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Environment-friendly nanoscale bottom infiltrated layer material used for protecting concrete surface and preparation method of environment-friendly nanoscale bottom infiltrated layer material

An environmentally friendly concrete, nano-level technology, applied in the field of concrete protection, can solve the problems of inability to bond the concrete base surface firmly, increase the process, and cannot protect the protective effect of the protective layer, etc., to achieve excellent resistance to chloride ion erosion, good penetration and anchoring effect. , the effect of excellent protective effect

Active Publication Date: 2015-02-11
CCCC CIVIL ENG SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The concrete protection system generally consists of a bottom seepage layer and a protective layer. The existing bottom seepage layer materials mainly have the following disadvantages: First, the permeability is poor. The domestic similar products can only penetrate 1~3mm into the concrete, and cannot penetrate into the concrete for a certain period of time. The second is that the bonding performance is poor, and the adhesion to the concrete surface is less than the specification requirement (the specification requirement ≥ 1MPa), and it cannot be firmly bonded to the concrete base surface; the third is that the anti-carbonization effect is poor, and the carbonation depth is generally greater than the specification requirement (the specification requirement ≤1mm), unable to cooperate with the surface protective layer to play a protective effect; Fourth, the anti-chloride ion penetration is poor, and the anti-chloride ion permeability is generally greater than the specification requirements (standard requirements -12 m 2 / s), unable to effectively prevent chloride ions from intruding into the concrete; fifth, poor environmental protection, most of the domestic similar products contain VOC, polluting the environment; sixth, the painting process is complicated, domestic similar products need to be coated on the concrete base before use Primer, increase process, increase cost

Method used

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  • Environment-friendly nanoscale bottom infiltrated layer material used for protecting concrete surface and preparation method of environment-friendly nanoscale bottom infiltrated layer material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Step 1: Weigh 75 parts by weight of inorganic nano-silica solution, heat it to 55°C, and keep it warm;

[0046] Step 2: Mix 2 parts by weight of styrene-acrylic emulsion and 2 parts by weight of pure acrylic emulsion, stir until uniform, add to the solution in step 1, stir at a constant temperature for 30 minutes at a speed of 500r / min, and add 4 parts by weight while stirring The γ-aminopropyltriethoxysilane and the isobutyltriethoxysilane of 3 weight parts, the gained solution temperature is down to room temperature;

[0047] Step 3: Add 1 part of sodium metaphosphate and 1 part of tributyl phosphate into the solution obtained in step 2, and stir at a constant temperature for 15 minutes at a speed of 3000 r / min;

[0048] Step 4: Add 2 parts of butyl silicate to the solution obtained in Step 3, stir at a constant temperature at a speed of 500 r / min for 15 minutes, and let it stand for 10 minutes to obtain the bottom seepage layer material.

[0049] In step 1, the soli...

Embodiment 2

[0053]Step 1: Weigh 75 parts by weight of inorganic nano-silica solution, heat it to 55°C, and keep it warm;

[0054] Step 2: Mix 2 parts by weight of styrene-acrylic emulsion and 2 parts by weight of pure acrylic emulsion, stir until uniform, add to the solution in step 1, stir at a constant temperature for 30 minutes at a speed of 500r / min, and add 4 parts by weight while stirring The γ-aminopropyltriethoxysilane and the isobutyltriethoxysilane of 3 weight parts, the gained solution temperature is down to room temperature;

[0055] Step 3: Add 1 part of sodium metaphosphate and 1 part of tributyl phosphate into the solution obtained in step 2, and stir at a constant temperature for 15 minutes at a speed of 3000 r / min;

[0056] Step 4: Add 2 parts of butyl acetate into the solution obtained in Step 3, stir at a constant temperature at a speed of 500 r / min for 15 minutes, and let it stand for 10 minutes to obtain the material of the bottom seepage layer.

[0057] In step 1, t...

Embodiment 3

[0061] Step 1: Weigh 80 parts by weight of inorganic nano-silica solution, heat to 60°C, and keep warm;

[0062] Step 2: Mix 2 parts by weight of styrene-acrylic emulsion and 2 parts by weight of pure acrylic emulsion, stir until uniform, add to the solution in step 1, stir at a constant temperature for 30 minutes at a speed of 500r / min, and add 5 parts by weight while stirring The γ-aminopropyltriethoxysilane and the isobutyltriethoxysilane of 4 weight parts, the gained solution temperature is down to room temperature;

[0063] Step 3: Add 1 part of sodium metaphosphate and 1 part of tributyl phosphate into the solution obtained in step 2, and stir at a constant temperature for 15 minutes at a speed of 3000 r / min;

[0064] Step 4: Add 3 parts of sodium methyl silicate to the solution obtained in Step 3, stir at a constant temperature at a speed of 500 r / min for 15 minutes, and let stand for 10 minutes to obtain the bottom seepage layer material.

[0065] In step 1, the solid...

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Abstract

The invention relates to an environment-friendly nanoscale bottom infiltrated layer material used for protecting a concrete surface and a preparation method of the environment-friendly nanoscale bottom infiltrated layer material. A conventional infiltrated layer material used for protecting the concrete surface is extremely poor in permeability, can not guarantee the firm bonding with a concrete base, and is easy to fall off from the concrete surface under the action of external erosion conditions. The invention provides the nanoscale bottom infiltrated layer material which is prepared from an inorganic nano silicon dioxide solution, styrene-acrylic emulsion, pure acrylic emulsion, gamma-aminopropyl triethoxy silane, isobutyl triethoxy silane, sodium metaphosphate, tributyl phosphate and one of tetrabutyl orthosilicate, butyl acetate, sodium methyl silicate, acrylate and ethyl acetate. The environment-friendly nanoscale bottom infiltrated layer material can quickly infiltrate into concrete by certain depth and react with a concrete base material to seal pores inside the concrete, is good in bonding performance with a surface protective layer material, and can ensure the firm bonding between a concrete protective system and the concrete surface under the action of an outside environment and delay the occurrence of concrete diseases.

Description

technical field [0001] The invention belongs to the technical field of concrete protection, and in particular relates to an environment-friendly nano-level underseeding layer material for concrete surface protection and a preparation method thereof. Background technique [0002] Concrete is a widely used building material with excellent durability, but in the general atmospheric environment (carbon dioxide, water, oxygen, etc.) and winter deicing salt environment, due to the long-term erosion of carbon dioxide and chloride ions and its own performance defects (pore , micro-cracks, etc.), there will be concrete carbonation corrosion, chloride ion diffusion corrosion and other phenomena, and directly lead to the occurrence of internal steel corrosion, which will lead to a series of diseases such as concrete spalling, rust swelling cracks, etc., which seriously restrict the concrete structure. Use durability and use safety. As a protective measure, painting the protectiv...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B41/50
Inventor 葛胜锦王佐潘长平高山翟敏刚盖卫鹏吕晓霞赵秋华汪明天李翔齐菲贺鹏邹顺于成云
Owner CCCC CIVIL ENG SCI & TECH
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