Method and system for preparing high-purity lithium carbonate

A preparation system, lithium carbonate technology, applied in lithium carbonate;/acid carbonate, general water supply saving, energy input and other directions, can solve the problems of energy, fresh water shortage, low efficiency, large influence of natural conditions, etc. To achieve the effect of reducing ecological problems, easy to use, and high energy efficiency

Active Publication Date: 2015-06-24
TIBET JINRUI ASSET MANAGEMENT +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006]1. It is necessary to build a large area of ​​salt pan, and the construction cost and later maintenance cost are quite high; at the same time, artificially increased the additional production of the salt lake, destroying the liquid level balance of the salt lake, which may Affect the ecology of the salt lake area;
[0007]2. It is greatly affected by natural conditions;
[0008]3. The prepared lithium salt has low purity and many impurities, and needs to be transported to the factory for further processing; thus, the transportation cost is very high; and most of them are transported impurities "Useless carriage";
[0009]4. It takes a long time to make salt; the process cannot be automated and the efficiency is low
[0010]In addition, the existing salt lakes are basically located in remote areas, with inconvenient transportation, lack of energy and fresh water, which further increases the difficulty of purification

Method used

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  • Method and system for preparing high-purity lithium carbonate
  • Method and system for preparing high-purity lithium carbonate

Examples

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preparation example Construction

[0040] The preparation method of high-purity lithium carbonate comprises the steps:

[0041] 1) Concentrate the carbonated salt lake brine, then raise the temperature to precipitate lithium carbonate saturated crystals, collect the crystals to obtain lithium carbonate refined salt;

[0042] 2) Rinse the collected lithium carbonate fine salt with the distilled water recovered when the brine is evaporated and concentrated above 60°C, and dissolve the sodium potassium salt therein;

[0043] 3) drying to obtain high-purity lithium carbonate.

[0044] Preferably, the salt lake brine is concentrated by evaporation under reduced pressure, and then the temperature is raised to above 60°C, preferably above 65°C or 70°C to precipitate lithium carbonate crystals. The higher the crystallization temperature, the more conducive to the precipitation of higher-purity lithium carbonate refined salt, which is conducive to reducing the difficulty of subsequent purification operations.

[0045]...

Embodiment 1

[0058] Li ion concentration 1.29g / L brine, above 60°C crystallization precipitates coarse lithium salt and brine mixed wet salt, simply removes the supernatant and weighs 897.6g, mixes with 80°C distilled water 3000g at one time and fully stirs for 3 minutes, after Suction filtration and oven dry, obtain the lithium carbonate 47.4g that purity is 62%, obtain lithium carbonate yield from thick lithium salt and be 73.5%.

Embodiment 2

[0060] Li ion concentration 1.29g / L brine, above 60°C crystallizes and precipitates coarse lithium salt and brine mixed wet salt, simply removes the supernatant and weighs 877.9g, uses 70°C distilled water 2250g, respectively 1200g, 600g, 300g, 150g A total of 4 times were rinsed in the manner of Example 1, and each fully stirred for 30 seconds for a total of 2 minutes. After suction filtration and drying, the dry purity obtained was 91.3% Lithium Retard 37.56g, and Lithium Retard yield was obtained from the thick lithium salt. was 85.7%.

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Abstract

The present invention disclosed the preparation method and system of high -purity lithium carbonate.The preparation method of high -purity lithium carbonate, including the following steps: condense carbonate salt lake brine, then heat up the crystallization of the carbonate, collect crystallization to get lithium carbonate salt;Lithium carbonate refined salt, dissolved in the sodium and potassium salt;The invention process does not need to use chemical reagents. It can complete the purity of lithium carbonate through physical operations. The purity of lithium carbonate is as high as 95%or more, which will help reduce the cost of later transportation to further purify the cost.The invention technology has extremely low requirements for transportation and does not pollute the environment.

Description

technical field [0001] The invention relates to a process and system for purifying lithium carbonate. Background technique [0002] Due to its strong electrochemical activity and being a light metal, lithium has a wide range of uses. At present, the application fields of lithium include: ceramics and glass, synthetic rubber, aluminum production, plastics, pharmaceuticals, lubricants, air conditioners, televisions (fluorescent screens), lithium batteries, lithium alloys and nuclear industry, etc.; consumption reaches tens of thousands of tons per year , and still growing. [0003] In the world's total lithium resources, brine lithium ore accounts for about 75%, and hard rock lithium ore accounts for 25%. In my country's total lithium resources, brine lithium ore accounts for about 72%, and hard rock lithium ore accounts for 28%. Before the 1960s, lithium resources mainly came from hard salt lithium ore. The cost of extracting lithium from salt lakes is 1-1.5 times lower th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01D15/08
CPCY02A20/212Y02P20/129
Inventor 朱彬元余昊
Owner TIBET JINRUI ASSET MANAGEMENT
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