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Seaweed ammonium phosphate fertilizer and preparation method thereof

A technology of seaweed ammonium phosphate and seaweed diammonium phosphate, applied in fertilization devices, fertilizer mixtures, applications, etc., can solve the problems of low extraction rate, high requirements for seaweed raw material pretreatment and equipment, and limited promotion, so as to improve absorption efficiency and utilization rate, beneficial to the growth of crop root system, and the effect of alleviating the imbalance of chemical fertilizer ratio

Active Publication Date: 2014-03-12
青岛海大生物集团股份有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the degradation of polysaccharides by acidic high-pressure degradation is relatively thorough, basically existing in the form of small molecule oligosaccharides, but the degradation process is too severe, and the damage to other active ingredients in seaweed is relatively large; the conditions of alkaline degradation are relatively mild, but the molecular weight of the degraded polysaccharides is relatively mild. Larger, it is easy to form colloids in water, so it is easy to gel and precipitate during the compounding process; the compound enzyme degradation method has higher requirements for raw material pretreatment, and it needs to reach a certain fineness to effectively degrade, and the molecular weight of the degraded polysaccharide is also the same There are problems such as large molecular weight and easy gelation; the microbial degradation method takes too long, and there are problems of incomplete degradation and low extraction rate; ultrasonic degradation method has high requirements for seaweed raw material pretreatment and equipment, which leads to its popularization. limit

Method used

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preparation example Construction

[0021] A kind of preparation method of seaweed ammonium phosphate fertilizer of the present invention, specific embodiment comprises the following steps:

[0022] First prepare seaweed oligosaccharide phosphate, combined with the production and preparation process of ammonium phosphate fertilizer, add seaweed oligosaccharide phosphate concentrate or powder, and adjust different neutralization degrees according to the ratio of nitrogen and phosphorus in the required ammonium phosphate fertilizer, Then, the seaweed ammonium phosphate fertilizer with different nitrogen and phosphorus ratios is prepared through drying, screening, anti-caking wrapping, and cooling processes, and the seaweed ammonium phosphate fertilizer includes seaweed monoammonium phosphate and seaweed diammonium phosphate fertilizer.

[0023] Specifically, 1-5 parts by weight of seaweed oligosaccharide phosphate concentrate and 95-99 parts by weight of ammonium phosphate are used to make monoammonium phosphate an...

Embodiment 1

[0031]Take 50kg of dry kelp, add 1500kg of water, then add 12kg of sodium carbonate, keep stirring at 80°C for 1 hour, neutralize the pH to 6.0 with phosphoric acid, add 0.1 kg of potassium permanganate for further catalytic degradation for 20 minutes, and then add polyphosphoric acid Ammonium 25 kg, polyphosphorylation reaction was carried out at 70-80°C for 0.5 hour. Filter and concentrate the extract to obtain a seaweed oligosaccharide phosphate concentrate, in which the concentration of solids is 30%-40%. Take 10 kg of seaweed oligosaccharide phosphate concentrate and dissolve it into the phosphoric acid washing tower in the production process of diammonium phosphate to obtain 1 ton of seaweed diammonium phosphate.

Embodiment 2

[0033] Take 50kg of Enteromorpha powder, add 500kg of water, then add 5kg of potassium hydroxide, raise the temperature to 90°C, keep it under stirring for 1.5 hours, neutralize the pH to 5.5 with phosphoric acid, add 0.05kg of potassium permanganate, 10kg of ammonium polyphosphate , carry out the polyphosphorylation reaction at 70-80° C. for 0.5 hours. The extract is centrifugally filtered and concentrated to obtain a concentrated solution of seaweed oligosaccharide phosphate, in which the concentration of solids is 30%-40%. Take 50 kg of concentrated solution of seaweed oligosaccharide phosphate and dissolve it into the phosphoric acid in the production process of monoammonium phosphate Washing tower to produce 1 ton of seaweed monoammonium phosphate.

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Abstract

The invention provides a seaweed ammonium phosphate fertilizer and a preparation method thereof. The seaweed ammonium phosphate fertilizer is characterized by being prepared from a concentrated solution or powder of seaweed oligose phosphate and ammonium phosphate. According to the preparation method, the seaweed oligose phosphate is firstly prepared, the oligose molecular weight of the seaweed oligose phosphate is 1000-5000Da, by combining with the preparation technology of ammonium phosphate fertilizer, a seaweed monoammonium phosphate and seaweed diammonium phosphate fertilizer is prepared from 1-5 parts by weight of concentrated solution of seaweed oligose phosphate and 95-99 parts by weight of ammonium phosphate, or the seaweed monoammonium phosphate and seaweed diammonium phosphate fertilizer is prepared by 0.2-1 part by weight of powder of seaweed oligose phosphate and 99-99.8 parts by weight of ammonium phosphate. The seaweed oligose phosphate and ammonium phosphate fertilizer are combined, so that the absorptivity and use ratio of the ammonium phosphate fertilizer by crops are improved, soil hardening caused by application of a single ammonium phosphate fertilizer is relieved, the ecological environment of the farmland is optimized, the fertilizer disproportionality is lightened, and the preparation method is simple and reasonable.

Description

technical field [0001] The invention belongs to the technical field of chemical fertilizer production, and relates to the production technology of ammonium phosphate fertilizer, in particular to a seaweed ammonium phosphate fertilizer and a preparation method thereof. Background technique [0002] At present, there are many application technologies of seaweed in fertilizers, among which the extraction technology of seaweed polysaccharide generally adopts one technology or a combination of several technologies such as acid method, alkali method, compound enzymatic hydrolysis method, microbial degradation method and ultrasonic degradation method. Among them, the degradation of polysaccharides by acidic high-pressure degradation is relatively thorough, basically existing in the form of small molecule oligosaccharides, but the degradation process is too severe, and the damage to other active ingredients in seaweed is relatively large; the conditions of alkaline degradation are re...

Claims

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Application Information

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IPC IPC(8): C05G3/00
Inventor 王海华单俊伟
Owner 青岛海大生物集团股份有限公司
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