PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material and preparation method thereof

A composite material and antistatic masterbatch technology, applied in the field of PVC/graphene antistatic composite material and its preparation, to achieve excellent comprehensive performance, solve poor processing performance, and ensure the effect of electrical conductivity

Active Publication Date: 2012-11-14
XIAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Using traditional processing methods, it is difficult for PVC to achieve a surface resistivity of 3.0×10 for a long time 8 Antistatic requirements of GB / T20105-2006 and coal mining industry MT164-2007, MT165-2007 below Ω

Method used

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  • PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material and preparation method thereof
  • PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material and preparation method thereof
  • PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039]The PVC / graphene antistatic composite material of the present embodiment is characterized in that it is made of the following raw materials in weight percentage: 9.5% impact modifier, 4.5% conductive filler, 3.5% processing aid, and 82.5% matrix resin; The impact modifier is chlorinated polyethylene and a copolymer of methyl methacrylate and acrylate (mass ratio 8.9:0.6); the conductive filler is expanded graphite; the processing aid consists of a heat stabilizer It is mixed with lubricant according to the mass ratio of 2.9:0.6, wherein the heat stabilizer is N-phenylmaleamide radical lanthanum, and the lubricant is stearic acid and paraffin (mass ratio 1:1); the base resin It is polyvinyl chloride; the expanded graphite is made of expandable graphite (commercially available Kp25) with an expansion rate of 200-350 and expanded by microwave irradiation with a frequency of 2450MHz for 10s.

[0040] The preparation method of the PVC / graphene antistatic composite material of...

Embodiment 2

[0051] The PVC / graphene antistatic composite material of the present embodiment is characterized in that it is made of the following raw materials in weight percentage: 8% impact modifier, 3% conductive filler, 14% processing aid, and 75% matrix resin; The impact modifier is chlorinated polyethylene and a copolymer of methyl methacrylate and acrylate (mass ratio 7.6:0.4); the conductive filler is expanded graphite; the processing aid consists of a heat stabilizer , lubricant and plasticizer are mixed according to the mass ratio of 3.6:0.4:10, wherein the thermal stabilizer is N-phenylmaleamide lanthanum, and the lubricant is stearic acid and paraffin (mass ratio 1:1 ), the plasticizer is polyethylene adipate with a molecular weight of 2250; the matrix resin is polyvinyl chloride; the expanded graphite is composed of expandable graphite (commercially available Kp32) with an expansion ratio of 200 to 400. Made by 2450MHz microwave irradiation for 3s.

[0052] The preparation me...

Embodiment 3

[0062] The PVC / graphene antistatic composite material of the present embodiment is characterized in that it is made of the following raw materials in weight percentage: 5% impact modifier, 5% conductive filler, 5% processing aid, and 85% matrix resin; The impact modifier is chlorinated polyethylene and a copolymer of methyl methacrylate and acrylate (mass ratio 3:2); the conductive filler is expanded graphite; the processing aid consists of a heat stabilizer It is mixed with a lubricant at a mass ratio of 3:2, wherein the heat stabilizer is N-phenylmaleamide lanthanum, and the lubricant is stearic acid and paraffin (mass ratio 1:1); the base resin It is polyvinyl chloride; the expanded graphite is made of expandable graphite (commercially available Kp32) with an expansion rate of 200-400 and expanded by microwave irradiation with a frequency of 2450MHz for 15s.

[0063] The preparation method of the PVC / graphene antistatic composite material of the present embodiment is:

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Abstract

The invention discloses a PVC (Polyvinyl Chloride)/graphite alkene antistatic composite material. The PVC graphite alkene antistatic composite material is prepared by the following ingredients in percentage by weight: 2-20% of a shock resistance modifying agent, 0.5-10% of an electric conductive filler, 2-20% of a processing agent and the balance of matrix resin. In addition, the invention also provides a preparation method of the PVC/graphite alkene antistatic composite material. Due to the adoption of the preparation method, the PVC has the antistatic property, and the enhancing and toughening are realized at the same time; and the surface resistivity of the prepared PVC/graphite alkene antistatic composite material is 104-108 omega, the volume resistivity is not more than 108 omega/cm, the tensile strength is not less than 50MPa, the impact strength is not less than 5kJ/m<2>, the elongation at break is not less than 75%, and the antistatic requirements on GB/T20105-2006 and MT164-2007 and MT165-2007 in the colliery industry are met.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a PVC / graphene antistatic composite material and a preparation method thereof. Background technique [0002] PVC has the advantages of flame retardant, chemical corrosion resistance, wear resistance, excellent electrical insulation and high mechanical strength. It is widely used in various fields and is the second largest general-purpose plastic in output after polyethylene. But the surface resistance of PVC is as high as 10 14 Ω~10 17 Ω is easy to generate static electricity, which is easy to cause explosion and fire. Improving the antistatic ability of PVC materials can broaden its application in chemical industry, coal mine, electronics and other fields. Using traditional processing methods, it is difficult for PVC to achieve a surface resistivity of 3.0×10 for a long time 8 Antistatic requirements of GB / T20105-2006 and coal mining industry MT164-2007,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L23/28C08L33/12C08L51/00C08L67/02C08K13/06C08K9/04C08K9/00C08K7/24C08K3/04C08K5/00C08K5/20C08K5/098B29C47/92B29C43/58B29C48/92
Inventor 李侃社张升炎汪晓芹牛红梅陈创前康洁李锦闫兰英梁耀东李树良朱雪丹
Owner XIAN UNIV OF SCI & TECH
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