Polishing solution for TSV barrier layer
A technology of polishing liquid and barrier layer, applied in the field of polishing liquid, to achieve the effect of clear and sharp thin line area, good planarization efficiency and good corrosion resistance
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[0029] The advantages of the present invention will be further elaborated below through specific embodiments.
[0030] Polishing conditions:
[0031] Polishing pad: IC pad
[0032] Polishing conditions: 70 / 90rpm
[0033] Polishing fluid flow: 100ml / min
[0034] Static corrosion rate: Put the freshly polished copper sheet into the slurry and immerse it for 15 minutes, and measure the film thickness before and after.
[0035] Butterfly Depression: A Semitech 854 patterned wafer was used to measure the butterfly depression of an 80um metal block.
[0036] Polishing Uniformity Within Slice: Butterfly dips for different line widths within a die.
[0037] Blank Wafer: PETEOS, Ta, Cu, Si3N4
[0038] Table 1, the formula of embodiment 1-7 and contrast polishing liquid
[0039]
[0040]
[0041] BTA: benzotriazole, PAA: polyacrylic acid, PBTCA: 2-phosphonic acid-1,2,4-tricarboxylic butane. DISN1, disodium methylene bis-naphthalenesulfonate, DISN2: methylnaphthalenesulfonat...
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