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Process for preparing arsenic-removing composite materials from red mud

A composite material and red mud technology, applied in the field of materials engineering, can solve the problems of unfavorable promotion and application in the field of arsenic removal, high cost of preparation of nano-iron particles, and reduction of reaction specific surface area, so as to facilitate large-scale production and improve governance efficiency , Reduce the effect of red mud pollution

Active Publication Date: 2016-01-06
北京爱吾尔德技术开发有限公司
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  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, iron is ferromagnetic, and nano-iron particles will aggregate without a carrier, reducing the specific surface area of ​​the reaction, thereby reducing the efficiency of arsenic treatment
In addition, in the prior art, raw materials such as iron salt need to be purchased, and the preparation cost of nano-iron particles is relatively high, which is not conducive to its promotion and application in the field of arsenic removal.

Method used

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  • Process for preparing arsenic-removing composite materials from red mud

Examples

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Embodiment 1

[0023] Pickling: Take out 10ml of 37% hydrochloric acid, add 110ml of distilled water to dilute to a 3% solution (1 mol / L). Take out 10 grams of red mud slurry, add 60 ml of 3% dilute hydrochloric acid solution, add distilled water to 500 ml, heat to 90 degrees, stir thoroughly for 30 minutes and then cool to room temperature. The red mud solids and filtrate were separated by filtration. The separated filtrate was put into a 500 ml container and cooled to room temperature for use. The separated red mud solids were washed three times with distilled water and filtered for later use.

[0024] Reduction: take out 3.8 g of sodium borohydride, add 100 ml of distilled water to dilute to a solution of 38 g / L (1 mol / L). Add 50 milliliters of 1 mol / liter sodium borohydride solution to reduce the iron in the solid to the separated red mud solid for use in the previous step. After filtering, the solid and the liquid were separated, and the separated solid was washed three times with di...

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Abstract

The invention discloses a process for preparing composite materials for removing arsenic from red mud. The process is characterized by comprising the steps of (1) adding the red mud slurry as raw materials to a diluted hydrochloric acid solution, heating to 80 DEG C-90 DEG C, and stirring; (2) after stirring, then cooling the mixture, filtering pickled red mud solids and filtrate, and then washing red mud solids with water; and (3) adding a reducing agent into red mud solids washed with water in step (2), carrying out a reduction reaction, and filtering after the reduction reaction is completed to obtain the obtained composite material for removing arsenic. Since the industrial red mud waste is used as the raw materials, the process disclosed by the method is environment friendly; the convenient preparation process is convenient and rapid and is conducive to large-scale production, and the obtained composite material has an excellent arsenic removal effect.

Description

technical field [0001] The invention relates to the field of material engineering, in particular to a process for preparing arsenic-removing composite materials by utilizing industrial red mud waste residues. Background technique [0002] Arsenic and its compounds are one of the main pollutants in industrial wastewater. Symptoms of acute arsenic poisoning include nausea, vomiting, metallic taste in the mouth, severe abdominal pain, etc. In severe cases, dizziness, gastrocnemius spasm, cyanosis and even Shock, in severe cases, symptoms of central nervous paralysis, painful spasms of limbs, loss of consciousness, etc. [0003] Red mud is the polluting waste slag discharged when the aluminum industry extracts alumina. Generally, for every ton of alumina produced, 1.0 to 2.0 tons of red mud are incidentally produced. As the world's fourth largest producer of alumina, China discharges millions of tons of red mud every year. A large amount of red mud cannot be fully and effectiv...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/58
Inventor 郑同华
Owner 北京爱吾尔德技术开发有限公司
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