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Silicon-based multi-junction tandem solar cell with flexible substrate and interlayer

A technology of solar cells and flexible substrates, applied in circuits, photovoltaic power generation, electrical components, etc., can solve problems such as limiting battery efficiency, no explanation or report found, wide band gap, etc., and achieve improved short-circuit current density and photoelectric conversion efficiency High and stable effect

Inactive Publication Date: 2013-02-20
SHANGHAI INST OF SPACE POWER SOURCES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the thin-film solar cells widely used at present, amorphous silicon thin-film materials are mainly used, but there are two important problems in amorphous silicon thin-film solar cells: (1) the light-induced degradation effect makes the battery stability not ideal; (2) The gap is wide, and the material itself does not fully absorb long-wave light in the solar radiation spectrum, which limits the further improvement of cell efficiency.
[0003] At present, there is no description or report of the similar technology of the present invention, and no similar data at home and abroad have been collected yet.

Method used

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  • Silicon-based multi-junction tandem solar cell with flexible substrate and interlayer
  • Silicon-based multi-junction tandem solar cell with flexible substrate and interlayer

Examples

Experimental program
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Effect test

Embodiment

[0023] Example Double-junction stack cell

[0024] A double-junction stack cell was fabricated on a polyimide substrate with a thickness of 75 μm according to the following steps:

[0025] In step 1, the Ag / ZnO back reflection electrode 12 is deposited on the polyimide substrate 11 by magnetron sputtering.

[0026] Step 2, using the plasma chemical vapor deposition (PECVD) method to deposit an amorphous silicon germanium bottom cell 13 with a NIP structure, wherein the reaction gas of the N layer of amorphous silicon is hydrogen, silane and phosphine, and the thickness is 10nm~50nm. The reaction gas of the crystalline silicon germanium layer is hydrogen, silane and germane, with a thickness of 150nm~400nm, and the reaction gas of the P layer nano silicon is hydrogen and silane, with a thickness of 10nm~50nm.

[0027] In step 3, the bottom battery 13 is taken out from the vacuum equipment, and placed in a dry cabinet (humidity lower than 30%) at room temperature for about 24 h...

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Abstract

The invention discloses a silicon-based multi-junction tandem solar cell with a flexible substrate and an interlayer. The solar cell comprises a metal foil or polyester film flexible substrate, a back reflector electrode, a microcrystalline silicon or amorphous silicon germanium bottom cell, an interlayer and an amorphous silicon top cell, which are sequentially arranged from bottom to top, and a top cell, wherein the top electrode is a transparent conductive thin film; and the interlayer is a transparent conductive thin film located between the top cell and the bottom cell, can reflect short-wavelength light with a wavelength smaller than 650nm to 700nm and can transmit long-wavelength light with a wavelength larger than 650nm to 700nm. The interlayer can reflect a portion of incident light originally entering the bottom cell to the top cell so as to increase the short-circuit current density of the top cell. The cell structure provided by the invention is good to improve the short-circuit current density of the silicon-based multi-junction tandem solar cell, thereby improving photoelectric conversion efficiency and stability of the cell.

Description

technical field [0001] The invention relates to a photovoltaic cell, in particular to a flexible substrate silicon-based multi-junction lamination thin film solar cell including an intermediate layer. Background technique [0002] In the thin-film solar cells widely used at present, amorphous silicon thin-film materials are mainly used, but there are two important problems in amorphous silicon thin-film solar cells: (1) the light-induced degradation effect makes the battery stability not ideal; (2) The gap is wide, and the material itself does not fully absorb long-wave light in the solar radiation spectrum, which limits the further improvement of cell efficiency. In order to solve these two problems, research work on amorphous silicon / microcrystalline silicon stacked solar cells and amorphous silicon / amorphous silicon germanium stacked solar cells has been widely carried out in recent years. The amorphous silicon (a-Si:H) material used for the top cell has a strong light-i...

Claims

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Application Information

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IPC IPC(8): H01L31/076H01L31/0376
CPCY02E10/50Y02E10/548
Inventor 徐正军刘成杨君昆
Owner SHANGHAI INST OF SPACE POWER SOURCES
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