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Preparation method of high alkaline shale sintered brick

A high-alkali shale and sintered brick technology, which is applied in the field of building wall materials, can solve the problems of frost back, increased surface area, hollow bulge, etc., and achieves the effects of good anti-frost effect, improved service life, simple and stable process

Inactive Publication Date: 2013-10-09
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] my country's shale brick production began in the 1960s and 1970s. First, a number of brick factories were built in Sichuan and Guizhou, and then Liuzhou, Baise, and Guilin in Guangxi also successively built a number of brick factories. In the 1980s and 1990s, Jiangsu Shale brick factories have also been built in China, Zhejiang, Lianghu, Guangdong, Shandong, Shanxi, Northeast China, Tianjin and other places; however, some new problems have also appeared in the process of using shale to make bricks, such as: The problem of frosting of sintered bricks due to excessive high temperature has seriously affected the application and promotion of shale sintered bricks. Especially under the new requirements of energy saving and emission reduction, shale sintered bricks are gradually developing towards porous and hollow. As the surface area increases, the phenomenon of frost return is more serious. Generally speaking, the sealing effect is mainly adopted in the construction stage to reduce the problem of frost return in the actual use process. However, due to the high alkali content of some shales, hollowing still exists during use. , Various quality problems of cracking

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] K first 2 O content is 1% and Na 2 O2% high-alkali shale is crushed to 0.125mm-0.25mm, add coal powder of 0.125mm-0.25mm and stir in hot water at 60°C for 10 minutes, enter the aging warehouse for 48 hours, and extrude in the extruder Forming, the green body obtained after forming is in the waste heat environment provided by the sintering kiln (the CO containing CO provided by the kiln exhaust gas of the conventional process 2 or CO 2 with SO 3 The high-temperature gas, the same below), is cured for 20 hours at a humidity of 100% and a temperature of 300°C for 20 hours, and then after 8 hours in an environment with a humidity of 20% and a temperature of 250°C, it is cooled to room temperature and calcined in a conventional tunnel kiln. The calcination temperature is 1080-1200°C (30-50°C higher than the existing calcination temperature), and the sintering time is 7-13h (1-3h longer than the existing sintering time), which can meet the requirements of slight frost retu...

Embodiment 2

[0019] K first 2 O content is 3% and Na 2 O2% high-alkali shale is crushed to 0.125mm-0.25mm, add coal powder of 0.125mm-0.25mm and stir in hot water at 80°C for 10 minutes, enter the aging warehouse for 20 hours, and extrude in the extruder Forming, the green body obtained after forming is cured in the waste heat environment provided by the sintering kiln with a humidity of 80% and a temperature of 200°C for 48 hours, and then in an environment with a humidity of 0% and a temperature of 250°C for 9 hours, and then cooled to room temperature. Carry out calcination in a conventional wheel kiln, the calcination temperature is 1080-1200°C (30-50°C higher than the existing calcination temperature), and the sintering time is 7-13h (1-3h longer than the existing sintering time), which can be satisfied Sintered shale bricks required for slight frost return in GB T2542.

Embodiment 3

[0021] K first 2 O content is 2.5% and Na 2 O1% high-alkali shale is crushed to 0.125mm-0.25mm, add coal powder of 0.125mm-0.25mm and stir in hot water at 80°C for 10 minutes, enter the aging warehouse for 30 hours, and extrude in the extruder Forming, the green body obtained after forming is cured in the waste heat environment provided by the sintering kiln with a humidity of 90% and a temperature of 250°C for 36 hours, in an environment with a humidity of 10% and a temperature of 250°C for 10 hours, and then cooled to room temperature. Calcination is carried out in a conventional wheel kiln, the calcination temperature is 1080-1200°C (30-50°C higher than the existing calcination temperature), and the sintering time is 7-13h (1-3h longer than the existing sintering time), which can meet the GB Sintered shale bricks required for slight frost return in T2542.

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PUM

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Abstract

The invention specifically relates to a preparation method of a high alkaline shale sintered brick. The preparation method comprises the following steps of: first, crushing aired high alkaline shale; adding pulverized coal with same fineness and stirring for 10-60 minutes at 60-80 DEG C; aging for 20-48 hours in an aging storeroom; extruding and forming in an extruder; maintaining a blank formed; and drying and sintering to obtain the anti-frost return shale sintered brick. The method provided by the invention has the advantages of simple process and good anti-frost return effect. The method further has the advantages that 1) no extra additives are added into a proportioning system, so that the process is concise and stable; 2) the blank used in high temperature and high humidity and acidic atmosphere on the one hand can reduce emission of harmful gases, and on the other hand, can use inferior sulphur coal, so that the application path of inferior resources in the field is expanded; and 3) a molten compact structure is formed on the surface through an eutectic evaporative substance, so that the channels through which harmful ions enter can be reduced, and therefore, the service life of the product can be prolonged, and the sintered brick has a certain decorative effect.

Description

technical field [0001] The invention specifically relates to a method for preparing high-alkali shale sintered bricks, which are mainly used as building wall materials. Background technique [0002] Sintered bricks or blocks have the characteristics of good chemical stability, convenient construction and low price. They are widely used in urban and rural construction in my country. Among them, fired clay bricks are used in the largest amount. The destruction of land reached more than 1.5 million mu, which seriously threatened the red line of guaranteeing 1.8 billion mu of arable land in our country. With the further implementation of the wall reform policy, shale has become the main raw material to replace clay, and together with coal gangue, fly ash, and river silt, it has become the four major new wall material raw materials. [0003] my country's shale brick production began in the 1960s and 1970s. First, a number of brick factories were built in Sichuan and Guizhou, and ...

Claims

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Application Information

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IPC IPC(8): C04B30/00B28B11/24
Inventor 蹇守卫孔维周浩汪婷郅真真蔡礼雄王智陈露
Owner WUHAN UNIV OF TECH
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