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Composition for forming an antireflection film containing a reaction product of an isocyanuric acid compound and a benzoic acid compound

A technology of anti-reflection film and compound, which is applied in the field of composition forming the anti-reflection film, and can solve problems such as bad effects of processing procedures

Active Publication Date: 2017-10-20
NISSAN CHEM IND LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This is because if the photoresist pattern has a large curl shape, it will have a bad influence on the subsequent processing steps

Method used

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  • Composition for forming an antireflection film containing a reaction product of an isocyanuric acid compound and a benzoic acid compound
  • Composition for forming an antireflection film containing a reaction product of an isocyanuric acid compound and a benzoic acid compound
  • Composition for forming an antireflection film containing a reaction product of an isocyanuric acid compound and a benzoic acid compound

Examples

Experimental program
Comparison scheme
Effect test

Synthetic example 1

[0095] 175 g of tris(2,3-epoxypropyl)isocyanuric acid (manufactured by Nissan Chemical Industry Co., Ltd., trade name TEPIC), 628 g of 3,5-diiodo-2-hydroxybenzoic acid, and benzyl tris After dissolving 9.2 g of ethylammonium chloride in 3,250 g of propylene glycol monomethyl ether, it was reacted at 130° C. for 24 hours to obtain a solution containing a reaction product. In addition, it is considered that the reaction product contains an isocyanuric acid compound obtained by converting a 2,3-epoxypropyl group into a group of formula (5) and an oligomer (or polymer) having a structure of formula (6). ).

[0096]

Synthetic example 2

[0098] Dissolve 457 g of tris(2,3-epoxypropyl)isocyanuric acid (manufactured by Nissan Chemical Industries, Ltd., trade name TEPIC), 407 g of 4-hydroxybenzoic acid, and 136 g of 4-cyanobenzoic acid in propylene glycol monomethyl 1000 g of base ether, and reacted at 130° C. for 24 hours to obtain a solution containing a reaction product. In addition, it is considered that the reaction product contains an isocyanuric acid compound in which a 2,3-glycidyl group is converted into a group of formula (7) or formula (8).

[0099]

Embodiment 1

[0101] 9.6 g of propylene glycol monomethyl ether, 65.8 g of ethyl lactate, and 0.11 g of triphenylhexafluorosulfonium antimonate as a photoacid generator were added to 23.3 g of a solution containing 4.7 g of the reaction product obtained in Synthesis Example 1. , 1.2 g of tetramethoxymethyl glycoluril (manufactured by Japan Cytech Indastres Co., Ltd. (former Mitsui Cytech Co., Ltd.), trade name Paudaring 1174) and 0.06 g of pyridinium p-toluenesulfonate were used to form a solution. Then, filtration was performed using a polyethylene microfilter with a pore diameter of 0.10 μm, and then a polyethylene microfilter with a pore diameter of 0.05 μm was used to prepare a solution of an antireflection film-forming composition.

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Abstract

The invention aims at providing an anti-reflection film which is high in anti-reflection effect, is not mixed with a photoresist, can be used for forming a photoresist graph without a large turned edge shape at the bottom, and can be used in the photoetching procedure using irradiation light of ArF excimer laser, F2 excimer laser and the like; the invention also provides a composition for forming the anti-reflection film. In order to solve the problems, the invention provides the composition for forming the anti-reflection film, namely, the composition for forming the anti-reflection film contains the following reaction product which is obtained by the reaction between isocyanuric acid compound with two or three 2, 3-glycidyls and benzoic acid component.

Description

[0001] This application is a branch of a patent application with a filing date of September 27, 2005, an application number of 200580051639.1, and an invention title of "A composition for forming an anti-reflection film containing a reaction product of an isocyanuric acid compound and a benzoic acid compound". case application. technical field [0002] The present invention relates to a composition for forming an antireflection film. Specifically, it relates to an anti-reflection film used in order to reduce the reflection of exposure light from a semiconductor substrate to a photoresist layer coated on a semiconductor substrate in a photolithography process for manufacturing a semiconductor device, and an antireflection film for forming the same. Composition for antireflection film. More specifically, it relates to an antireflection film used in a photolithography process for manufacturing a semiconductor device using exposure irradiation light with a wavelength of 248 nm, 1...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/11G02B1/04
Inventor 岸冈高广坂本力丸丸山大辅
Owner NISSAN CHEM IND LTD
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