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Ultrahigh-alkalinity crystallizer mould flux special for high-pulling-rate peritectic steel

The technology of mold powder and mold powder, which is applied in the field of steelmaking auxiliary material preparation, can solve the problems of coordinated heat transfer and control of heat transfer defects of mold powder, complicated slag network structure, weakening of the lubricating effect of mold powder, and the like. No crusting and agglomeration, effective control of melting rate, good spreading effect

Active Publication Date: 2014-05-14
XIXIA LONGCHENG METALLURGICAL MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when using the mold slag in the traditional peritectic steel formation area, it is often found that the lubrication of the slab shell has deteriorated to varying degrees. The reason is that the solid slag film becomes thicker after the mold slag crystallization ability is enhanced, and the liquid slag film becomes relatively thinner, thus deteriorating For the lubrication of the billet shell, this situation can be alleviated in some cases by reducing the viscosity of mold flux, but it is difficult to fundamentally solve this problem
Later, through theoretical calculation and practice, it was found that after the lance spar was precipitated, the alkalinity of the remaining liquid slag would decrease, and the trace amount of SiO 2 will increase, the first may complicate the slag network structure and increase the viscosity of liquid slag, and the second is excessive SiO 2 Possibly due to other components of slag such as Al 2 o 3 , MgO, etc. form high melting point compounds, which are easy to deteriorate, and these will easily weaken the lubricating effect of the mold flux, so that the mold flux has defects in coordinating heat transfer and controlling heat transfer

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A high-speed peritectic steel special ultra-high alkalinity crystallizer protective slag, its raw material formula weight percentage composition is: wollastonite 41.5%, cement clinker 13.9%, fluorite 13.6%, sodium carbonate 1.6%, lithium carbonate 2%, carbon black 1.8%, graphite 4.3%, sodium fluoride 4%, albite 3.8%, calcite 5.7%, magnesia 1.6%, cryolite 3%, bauxite 2%, dextrin 0.6%, plant 0.6% starch.

[0022] The protective slag is prepared according to the conventional process, and its chemical composition weight percentage is: CaO: 39.7%, SiO 2 : 29.3%, MgO: 2.4%, Al 2 O 3 : 3.5%, F - : 9.2%, C: 4.9%, Na 2 O: 4.6%, Li 2 O: 4.5%, balance: impurities.

[0023] The basicity of the ultra-high basicity mold powder for high-speed peritectic steel is CaO / SiO 2 It is 1.35, melting point is 1050°C, viscosity is 0.48 Pa.s at 1300°C.

Embodiment 2

[0025] A high-speed peritectic steel special ultra-high alkalinity crystallizer protective slag. Its raw material formula weight percentage composition is: wollastonite 43.2%, cement clinker 14.3%, fluorite 13.2%, sodium carbonate 1.3%, lithium carbonate 2%, carbon black 1.8%, graphite 4.8%, sodium fluoride 4%, albite 3.5%, calcite 5.2%, magnesia 2.6%, cryolite 1.6%, bauxite 1.3%, vegetable starch 1.2%.

[0026] The protective slag is prepared according to the conventional process, and its chemical composition weight percentage is: CaO: 39.4%, SiO 2 : 27.5%, MgO: 3.8%, Al 2 O 3 : 4.2%, F - : 8.7%, LiO 2 : 4.2%, Na 2 O: 5.2%, C: 5.2%, balance: impurities.

[0027] The basicity of the ultra-high basicity mold powder for high-speed peritectic steel is CaO / SiO 2 It is 1.43, melting point is 1096℃, viscosity is 0.51Pa.s at 1300℃.

Embodiment 3

[0029] A high-speed peritectic steel special ultra-high alkalinity crystallizer protective slag, its raw material formula weight percentage composition is: wollastonite 40%, cement clinker 11%, fluorite 15%, sodium carbonate 3%, lithium carbonate 1%, carbon black 1.8%, graphite 5%, sodium fluoride 4%, albite 6%, calcite 5%, magnesia 3%, cryolite 2%, bauxite 2%, dextrin 1.2%.

[0030] The protective slag is prepared according to the conventional process, and its chemical composition weight percentage is: CaO: 38%, SiO 2 : 25%, MgO: 5%, Al 2 O 3 : 3.5%, F - : 10%, Li 2 O: 4.5%, Na 2 O: 5.2%, C: 7%, balance: impurities.

[0031] The basicity of the ultra-high basicity mold powder for high-speed peritectic steel is CaO / SiO 2 It is 1.52, melting point is 1120℃, viscosity is 0.55Pa.s at 1300℃.

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Abstract

The invention discloses an ultrahigh-alkalinity crystallizer mould flux special for high-pulling-rate peritectic steel. 38%-42% of CaO, 25%-29% of SiO2 and 7%-10% of F- are adopted to improve the crystallization capacity of the mould flux, reduce stress concentration and improve lubrication; 2%-5% of MgO and 2%-5% of Al2O3 are adopted to improve the fluidity of a flux film and reduce cracks; an excellent heat transfer coordination and heat transfer control effect is achieved by adopting the mould flux with the alkalinity ranging from 1.35 to 1.52, 25%-29% of SiO2, 2%-5% of Al2O3 and 2%-5% of MgO; the effects of effectively controlling the melting rate to guarantee melt flux feeding and preventing subsurface blowholes can be achieved with the carbon proportioning range of 4%-7%. Raw materials for preparing the ultrahigh-alkalinity crystallizer mould flux can be easily obtained, the flux consumption ranges from 0.32 kg per ton of steel to 0.38 kg per ton of steel, and cost of per ton of steel is low; on-spot practical application indicates that the mould flux can be well spread in a crystallizer and be evenly and stably melt and is high in casting percent of pass.

Description

Technical field [0001] The invention belongs to the technical field of the preparation of steelmaking auxiliary materials, and specifically relates to an ultra-high basicity crystallizer mold powder special for high-speed peritectic steel. Background technique [0002] Continuous casting mold mold powder is an important material in continuous casting production, which can improve the surface and subcutaneous quality of cast slabs and expand the steel grades for continuous casting. The alkalinity of continuous casting mold powder is an important indicator, which determines the position of the entire mold powder design system. The basicity of the mold fluxes mainly used by major steel mills is generally controlled between 0.9 and 1.5, so that the mold fluxes have good adsorption and good heat transfer effect. High-basicity mold powder is not the mainstream in the production process, but for some high-speed solidification processes that have peritectic reaction and are prone to lon...

Claims

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Application Information

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IPC IPC(8): B22D11/111
Inventor 彭会志王正英梁冠东薄红涛王旭阳谭政委王岩
Owner XIXIA LONGCHENG METALLURGICAL MATERIALS CO LTD
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