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Method for extracting lithium from bittern and preparing high-purity lithium concentrate

The invention discloses a method for extracting lithium from bittern and preparing a high-purity lithium concentrate. The method is characterized by comprising the following steps: adding a 0.5-20kg/t magnetic lithium ion sieve into a bittern conveying pipeline, and adjusting the pH value to be higher than or equal to 5.0; separating the magnetic lithium ion sieve from the bittern by a magnetic separation system; feeding the magnetic lithium ion sieve into a desorption activation link; performing magnetic separation of the ion sieve and the desorption liquid again; feeding the magnetic lithium ion sieve into the raw bittern, and extracting lithium again; circulating the desorption liquid repeatedly until the lithium concentration is higher than or equal to 3g/l, and enabling the desorption liquid to pass through a nanofiltration membrane, wherein the filtered part of the nanofiltration membrane is the high-purity concentrate with purity of higher than or equal to 99%, and a lithium carbonate product is directly prepared; repeatedly circulating the intercepted part of the nanofiltration membrane by a nanofiltration link until the manganese-lithium ratio is greater than 2:1; adding sodium bicarbonate to prepare a manganese carbonate product; separating with PP cotton; and returning the lithium liquid to feed water to the nanofiltration membrane. In the invention, high-purity lithium concentrate can be prepared by use of the magnetic lithium ion sieve and by combining the magnetic separation and membrane separation technology; and in the process, the lithium concentration links such as solarization and reverse osmosis are not needed.
Owner:衢州永正锂业科技有限公司
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