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Preparation method of chemical adsorption material for removing ammonium ions in wastewater

A chemical adsorption, ammonium ion technology, applied in chemical instruments and methods, separation methods, inorganic chemistry and other directions, can solve problems such as high water content, secondary pollution, large sludge volume, etc., to improve utilization, reduce side effects, etc. The effect of reacting and avoiding secondary pollution

Inactive Publication Date: 2014-07-30
CHANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The invention revolves around the fact that the traditional chemical precipitation method requires excessive magnesium ions and phosphate ions to be added to remove ammonium ions, and the generated sludge has a large amount and high water content, and at the same time introduces new phosphate ion residues, causing secondary pollution to the environment Problem, a preparation method for removing ammonium ion-containing chemical adsorption materials in wastewater is proposed. Using this adsorption material to treat wastewater containing ammonium ion has high reaction efficiency and produces pure substances, which greatly reduces the risk of secondary pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0021] First crush the magnesite and decompose it with nitric acid to generate a magnesium nitrate solution; then add sodium hydroxide to the above solution and continuously feed CO 2 gas, generate a yellow-white precipitate, filter to obtain a filter residue; then the resulting filter residue is repeatedly washed three times with horny ethanol and methyl ketone under the action of ultrasonic waves; 3% polyacrylonitrile, 15% polycaprolactam and 3% azoaminobenzene solution, mixed evenly, and set aside overnight; then the above-mentioned prepared mixture was cooked at a pressure of 2.0 MPa and a temperature of 90 ° C for 3 hours; Finally, after cooking, release under reduced pressure at a vacuum degree of 0.02 MPa and normal temperature to obtain a fluffy, porous white substance, which is the ammonium chemical adsorption material.

[0022] First treat the adsorption material with phosphoric acid, then put the adsorption material as filler into the adsorption tower; then let the ...

example 2

[0024] First crush the magnesite and decompose it with nitric acid to generate a magnesium nitrate solution; then add sodium hydroxide to the above solution and continuously feed CO 2 gas, generate a yellow-white precipitate, filter to obtain a filter residue; then the resulting filter residue is repeatedly washed three times with horny ethanol and methyl ketone under the action of ultrasonic waves; 4% polyacrylonitrile, 20% polycaprolactam and 4% azoaminobenzene solution, mixed evenly, and set aside overnight; then the above-mentioned prepared mixture was cooked at a pressure of 3.0 MPa and a temperature of 100 ° C for 4 hours; Finally, after cooking, release under reduced pressure at a vacuum degree of 0.04 MPa and normal temperature to obtain a fluffy, porous white substance, which is the ammonium chemical adsorption material.

[0025] First treat the adsorption material with phosphoric acid, then put the adsorption material as a filler into the adsorption tower; then let t...

example 3

[0027] First crush the magnesite and decompose it with nitric acid to generate a magnesium nitrate solution; then add sodium hydroxide to the above solution and continuously feed CO 2 gas, generate a yellow-white precipitate, filter to obtain a filter residue; then the resulting filter residue is repeatedly washed three times with horny ethanol and methyl ketone under the action of ultrasonic waves; 3% polyacrylonitrile, 18% polycaprolactam and 4% azoaminobenzene solution, mix well, and set aside overnight; then cook the above-mentioned prepared mixture at a pressure of 2.0MPa and a temperature of 95°C for 3.5 hours; Finally, after cooking, release under reduced pressure at a vacuum degree of 0.03MPa and normal temperature to obtain a fluffy, porous white substance, which is the ammonium chemical adsorption material.

[0028] First treat the adsorption material with phosphoric acid, then put the adsorption material into the adsorption tower as a filler; then let the wastewater...

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Abstract

The invention relates to a preparation method of a chemical adsorption material for removing ammonium ions in wastewater, and belongs to the field of wastewater treatment. The preparation method includes the steps: firstly, grinding magnesite into powder and generating deposits after acid washing and alkaline leaching; mixing the deposits with 3-4% of polymerized organic polyacrylonitrile, 15-20% of polycaprolactam and 3-4% of diammonium nitrogen-based benzene solution of foaming agents; and generating the adsorption material with free Mg2+ under the pressure of 2.0-3.0MPa and at the temperature of 90-100 DEG C. Firstly, the adsorption material is soaked by phosphoric acid and then placed into an adsorption tower by serving as packing; secondly, the wastewater containing the ammonium ions flows through the adsorption tower and chemically reacts with the adsorption material in the packing tower; and finally, white crystalline magnesium ammonium phosphate is generated. The influence of side reaction is avoided by the adsorption material, phosphate deposits with high purity are obtained, and secondary pollution caused by a traditional precipitation method is avoided.

Description

technical field [0001] The invention discloses a preparation method of a chemical adsorption material containing ammonium ions in wastewater, belonging to the field of sewage treatment. Background technique [0002] The traditional chemical precipitation method to remove ammonium ions is to add magnesium ions. Phosphate ions react with ammonium ions to form magnesium ammonium phosphate precipitation. Magnesium salts and phosphate ions need to be added. Due to the presence of other ions in the wastewater, this reduces the direct reaction ion magnesium The collision probability of ions, phosphate ions and ammonium ions produces a quasi-equilibrium phenomenon of tiny precipitated particles, causing the apparent solubility product to be much higher than the real solubility product. In order to achieve the formation conditions of phosphate precipitation, it is necessary to add metal ions The concentration of the precipitant is often 1-2 orders of magnitude greater than the normal...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/30B01J20/04B01J20/34C02F1/28C02F1/58C01B25/45
Inventor 陈毅忠包铠
Owner CHANGZHOU UNIV