Completely biodegradable material and preparation method thereof and cosmetics container
A biodegradable material and biodegradable technology, applied in the field of completely biodegradable materials and their preparation, cosmetic packaging boxes, can solve the problems of low impact strength, low elongation at break, etc., achieve improved crystallization speed, simple operation, excellent The effect of mechanical properties
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[0044] The preparation method of the fully biodegradable material of the present invention may include the following steps:
[0045] a. Dry the fully biodegradable polymer and the nucleating agent separately;
[0046] b. Melt blend the dried fully biodegradable polymer and nucleating agent with the remaining components to obtain mixed components;
[0047] c. The mixed components are molded by injection, molding or extrusion blow molding.
[0048] In step a, the temperature of the fully biodegradable polymer drying treatment may be 60-100° C., and the drying treatment time may be 8-12 hours. The temperature of the drying treatment of the nucleating agent may be 80 to 120°C, and the time of the drying treatment may be 2 to 5 hours. In step b, an internal mixer or extruder can be used to melt and blend the components. The temperature of the extruder or internal mixer can be set at 170-220°C, preferably 180-210°C, and the rotation speed can be 10~200rmp. In step c, the cosmetic packagi...
Embodiment 1
[0051] The raw materials and dosage are: 50 grams of PLA (4032D, LD mixed type, Mn=127,000, NatureWorks), 0.25 grams of TMC-300 nucleating agent (Shanxi Institute of Chemical Industry), 2.5 grams of acetyl tributyl citrate plasticizer, 0.25 grams of antioxidant 1010, 1.25 grams of lubricant aluminum stearate. PLA was dried in a vacuum oven at 80°C for 12 hours; the TMC-300 nucleating agent was dried in a vacuum oven at 80°C for 2 hours. Then, the raw materials are mixed uniformly and then added to the internal mixer for melting and mixing. The temperature of the three parts of the internal mixer is 190°C, 195°C and 190°C, the rotating speed is 35rpm, and the banburying time is 10 minutes. The melted and mixed resin is hot-pressed in a mold and preheated for 5 minutes; the hot pressing temperature of the upper and lower molds is 190°C, the pressure is 10MPa; the hot pressing time is 5 minutes. The properties of the material obtained: the tensile strength is 47MPa, and the heat ...
Embodiment 2
[0053] The raw materials and dosage are: 25g PBS, 25g PLA (4032D, LD mixed type, Mn=127,000, Nature Works), 0.25g TMC-306 nucleating agent (Shanxi Institute of Chemical Industry), 0.025g diisopropyl peroxide Benzene, 0.25 g maleic anhydride, 2.5 g acetyl tributyl citrate plasticizer, 0.25 g antioxidant 1010, 1.25 g lubricant aluminum stearate. PBS and PLA were dried in a vacuum oven at 80°C for 12 hours; the TMC-306 nucleating agent was dried in a vacuum oven at 80°C for 2 hours. Then, the raw materials are mixed uniformly and then added to the internal mixer for melting and mixing. The temperature of the three parts of the internal mixer is 190°C, 195°C and 190°C, the rotating speed is 35rpm, and the banburying time is 10 minutes. The melted and mixed resin is hot-pressed in a mold and preheated for 5 minutes; the hot pressing temperature of the upper and lower molds is 190°C, the pressure is 10Mpa, and the hot pressing time is 5 minutes. The properties of the material obtain...
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