A method for preparing high-purity aluminum hydroxide powder by electrochemical method
An aluminum hydroxide, high-purity technology, applied in the electrolysis process, electrolysis components and other directions, can solve the problems of high raw material preparation cost, difficult particle size, complicated process operation, etc., and achieves favorable environmental protection, simple preparation process, and strong scale benefit. Effect
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Embodiment 1
[0026] The preparation method of the high-purity aluminum hydroxide in this embodiment is carried out according to the following steps: surface-treating the high-purity aluminum plate, and purifying the electrolyte solution containing 200 g / L of choline chloride. The surface-treated high-purity aluminum plate is placed in the purified electrolyte as the cathode and anode at the same time, the pH is 7-8, and the current density is 3A / dm 2 , the temperature is 60°C, and the mechanical stirring gas supply volume is 800L / min. Electrolytic aluminum plate. When the precipitation content in the electrolyte reaches 28%, filter the bath to obtain aluminum hydroxide powder; wash the aluminum hydroxide powder, put it into a high-pressure container, and add high-purity water, seeds and filter cake weight 5% citric acid; under the conditions of 200°C and 12kg pressure, hydrothermal treatment was carried out at constant temperature for 6 hours; the amount of high-purity water was 4 times th...
Embodiment 2
[0029] The preparation method of the high-purity aluminum hydroxide of the present embodiment is carried out according to the following steps:
[0030] The high-purity aluminum plate is subjected to surface treatment, and the electrolyte solution containing 400 g / L of benzyltrimethylammonium chloride is purified. Put the surface-treated high-purity aluminum plate as the cathode and anode in the purified electrolyte at pH 8-10; current density 1A / dm 2 , the temperature is 40°C, and the mechanical stirring gas supply volume is 100L / min to electrolytic aluminum plate. When the precipitation content in the electrolyte reaches 15%, filter the bath to obtain aluminum hydroxide powder; wash the aluminum hydroxide powder, put it into a high-pressure container, and add high-purity water, crystal seeds and aluminum hydroxide powder 5% by weight of citric acid, at a temperature of 100 ° C and a pressure of 10 kg, the hydrothermal treatment was carried out at a constant temperature for 1...
Embodiment 3
[0033] The preparation method of the high-purity aluminum hydroxide of the present embodiment is carried out according to the following steps:
[0034] The high-purity aluminum plate is subjected to surface treatment, and the electrolyte solution containing 400 g / L of benzyltriethylammonium chloride is purified. Put the surface-treated high-purity aluminum plate as the cathode and anode in the purified electrolyte at pH 8-10; current density 5A / dm 2 ; The temperature is 90 ℃; the electrolytic aluminum plate is under the condition of air stirring and air supply of 1000L / min. When the content of aluminum hydroxide powder in the electrolyte reaches 30%, filter the bath to obtain aluminum hydroxide powder; wash the aluminum hydroxide powder, put it into a high-pressure container, and add high-purity water, seed crystals and hydrogen 10% tartaric acid by weight of alumina powder, at a temperature of 300 ° C; under the condition of 87 kg pressure, hydrothermal treatment is carried ...
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