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Absorption and hydration coupling device and method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas

An ethylene cracking and catalytic cracking technology, applied in the ethane combined plant, chemical industry, and ethylene fields, can solve the problems of low concentration separation, such as uneconomical economy, and achieve high efficiency separation, improved purity and yield, and reduced energy grade. Effect

Inactive Publication Date: 2013-04-10
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional absorption separation method achieves separation through the difference in the distribution coefficient of the gas in the gas-liquid two-phase, but in practical applications, when the concentration of C2 in the gas phase is low, due to the influence of the equilibrium relationship, it is necessary to use a large amount of absorbent, so low concentration Separation doesn't make sense

Method used

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  • Absorption and hydration coupling device and method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas
  • Absorption and hydration coupling device and method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas
  • Absorption and hydration coupling device and method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas

Examples

Experimental program
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Effect test

Embodiment 1

[0029] The molar composition of the feed gas is 25.64%N2+39.68%CH4+18.32%C2H4+16.36%C2H6, the mass flow rate is 10000kg / h, and the feed temperature is 20℃. In the absorption process, the circulating amount of n-pentane used by the absorbent is 46605kg / h, and 1894kg / h of n-pentane is supplemented per hour. Pure water is used in the hydration separation process, and the gas-liquid ratio is 140:1 under standard conditions.

[0030] The heat exchanger B2 heats the streams 2, 6, and 8 to 35°C. The temperature of the balance tank B3 is 35℃ and the pressure is 3MPa. The absorption tower B4 is operated at 3MPa, 10 trays, an intermediate condenser is set between the 3rd and 4th trays, the liquid phase temperature is set to 35℃, and the temperature of the top absorbent It is 35°C. The desorption tower B5 has an operating pressure of 3MPa and a bottom temperature of 143.6°C. An intermediate reboiler is set between the 5th and 6th trays with a temperature of 85°C and a pressure of 3MPa. A...

Embodiment 2

[0035] The molar composition of the feed gas is 25.64%N2+39.68%CH4+18.32%C2H4+16.36%C2H6, the mass flow rate is 10000kg / h, and the feed temperature is 20℃. In the absorption process, a mixed solvent of n-butane and n-pentane is used as the absorbent, and the circulation amount is 23198.84 kg / h, supplemented with n-butane 281.14 kg / h, and supplemented with n-pentane 432.91 kg / h. Pure water is used in the hydration separation process, and the gas-liquid ratio is 140:1 under standard conditions.

[0036] The heat exchanger B2 heats the streams 2, 6, and 8 to -30°C. The temperature of the balance tank B3 is -30℃ and the pressure is 2MPa. The absorption tower B4 is operated at 2MPa, with 10 trays, an intermediate condenser is set between the 3rd and 4th trays, the liquid phase temperature is set to -30℃, and the top absorption The temperature of the agent is -30°C. The desorption tower B5 has an operating pressure of 2MPa and a bottom temperature of 49.2°C. Absorbent regeneration t...

Embodiment 3

[0041] The molar composition of the feed gas is 25.64%N2+39.68%CH4+18.32%C2H4+16.36%C2H6, the mass flow rate is 10000kg / h, and the feed temperature is 20℃. In the absorption process, a mixed solvent of n-butane and n-pentane is used as the absorbent. The circulation amount is 24348.69 kg / h, supplemented with n-butane 328.16 kg / h, and supplemented with n-pentane 603.73 kg / h. Pure water is used in the hydration separation process, and the gas-liquid ratio is 140:1 under standard conditions.

[0042] The heat exchanger B2 heats the streams 2, 6, and 8 to 0°C. The temperature of the balance tank B3 is 0℃ and the pressure is 4MPa. The absorption tower B4 is operated at 4MPa, 10 trays, an intermediate condenser is set between the 3rd and 4th trays, the liquid phase temperature is set to 0℃, and the temperature of the top absorbent It is 0°C. The desorption tower B5 has an operating pressure of 4MPa and a bottom temperature of 118.3°C. Absorbent regeneration tower B6 has an operating...

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Abstract

The invention provides an absorption and hydration coupling device and a method for separating ethylene and ethane in catalytic cracking dry gas or ethylene pyrolysis gas. The method is divided into two processes: the catalytic dry gas or the ethylene pyrolysis gas enters an absorption separation process; a high-purity C2 product is obtained through absorption, desorption and absorbent regeneration; C2 lean gas at the top of an absorption tower enters a hydration separation process; and then C2 gas recovered in hydration separation and virgin gas are merged and return to the absorption separation process. The absorption separation process and the hydrate separation process are combined; the advantages that the separation efficiency of an absorption method in a high concentration area is high, and the separation efficiency of a hydration separation method in a low concentration area is high are exerted; the solvent amount required by the absorption process is reduced; the defects that the hydration separation purity is not high and the separation efficiency is low are avoided; the purity of the obtained C2 product can reach 99.6%; and the C2 product can directly enter an ethylene tower. The method is suitable for separating the recovered C2 from the catalytic cracking dry gas or the ethylene pyrolysis gas, and is hopeful for substituting a cryogenic separation technology.

Description

Technical field [0001] The invention relates to a combined device and method for separating and recovering ethylene and ethane in catalytic dry gas or ethylene cracking gas by combining an absorption separation process and a hydration separation process, and belongs to chemical technology. Background technique [0002] As the core of oil refining technology, catalytic cracking plays an important role in the deep processing of crude oil, and it is also one of the biggest benefit devices of oil refining enterprises. The liquefied gas produced by the catalytic cracking unit is recycled through the gas separation unit to recover propylene, which has also brought very good benefits to many oil refineries. However, the dry gas, which is a by-product of the catalytic device, has not been paid much attention to at present and is usually used as a fuel. However, the catalytic dry gas contains higher value-added ethylene, if it can be properly recovered, it will be another bright spot for...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C11/04C07C9/06C07C7/00C07C7/11C10G70/06
CPCY02P30/464Y02P30/40
Inventor 李鑫钢陈超辛峰李永红丁辉史荣会
Owner TIANJIN UNIV
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