Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of light hydrocarbon oil catalytic conversion method

A catalytic conversion method and a technology for hydrocarbon oil are applied in the field of catalytic conversion of light hydrocarbon oil to produce low-carbon olefins, which can solve the problems of rapid deactivation of catalysts, difficulty in realizing high temperature reaction, and high conversion rate of cracking reaction, and can solve the problems of petrochemical raw materials. The effect of shortage, reducing the total surface area of ​​heat dissipation, and improving the yield of light olefins

Active Publication Date: 2015-07-29
CHINA PETROLEUM & CHEM CORP +1
View PDF13 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] CN102040438A proposes a coaxial embedded riser reaction-regeneration device, which aims to solve the problem that it is difficult to achieve high-temperature reaction when using a riser reactor for cyclic reaction-regeneration in the existing light oil / light hydrocarbon catalytic cracking process, The device adopts the technical scheme that the main reaction zone of the riser reactor is located inside the regenerator, and the settler, stripper and riser reactor are located on the same axis, making full use of the heat of the regenerator
[0011] CN101134160A proposes a reaction device for the production of low-carbon olefins by catalytic cracking, using the high-temperature regeneration flue gas of the catalytic cracking device as a heat source, and using light oil products such as naphtha as raw materials to carry out catalytic cracking reactions to produce low-carbon olefins. Due to the use of tubular reactors, it is difficult to solve the problem of rapid catalyst deactivation for highly active molecular sieve catalysts
[0012] Due to the high conversion rate of the cracking reaction of the catalytic cracking process, the high reaction temperature, and the high heat of the cracking reaction, compared with conventional catalytic cracking or other catalytic conversion methods, the heat required for the reaction is more, and the coke generated by its own cracking often cannot meet the requirements of the reaction. - Requirements for heat balance of the regenerative system itself

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of light hydrocarbon oil catalytic conversion method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0106] This embodiment is tested according to the flow process of the accompanying drawing, using straight-run naphtha as raw material, the test is carried out on the medium-sized device of the riser reactor, the preheated raw material oil enters the bottom of the riser, and at a reaction temperature of 675 ° C and a reaction time 2 seconds, the weight ratio of the catalytic cracking catalyst to the raw oil is 25, and the weight ratio of the water vapor to the raw oil is 0.55 to carry out the cracking reaction, and the reaction product, water vapor and the raw catalyst enter the closed cyclone from the reactor outlet, The reaction product and the catalyst are quickly separated, and the reaction product is cut according to the distillation range in the separation system after exchanging heat with the raw material, so as to obtain fractions such as dry gas, propylene, C4 and gasoline. The spent catalyst enters the regenerator under the action of gravity and contacts with air for ...

Embodiment 2

[0109] Using the reaction device, test method and raw materials of Example 1, the difference is that the reaction product oil gas is cut according to the distillation range through the separation system to obtain fractions such as dry gas, propylene, C4 and gasoline, wherein C4 returns to the reactor for further cracking For ethylene and propylene. The operating conditions and product distribution are listed in Table 2.

[0110] It can be seen from Table 2 that the yield of ethylene can reach 25.73% by weight, the yield of propylene can reach 27.68% by weight, and the ratio of propylene / ethylene is about 1.08.

[0111] Table 1

[0112] Raw oil properties

Density (20℃), g / cm 3

0.7358

Vapor pressure / kPa

50.0

Family composition / weight%

Paraffins

51.01

Naphthenic

38.24

Olefin

0.12

Aromatics

10.52

Distillation range, ℃

IBP

46

10%

87

...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention provides a light hydrocarbon oil catalytic conversion method. The method comprises the steps that a light hydrocarbon oil raw material enters a catalytic cracker to undergo a catalytic cracking reaction, generated reaction oil and gas are separated to obtain low carbon olefin and a spent catalyst is recycled after being regenerated, wherein the catalytic cracker comprises a regenerator (2), a riser reactor (1), a closed hood (3), a cyclone separator (5) and a regeneration standpipe (9); the closed hood (3) is arranged outside an outlet of the riser reactor and is communicated with an inlet of the cyclone separator (5) via an outlet in the top; a catalyst outlet of the cyclone separator (5) is communicated with the regenerator; the bottom of the closed hood (3) is communicated with the regenerator (2); the riser reactor (1), the closed hood (3), the cyclone separator (5) and the regeneration standpipe (9) are arranged in the regenerator (2). The method provided by the invention has the beneficial effects of reducing the total radiating surface area of a reaction regeneration system, reducing the radiation energy consumption of the reactor and solving the problem of insufficient heat caused by insufficiency of cokes generated by cracking of light petroleum hydrocarbon.

Description

technical field [0001] The invention relates to a method for catalytic conversion of hydrocarbon oil in the absence of hydrogen, in particular to a method for catalytic conversion of light hydrocarbon oil to produce light olefins. Background technique [0002] As important basic organic raw materials for petrochemical industry, ethylene and propylene play a pivotal role in the petrochemical industry. In the production technology of hydrocarbon cracking to produce ethylene and propylene, tube furnace thermal cracking method accounts for the largest share of the world's ethylene and propylene production. Dominant, more than 98% of ethylene and 67% of propylene come from tube furnace cracking technology. With the increase of demand for propylene derivatives, the yield of propylene produced by thermal cracking can no longer meet the growing demand for propylene in the domestic and foreign markets. In the past 10 years, the growth rate of world propylene demand has been higher th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C10G11/14
Inventor 魏晓丽毛安国张久顺袁起民白风宇
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products