment 3
[0125] In addition to changing the amount of aluminum nitride (trade name: H-Grade, average particle size 1.1 μm, Mohs hardness 8, thermal conductivity 200W / (m·K), manufactured by Tokuyama Co., Ltd.) to 267 parts by mass, The rest were performed in the same manner as in Example 1 to obtain a film adhesive. The same measurement as in Example 1 was performed on the obtained film adhesive. The obtained results are shown in Table 1 together with the composition of the film adhesive.
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