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35results about How to "Improve the ratio of agent to oil" patented technology

Pre-treatment process method of high acid crude oil

The invention relates to a pre-treatment process method of high acid crude oil. The method comprises the following steps that high acid crude oil is treated by coupling deacidification and electro-desalting processes by combining chemical extraction and electro-desalting; a first level tank is taken as a deacidification and electro-desalting tank; a demulsifier and an extractant are injected before a crude oil electro-desalting static mixer; after being fully mixing with crude oil, the mixture enters into the first level desalting tank; generated naphthenate and salt-containing sewage in the crude oil are dissolved in the extractant; treated deacidified oil enters into second and third level desalting tanks after being mixed with the demulsifier and water through the static mixer for desalination and dehydration; treated crude oil enters into a subsequent heat exchange unit; after a period time of operation of an electro-desalting system, impurities such as mud in raw material oil are flushed by a non-stop back purge device to discharge mud-containing sewage out of the tank; an extract phase is acidified to separate out naphthenic acid which is further extracted and purified by light dydrocarbon, and the extractant is purified and recovered and recycled.
Owner:长江三星能源科技股份有限公司

Hydrocarbons catalytic conversion method for preparing low olefin-content gasoline

The invention relates to a hydrocarbon catalytic conversion method for preparing gasoline with low alkene, wherein, in a reactor comprising a mixing area, a first reaction area and a second reaction area, regenerated catalyst and steam stripped charcoal catalyst enter into the mixing area and are mixed together, and flow upward and enter into the first reaction area under the action of a pre-lifted medium; the mixture contacts and reacts with catalyzing materials at the lower part of the first reaction area and flows upward; the generated oil agent mixture enters into the second reaction area and continue to contact and react fully; the oil agent mixture coming out from the second reaction area enters in a settler through a outlet area of the reactor to perform gas-solid separation, the charcoal catalyst after reaction enters into a stripper section of the settler for steam stripping; at lest one part of the steam stripped charcoal catalyst returns to the mixing area for cycling use, and the remained steam stripped charcoal catalyst is regenerated in a regenerator and then enters into the mixing area for cycling use; the reaction oil-gas after separating the charcoal catalyst is sent to a follow-up product separating system. Under the condition of low dry gas yield, the catalytic gasoline with low alkene can be produced by the method.
Owner:CHINA PETROLEUM & CHEM CORP +1

Device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation

InactiveCN103571536APromote absorptionReduce Saturation RequirementsTreatment with hydrotreatment processesGasolineTower
The invention discloses a device and method for producing clean gasoline and increasing propylene yield through catalytic cracking and hydrogenation. The device comprises a reaction-regeneration system, a fractionating system, an absorption stable system and a hydrofining unit. The method comprises the following steps: adding a gasoline fractionating tower to the top of a catalytic cracking fractionating tower to divide crude gasoline into a light fraction and a heavy fraction, wherein the heavy gasoline enters the hydrogenation unit for refining, and one part of the light gasoline enters the absorption stable system to obtain stable light gasoline, and the other part of the light gasoline directly returns to the upper part of a catalytic cracking riser reactor to be cracked to increase the propylene yield under a relatively harsh reaction condition; and finally, blending the stable light gasoline and the modified heavy gasoline to obtain the product of clean gasoline. By adopting the method, the catalytic cracking gasoline is efficiently modified, the propylene yield is increased, and the catalyst-oil ratio of a catalytic cracking device can be increased to promote the conversion of heavy petroleum hydrocarbon; and meanwhile, the load and energy consumption of the absorption stable system are reduced, the process is simplified, the synergistic effect between the two devices of catalytic cracking and hydrofining is enhanced, and the processing cost is lowered.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA) +1

Device and method for producing clean gasoline by combining catalytic cracking and hydrofining

The invention discloses a device and method for producing clean gasoline by combining catalytic cracking and hydrofining. The device comprises a reaction-regeneration system, a fractionating system, an absorption stable system and a hydrofining unit. The method comprises the following steps: adding a gasoline fractionating tower to the top of a catalytic cracking fractionating tower to divide crude gasoline into a light fraction and a heavy fraction, wherein the heavy fraction gasoline enters the hydrofining unit for selective hydrogenation desulfurization, and one part of the light fraction gasoline enters the absorption stable system to obtain stable light gasoline, and the other part of the light fraction gasoline directly returns to a reaction area at the upper part of a catalytic cracking second riser reactor to be modified under a mild condition; and blending the stable light gasoline and the modified heavy gasoline to obtain the product of clean gasoline. By adopting the method, the catalytic cracking gasoline is efficiently modified, and the catalyst-oil ratio of a catalytic cracking device can be increased to promote the conversion of heavy petroleum hydrocarbon; and meanwhile, the load and energy consumption of the absorption stable system are reduced, the synergistic effect between the two devices of catalytic cracking and hydrofining is enhanced, and the processing cost is lowered.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA) +1

Catalytic cracking cold-hot catalyst pre-lifter

The invention provides a catalytic cracking cold-hot catalyst pre-lifter which is suitable for a catalytic cracking lifting pipe reactor with at least one cold catalyst feeding and one hot catalyst feeding. The pre-lifter comprises a pre-lifting cylinder (5), a hot catalyst feeding pipe (4) and a cold catalyst feeding pipe (8), and is characterized in that a guide cylinder (3) is arranged in the pre-lifting cylinder (5) and divides the pre-lifting cylinder (5) into two communicated areas that is an inner ring (I) and an outer ring (II); and the hot and cold catalyst feeding pipes (4 and 8) are arranged between the upper edge and the lower edge of the guide cylinder. With the adoption of the pre-lifter, the cold catalyst and hot catalyst are uniformly mixed and subjected to heat exchange in a short residence time, so that the requirements of catalytic cracking reactions are satisfied effectively, the catalytic cracking reaction is strengthened and the thermal cracking reaction is inhibited, the conversion rate of the devices is increased and the selectivity of products is enhanced.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Tube-shell type solid-solid heat exchanger

InactiveCN103289726BGuaranteed thermal balanceGuaranteed to maintain heat balance under the condition of large agent-to-oil ratioCatalytic crackingSolid particleEngineering
The invention relates to a tube-shell type solid-solid heat exchanger without blending between cold and hot solid particles for heat exchange, inner spaces of an upper sealing head (3) and a lower sealing head (4) and the inner space of a heat exchange tube (2) form a tube pass, a space defined by a shell (1), an upper tube plate (5), a lower tube plate (6) and a heat exchange tube (2) forms a shell pass, fluidizers are respectively arranged in the tube pass and the shell pass, the cold and hot solid particles are fluidified and flow in the shell pass and the tube pass respectively, and heat exchange is realized between the cold and hot solid particles by virtue of the heat exchange tube (2). By adopting the tube-shell type solid-solid heat exchanger, heat exchange can be carried out between a thermal regeneration agent and a cold spent agent of a catalytic cracking unit, thus stable operation with high agent-oil ratio is realized, thermal balance of the whole device is maintained, and liquid yield of the tube-shell type solid-solid heat exchanger is increased; and thermal steam stripping on the spent agent can be realized, and benefit of the catalytic cracking unit is increased. The tube-shell type solid-solid heat exchanger provided by the invention can be applied to all the catalytic cracking units and other devices requiring heat exchange between the cold and hot solid particles.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Coupling equipment for realizing temperature adjustment and stripping of catalytic cracking regenerant

InactiveCN101760229BRealize the function of removalInhibitory inactivation effectCatalytic crackingFlue gasGas compressor
The invention provides coupling equipment for realizing the temperature adjustment and the stripping of catalytic cracking regenerant, which comprises a temperature adjustment section arranged at the upper part and a stripping section arranged at the lower part; the temperature adjustment section is provided with a built-in heat exchange component and at least an air distributor; and the temperature adjustment section extends downwards and reduces the circulation area to form the stripping section. By coupling the stripping area with quite small circulation area at the lower part of the temperature adjustment section, the invention can realize the function of flue gas removal without or only with a small amount of stripping steam, and can best inhibit the inactivation of the regenerant under the steam atmosphere. The coupling equipment of the invention can be arranged in a regenerant circulating pipeline of a catalytic cracker, so that the regenerant directly enters a rise reactor after the temperature is adjusted and the flue gas is removed, thereby not only significantly improving the oil ratio, the regeneration temperature and the raw material pre-heating temperature of the catalytic cracker and facilitating the improvement of product distribution, but also having the function of glue gas removal and reducing the load of a rich gas compressor and the energy consumption of the device.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Method and device of heavy oil two stage catalytic cracking reforming and gasoline upgrade coupling

The invention is a two-stage heavy oil catalytic cracking conversion method and device, belonging to petroleum refining process and device technical field, separating heavy oil reaction course into top and bottom reacting regions, making raw oil and regenerated catalyst firstly contact and react with each other in the bottom reacting region and successively separating the carbon deposit deactivated catalyst from reacting oil; making the oil gas go up into the second reacting region to mix with the catalyst used in gasoline reaction and continue reaction; a heavy oil reactor is connected in parallel with gasoline reacting part; the gasoline and catalyst complete reaction in the gasoline reactor and then make gas-solid separation in gasoline settler, where the oil gas is discharged through pipeline and the extracted catalyst is fed into pre-rising stages below the first and second heavy oil reacting regions to continue taking part in heavy reaction; a catalyst return pipe is arranged between the pre-rising stages of the gasoline settler and gasoline reactor to make a part of catalyst used in gasoline reaction return to the bottom of the gasoline reactor, so as to take part in gasoline reaction. And it can obviously raise efficiency of heavy oil reactor, improve product quality and need not consume energy because of catalyst change.
Owner:石宝珍

Catalytic cracking method of increasing gasoline yield

The invention discloses a catalytic cracking method of increasing gasoline yield, which comprises the following steps: (A) feeding raw material oil to the lower part of a first lifting tube reactor and carrying out a contact reaction to the raw material oil with a catalyst from a pre-lifting mixer; (B) feeding a to-be-regenerated catalyst from the first lifting tube reactor into a steam stripping part of a main precipitator, performing steam stripping and regenerating the catalyst in a regenerator; (C) feeding catalytic diesel or hydrotreated catalytic diesel into the lower part of a second lifting tube reactor and carrying out a contact reaction with the catalyst from the regenerator; (D) feeding the to-be-regenerated catalyst from the second lifting tube reactor into a steam stripping part of a sub precipitator; (E) performing air stripping to the to-be-regenerated catalyst from the steam stripping part of the sub precipitator, feeding one part of the catalyst into the regenerator and regenerating the catalyst, and feeding the other one part of the catalyst into the pre-lifting mixer and mixing the catalyst with the regenerated catalyst from the regenerator; and (F) feeding the mixed catalyst into the lower part of the first lifting tube reactor and carrying out a contact reaction with the raw material oil. By means of the method, the catalytic cracking device is increased by 3-20% in gasoline yield, is increased by more than 0.5 units in RON of gasoline and is reduced in the content of olefin by more than 3% by volume. The gasoline directly produced in the second lifting tube reactor is higher than 96 in RON and is less than 10% in the content of olefin.
Owner:LUOYANG PETROCHEMICAL ENG CORP SINOPEC +1

Device and method for producing clean gasoline by combining catalytic cracking and hydrofining

The invention discloses a device and method for producing clean gasoline by combining catalytic cracking and hydrofining. The device comprises a reaction-regeneration system, a fractionating system, an absorption stable system and a hydrofining unit. The method comprises the following steps: adding a gasoline fractionating tower to the top of a catalytic cracking fractionating tower to divide crude gasoline into a light fraction and a heavy fraction, wherein the heavy fraction gasoline enters the hydrofining unit for selective hydrogenation desulfurization, and one part of the light fraction gasoline enters the absorption stable system to obtain stable light gasoline, and the other part of the light fraction gasoline directly returns to a reaction area at the upper part of a catalytic cracking second riser reactor to be modified under a mild condition; and blending the stable light gasoline and the modified heavy gasoline to obtain the product of clean gasoline. By adopting the method, the catalytic cracking gasoline is efficiently modified, and the catalyst-oil ratio of a catalytic cracking device can be increased to promote the conversion of heavy petroleum hydrocarbon; and meanwhile, the load and energy consumption of the absorption stable system are reduced, the synergistic effect between the two devices of catalytic cracking and hydrofining is enhanced, and the processing cost is lowered.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA) +1

Two-stage regeneration catalytic cracking method and device

InactiveCN104277864AGuaranteed burnt effectReduce the coke rate of the deviceCatalytic crackingSolventPetrochemical
The invention relates to a two-stage regeneration catalytic cracking method, belonging to the technical field of petrochemical industry and aiming at solving the problem that the traditional two-stage regeneration catalytic cracking is unsuitable for regulating solvent-oil ratio within a large range. The two-stage regeneration catalytic cracking method comprises the steps of reaction coking, catalyst deactivation and two-stage catalyst regeneration. The two-stage regeneration catalytic cracking method is characterized in that heat removal is set in two-stage regeneration processes; when the solvent-oil ratio is regulated within a large range, by regulating the heat removal of the two-stage regeneration, the invariable main air quantity of the two-stage regeneration can be realized, the temperature of the two-stage regeneration can be controlled to ensure the coking effect, and a regenerated catalyst with temperature of 620-700 DEG C is provided for a reaction process. The invention also provides a device for realizing the method. The device comprises a first regenerator, a second regenerator, a regenerant cooler and an outer combined heat removing device. The two-stage regeneration catalytic cracking method disclosed by the invention can be used for a heavy oil catalytic cracking device and can enhance the solvent-oil ratio of the device, reduce the coking rate of the device and increase the product yield.
Owner:刘英聚

Heavy oil catalytic cracking method and device

InactiveCN104342192AIncrease mixing temperatureHigh activityCatalytic crackingChemical industryCatalytic pyrolysis
The invention discloses a heavy oil catalytic cracking method, belongs to the technical field of petroleum chemical industry, is used for processing heavy oil, can improve the catalyst-to-oil ratio, reduces coke and dry gas yields, improves product yield, and solves reactor coking. The heavy oil catalytic cracking method includes the processes of catalyst feeding, raw material oil feeding, raw material oil vaporization, gas-solid contact, catalytic cracking reaction and gas-solid separation, and is characterized in that through arrangement of temperature reduction with a regeneration agent, heat collection with a pre-lifting device, and heat collection at the middle part of a lifting pipe reactor, the catalyst-to-oil ratio is increased, a mixing temperature of a feeding section is improved, the catalyst activity in the catalytic cracking process is improved, and the feeding heavy oil vaporization rate is improved; through arrangement of a closed fast separation system, the oil and gas residence time in a settler is shortened. The method can reduce the dry gas and coke yields, increase the product yield, improve the product quality and solve the problem of coking of the lifting pipe reactor and the settler. A device for realizing the method is also provided, includes a regeneration agent temperature reducer, the pre-lifting device, a heat collector, a lifting pipe middle-part heat collection facility and a closed fast separation facility, and is the catalytic cracking and catalytic pyrolysis device applied for processing the heavy oil.
Owner:刘英聚

Heavy oil catalytic cracking method and device by double-area coupling and catalyst tandem

InactiveCN102102030BHigh yieldSolve the problem of increasing inferiorityTreatment with plural parallel cracking stages onlyReactive systemFuel oil
The invention provides a method and a device for realizing catalytic cracking of heavy oil by a double-area coupling and catalyst tandem process, and belongs to the technical field of petroleum processing. According to difference of reaction characteristics of heavy oil catalytic cracking materials, the heavy oil catalytic cracking materials are divided into quality catalytic materials and inferior catalytic materials according to carbon residue values; and the quality catalytic materials and the inferior catalytic materials respectively enter different reaction areas in a catalytic cracking reaction system for catalytic cracking reaction. For the quality catalytic materials, a conventional riser reactor is utilized; for the inferior catalytic materials, a turbulent bed or fast bed and transport bed combined reactor is utilized, and the catalyst tandem process is adopted, so that the two parts of materials adopt respectively optimized reaction conditions in respective independent reaction areas provided by different-structure reactors; and the catalyst and oil contact temperature difference is reduced and a large catalyst-oil ratio is achieved by arranging a catalyst cooler, the problem that the catalyst in a reaction area for the inferior materials is severe in coking, quick in deactivation and low in later activity is improved and the light oil yield and the integral liquid yield are obviously improved.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

A kind of catalytic cracking method of prolific gasoline

The invention discloses a catalytic cracking method for producing gasoline. The steps are: the feedstock oil enters the lower part of the first riser reactor to contact and react with the catalyst from the pre-lift mixer, the raw catalyst in the first riser reactor enters the stripping section of the main settler for stripping, and then enters the regenerator for regeneration. Catalyzed diesel or hydrotreated catalytic diesel enters the lower part of the second riser reactor to contact and react with the catalyst from the regenerator, and the ungenerated catalyst in the second riser reactor enters the stripping section of the secondary settler After being stripped, part of the spent catalyst enters the regenerator for regeneration, and the other part enters the pre-lift mixer to mix with the regenerated catalyst from the regenerator, and the mixed catalyst enters the lower part of the first riser reactor to contact with the raw material oil for reaction. By using the method of the invention, the gasoline yield of the catalytic cracking unit can be increased by 3-20 percentage points, the gasoline RON can be increased by more than 0.5 units, and the gasoline olefin content can be reduced by more than 3 volume percentage points. The RON of gasoline directly produced in the second riser reactor is above 96, and the volume content of olefins is below 10%.
Owner:SINOPEC LUOYANG PETROCHEM ENG CORP +1
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