Device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation

A catalytic cracking and gasoline technology, applied in hydrotreating process, petroleum industry, treatment of hydrocarbon oil, etc., can solve the problems that are not involved, increase energy consumption and equipment investment, and do not involve system coupling, etc.

Inactive Publication Date: 2014-02-12
CHINA UNIV OF PETROLEUM (EAST CHINA) +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, none of the above patents involves the olefin-reducing treatment of olefin-rich light gasoline, which makes heavy-distillate gasoline need to reach a certain olefin saturation rate in the hydrogenation process to make the final product gasoline meet the requirements of the latest gasoline standards
Another problem is that the above patents all cut the catalytic cracking stable gasoline, so the catalytic gasoline may have been cut twice, thereby increasing energy consumption and equipment investment
Patent CN101294108A proposes to separate light and heavy fractions of catalytic gasoline in the separation system of catalytic cracking products, and then carry out hydrofining of heavy fractions, but it does not involve the improvement of absorption-stabilization system flow and the treatment of light gasoline rich in olefins De-alkene upgrading does not involve the systematic coupling of the two processes of catalytic cracking and hydrofining

Method used

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  • Device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation
  • Device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation
  • Device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] Embodiment 1: Two-stage riser reactor

[0063] Such as figure 1 As shown, the unit of catalytic cracking and hydrofinishing combined to produce clean gasoline and increase the production of propylene provided in this example includes a reaction-regeneration system, a fractionation system, a hydrofinishing unit and an absorption-stabilization system,

[0064] Among them, the reaction-regeneration system includes a riser reactor, an oil separator and a catalyst regenerator,

[0065] The riser reactor is a two-stage riser reactor, comprising a first riser reactor 10 and a second riser reactor 11, the upper end of the first riser reactor 10 communicates with the oil separator 12, and the second riser reactor The upper end of the tube reactor 11 communicates with the oil separator 12, and the first riser reactor 10 is provided with a pre-lift gas inlet 103, a catalyst feed port 102 and a feedstock oil feed port 101 from bottom to top, and the second riser reactor The devic...

Embodiment 2

[0076] The device of the present invention see figure 2 , its structure is basically the same as that of Example 1, except that the second riser reactor adopts a turbulent bed or a combined reactor of a fast bed and a transport bed. Such as figure 2 with 3 As shown, the second riser reactor is composed of a pre-lift section 1101, a turbulent bed or fast bed reaction zone 1102, and a transport bed reaction zone 1103 from bottom to top. The specific design requirements are as follows: the total height of the reactor is 10~40m; The diameter of the pre-lift section 1101 is 0.2-5m, and its height accounts for 5-20% of the total height of the reactor; the height of the turbulent bed or fast bed reaction zone 1102 accounts for 5-50% of the total reactor height, and its diameter is the same The diameter ratio of 1101 is 1.2~5.0:1; the height of transport bed reaction zone 1103 accounts for 20~90% of the total height of the reactor, and the ratio of its diameter to the diameter of ...

Embodiment 3

[0078] Embodiment 3: single-stage riser reactor

[0079] Such as Figure 4 As shown, the device for the joint production of clean gasoline and increased propylene production by catalytic cracking and hydrofining provided in this example is similar to Example 1, except that the riser reactor of the reaction regeneration system in this example is a single-stage riser reactor.

[0080] Knot Figure 4 , the difference between the two devices is described as follows:

[0081] The upper end of the riser reactor 11' communicates with the oil separator 12', and the riser reactor 11' is provided with a pre-lift gas inlet 114', a catalyst feed port 113', and a naphtha light fraction feed port 112 from bottom to top. ', raw oil feed port 101' and circulating oil feed port 111', the solid phase outlet of the oil separator 12' communicates with the catalyst regenerator 13, and the catalyst regenerator 13 is connected to the catalyst of the riser reactor 11' through a pipeline The feedi...

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Abstract

The invention discloses a device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation. The device comprises a reaction-regeneration system, a fractionating system, an absorption stable system and a hydrofining unit. The method comprises the following steps: adding a gasoline fractionating tower to the top of a catalytic cracking fractionating tower to divide crude gasoline into a light fraction and a heavy fraction, wherein the heavy gasoline enters the hydrogenation unit for refining, and one part of the light gasoline enters the absorption stable system to obtain stable light gasoline, and the other part of the light gasoline directly returns to the upper part of a catalytic cracking riser reactor to be cracked to increase the propylene yield under a relatively harsh reaction condition; and finally, blending the stable light gasoline and the modified heavy gasoline to obtain the product of clean gasoline. By adopting the method, the catalytic cracking gasoline is efficiently modified, the propylene yield is increased, and the catalyst-oil ratio of a catalytic cracking device can be increased to promote the conversion of heavy petroleum hydrocarbon; and meanwhile, the load and energy consumption of the absorption stable system are reduced, the process is simplified, the synergistic effect between the two devices of catalytic cracking and hydrofining is enhanced, and the processing cost is lowered.

Description

technical field [0001] The invention belongs to the technical field of petrochemical industry, and in particular relates to a device and a process for jointly producing clean gasoline and increasing the production of propylene by catalytic cracking and hydrofining. Background technique [0002] In my country, catalytic gasoline provides nearly 80% of the blending components of finished gasoline, but also introduces more than 90% of sulfur and olefins. The poor quality of raw materials not only increases the sulfur content of catalytic gasoline, but also increases the olefin content of gasoline. At present, the olefin content of catalytic gasoline in my country is generally 40~60 vol.%, which is far from meeting the requirements of gasoline standards. Therefore, the key to improving the quality of gasoline in my country at this stage is to reduce the olefin content and sulfur content of FCC gasoline. [0003] Propylene is an important basic raw material for organic synthesis...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/00
Inventor 张金弘杨朝合贾少磊山红红刘文菁陈小博李春义
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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