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Preparation method of carbide strengthening heat-resistant steel matrix composite

A composite material and carbide technology, applied in the field of steel matrix composite materials, can solve problems such as unfavorable industrial production, inability to coat for long-term service work, small coating thickness, etc., and achieve the effect of excellent high temperature oxidation resistance.

Inactive Publication Date: 2013-12-11
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the coating process formed is relatively simple, due to the small thickness of the coating, the coating cannot be used for a long time, which is not conducive to industrial production

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Cr 3 C 2 Carbide (particle size: 75-95um), after adding 0.1% methanol process control agent by powder weight, ball milled for 50 hours to make the particle size 3-10um, and put it in a tank filled with argon for storage. Determine the chemical composition of austenitic heat-resistant steel (C: 0.58%; Si: 1.8%; Mn: 1.8%; Mo: 0.5%; S≤0.03%; P≤0.03%; Ni: 35%; Fe: the rest), Calculate and weigh the raw materials (scrap steel, pure nickel, ferromolybdenum, ferromanganese, ferrosilicon), and melt them sequentially in an electric furnace to 1500°C, then carry out slag removal, deoxidize with aluminum wire, and keep warm for 3 minutes. Put the molten steel out of the furnace and then pour it into the electric furnace. After continuing to heat up to 1500 ° C, carry out slag removal again, use aluminum wire to deoxidize and keep it warm for 1 minute. At this time, Cr 3 C 2 The powder (accounting for about 5% of the weight of molten steel) is poured and spread on the bottom of ...

Embodiment 2

[0023] The self-prepared Cr 7 C 3 Carbide powder (particle size: 55-75um), after adding 0.1% methanol process control agent by powder weight, ball milled for 30 hours to make the particle size 2-9um, and put it into a tank filled with argon for storage. Determine the chemical composition of austenitic heat-resistant steel (C: 0.58%; Si: 1.8%; Mn: 1.8%; Mo: 0.5%; S≤0.03%; P≤0.03%; Ni: 35%; Fe: the rest), Calculate and weigh the raw materials (scrap steel, pure nickel, ferromolybdenum, ferromanganese, ferrosilicon), and melt them sequentially in an electric furnace to 1500°C, then carry out slag removal, deoxidize with aluminum wire, and keep warm for 3 minutes. Put the molten steel out of the furnace and then pour it into the electric furnace. After continuing to heat up to 1500 ° C, carry out slag removal again, use aluminum wire to deoxidize and keep it warm for 1 minute. At this time, Cr 7 C 3 The powder (accounting for about 5% of the weight of molten steel) is poured an...

Embodiment 3

[0026] The self-prepared Cr 23 C 6 Carbide powder (particle size: 40-75um), after adding 0.1% methanol process control agent by powder weight, ball milled for 20 hours to make the particle size 3-9um, and put it into a tank filled with argon for storage. Determine the chemical composition of austenitic heat-resistant steel (C: 0.58%; Si: 1.8%; Mn: 1.8%; Mo: 0.5%; S≤0.03; P≤0.03; Ni: 35%; Fe: the rest), calculate and Raw materials (scrap steel, pure nickel, ferromolybdenum, ferromanganese, ferrosilicon) are weighed, and when they are melted in an electric furnace to 1500°C, the slag is removed, deoxidized by aluminum wire, and then kept for 3 minutes. Put the molten steel out of the furnace and then pour it into the electric furnace. After continuing to heat up to 1500 ° C, carry out slag removal again, use aluminum wire to deoxidize and keep it warm for 1 minute. At this time, Cr 23 C 6 The powder (accounting for about 5% of the weight of molten steel) is poured and spread ...

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Abstract

The invention discloses a preparation method of a carbide strengthening heat-resistant steel matrix composite, which comprises the steps that Cr3C2, Cr7C3 or Cr23C6 powder is subjected to appropriate ball milling treatment to form powder with a certain scale; the Cr3C2, Cr7C3 or Cr23C6 powder is spread at the bottom of a pouring ladle before pouring of heat-resistant molten steel; then the molten steel is poured in and subjected to pouring forming immediately and quickly; and the composite with Cr3C2, Cr7C3 or Cr23C6 dispersedly distributed in heat-resistant steel is obtained. The carbide strengthening heat-resistant steel matrix composite obtained by a preparation technology of the preparation method can be applied to heat-resistant components in a high-temperature oxidation atmosphere, such as a heat exchanger U-shaped pipe of a generator in a nuclear power unit, and products corroded by a high-temperature-resistant atmosphere such as critical and ultra-supercritical large power generation equipment key components (such as a high-medium pressure rotor, a high-temperature section blade, a steam pipeline, a finishing superheater and a reheater) and an ethylene cracking furnace pipe.

Description

technical field [0001] The invention belongs to the technical field of steel-based composite materials, and relates to a method for preparing a steel-based composite material, in particular to a method for preparing a carbide-reinforced heat-resistant steel-based composite material. Background technique [0002] Cr 3 C 2 、Cr 7 C 3 and Cr 23 C 6 Type carbides have excellent high temperature oxidation resistance. In addition to the natural formation of reticular or high-continuity carbide phases of steel materials mainly through the regulation and addition of alloy raw materials and the use of smelting and solidification casting methods, there are also methods such as surface spraying on the surface of steel. In a thin layer of wear-resistant, corrosion-resistant coating,. Although the formed coating process is relatively simple, due to the small thickness of the coating, the coating cannot be used for a long time, which is not conducive to industrial production. Cr 3...

Claims

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Application Information

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IPC IPC(8): C22C38/00C22C33/04
Inventor 皇志富高义民邢建东马胜强李烨飞符寒光
Owner XI AN JIAOTONG UNIV