Absorption solution for removing sulfides and carbon dioxide from natural gas
A technology of carbon dioxide and absorbing liquid, applied in gas fuel, chemical instruments and methods, petroleum industry, etc., can solve the problems of expensive solvent, can not meet the purification effect, etc., achieve low price, low regeneration energy consumption, good stability Effect
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Embodiment 1
[0015] The composition of the absorption liquid: 2-amino-2-methyl-1-propanol 15% (wt), MMEA 20% (wt), N-methylacetamide 20% (wt), sodium carbonate 2% (wt), remaining deionized water. Raw natural gas composition (molar ratio): CO 2 14%, H 2 S 3%, sulfide 389 mg / m 3 , Mercaptan 421 mg / m 3 , COS 401 mg / m 3 , the remaining N 2 , Absorbed at 40°C under normal pressure. Purge gas: H 2 S 19 mg / m 3 , CO 2 3.0%, sulfide removal rate: 71.2%, mercaptan removal rate: 87.1%, COS removal rate: 93.4%.
Embodiment 2
[0017] The composition of the absorption solution: 10% (wt) of piperazine and 2-piperidine ethanol, 40% (wt) of MDEA, 14% (wt) of N-methylacetamide, 1% (wt) of sodium carbonate, and the rest deionized water. Raw natural gas composition (molar ratio): CO 2 15%, H 2 S 3.5%, sulfide 377 mg / m 3 , Mercaptan 408mg / m 3 、COS 381mg / m 3 , the remaining N 2 , Absorbed at 40°C under normal pressure. purge gas H 2 S 2 mg / m 3 , CO 2 2.5%, sulfide removal rate: 91%, mercaptan removal rate: 90.2%, COS removal rate: 84.4%.
Embodiment 3
[0019] The composition of the absorption liquid: tert-butylaminodiethanolamine 60% (wt), DEA 20% (wt), N-methylacetamide 10% (wt), potassium carbonate 0.5% (wt), the rest deionized water. Raw natural gas composition (molar ratio): CO 2 13%, H 2 S 2.4%, sulfide 364 mg / m 3 , Thiol 376mg / m 3 、COS 355mg / m 3 , the remaining N 2 , Absorbed at 40°C under normal pressure. Purge gas: H 2 S 17 mg / m 3 , CO 2 2.7%, sulfide removal rate: 78.6%, mercaptan removal rate: 88.7%, COS removal rate: 79.4%.
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