Polyurethane-material polishing pad and preparation method thereof

A polyurethane material, polishing pad technology, applied in grinding/polishing equipment, manufacturing tools, metal processing equipment, etc., can solve the problems of affecting the transportation of polishing liquid, deterioration of polishing performance, increase of manufacturing cost, etc., to improve the decomposability of the environment , reliable performance, low manufacturing cost and low production cost

Active Publication Date: 2014-06-18
HUBEI DINGLONG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Polyurethane polishing pads are usually composed of a polishing layer, a buffer layer and a transparent bottom pad. During manufacture, since the polishing layer and the buffer layer are all polyurethane materials, the prepolymer as an important manufacturing raw material is often used in order to ensure that the material can be stored for a long time. High-molecular-weight prepolymers, polyisocyanic acid refers to the high-molecular-weight prepolymers generated after reacting with polyols, which have high viscosity and poor fluidity, so there are the following problems: (1) In order to avoid mixing bubbles in the polishing layer and affecting the polishing effect , so it is necessary to defoam the prepolymer, and due to the high viscosity of the generated prepolymer (viscosity can reach 4000mPa·S, the test temperature is 80°C), the air bubbles mixed in the prepolymerization reaction ...

Method used

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  • Polyurethane-material polishing pad and preparation method thereof
  • Polyurethane-material polishing pad and preparation method thereof
  • Polyurethane-material polishing pad and preparation method thereof

Examples

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preparation Embodiment 1

[0042] 100g of solid MDI was put into a 1L three-necked flask, the reaction temperature was raised to 70°C within 30 minutes, and after all the MDI was melted, the stirrer was started, and the stirring speed was 300 rpm. 12 g of dipropylene glycol was added dropwise to MDI, and the dropwise addition time was controlled at 1.5 hours. After the dropwise addition, the reaction was continued at 80°C for 2 hours, and then the reactant was subjected to defoaming treatment. The free NCO mass percentage is 23%, the viscosity is 320mPa·S, and the viscosity test temperature is 25℃.

preparation Embodiment 2

[0044] 100g of solid MDI was put into a 1L three-necked flask, the reaction temperature was raised to 75°C within 30 minutes, and after all the MDI was melted, the stirrer was started, and the stirring speed was 300 rpm. 30 g of dipropylene glycol was added dropwise to MDI, and the dropwise addition time was controlled at 1.5 hours. After the dropwise addition, the reaction was continued at 80°C for 2 hours, and then the reactant was subjected to defoaming treatment. The free NCO mass percentage is 11%, the viscosity is 450mPa·S, and the viscosity test temperature is 25℃.

Embodiment 3

[0046] 100g of solid MDI was put into a 1L three-necked flask, the reaction temperature was raised to 60°C within 30 minutes, and after all the MDI was melted, the stirrer was started, and the stirring speed was 300 rpm. 5 g of dipropylene glycol was added dropwise to MDI, and the dropwise addition time was controlled at 1.5 hours. After the dropwise addition, the reaction was continued at 80°C for 2 hours, and then the reactant was subjected to defoaming treatment. The free NCO mass percentage is 29%, the viscosity is 280mPa·S, and the viscosity test temperature is 25℃. Preparation Example 4 of Isocyanate Ion-terminated Energy-saving Prepolymer A

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Abstract

The invention relates to a polyurethane-material polishing pad and a preparation method thereof. By adoption of the polyurethane-material polishing pad and the preparation method, the problems of high energy consumption, long period, high production cost and poor degradability in the existing process are solved. The polyurethane-material polishing pad comprises a polishing layer, a buffering layer and a transparent bottom pad, wherein the polishing layer is formed by mixing, forming and curing isocyanic acid radical ion end-blocking energy-saving prepolymer A, polyatomic alcohol B, a curing agent C and hollow polymer microspheres D; the mixing ratio of the isocyanic acid radical ion end-blocking energy-saving prepolymer A to the polyatomic alcohol B to the curing agent C to the hollow polymer microspheres D is (5-100):(5-100):(5-50):(0.15-10); the shore hardness of the polishing layer is 41D-90D, the density is 0.7-1.2g/ml, and the elongation at break is 50-200%. The polyurethane-material polishing pad and the preparation method have the advantages of simple process, low production cost and manufacturing cost, low energy consumption, short production period, fast degradation speed and environmental-friendly effect.

Description

technical field [0001] The invention relates to the polishing technical field of chemical mechanical planarization treatment, in particular to a polishing pad and a preparation method thereof. Background technique [0002] Chemical mechanical planarization, or chemical mechanical polishing (CMP), is a common technique used to planarize semiconductor wafers, substrates such as sapphire. In conventional CMP, the wafer is mounted on a holder assembly, and the wafer is brought into contact with a polishing pad in the CMP apparatus. The holder assembly provides controlled pressure on the wafer, pressing the wafer against the polishing pad. The applied driving force causes rotational motion of the polishing pad relative to the wafer. At the same time, a chemical composition or other polishing solution is provided between the wafer and the polishing pad. Thereby, the surface of the wafer is polished and flattened by the chemical and mechanical action of the polishing pad surface...

Claims

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Application Information

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IPC IPC(8): B24B37/24B24D18/00C08G18/66C08G18/48C08G18/42C08G18/10
CPCB24B37/24C08G18/10C08G18/3206C08G18/3814C08G18/4018C08G18/6651C08G18/6685C08G2230/00
Inventor 朱顺全梅黎黎李云峰
Owner HUBEI DINGLONG CO LTD
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