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Preparation method of copper sulfide nanowire

A copper sulfide and nanowire technology, applied in copper sulfide, nanotechnology, nanotechnology and other directions, can solve problems such as unfavorable large-scale synthesis, inability to synthesize in one step, cumbersome operation process, etc., achieving simple synthesis method and reaction device, and green reaction process. , the effect of cleaning the reaction process

Inactive Publication Date: 2014-07-23
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The defect of the above synthesis method is that it cannot be synthesized in one step, and the operation process is cumbersome, which is not conducive to the large-scale synthesis of industrialization, which limits its applicability

Method used

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  • Preparation method of copper sulfide nanowire
  • Preparation method of copper sulfide nanowire
  • Preparation method of copper sulfide nanowire

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) In a 50ml three-necked bottle, weigh 0.5mmol CuCl 2 2H 2 O and 10ml oleylamine, pass into N 2 Protected, heated to 160°C with stirring, and then kept at constant temperature for 1h.

[0026] (2) Take another 5ml of oleylamine in a test tube, add 0.5mmol (C2H5)2NCSSNa·3H2O(SDEDTC), stir and dissolve at 120°C.

[0027] (3) Inject the solution in (2) into (1) through a syringe pump at a rate of 30ml / h, and react at a constant temperature for 1h.

[0028] (4) Cool the obtained product to 60°C, centrifuge in a 10ml centrifuge tube, wash twice with cyclohexane, and finally disperse in 10ml chloroform, which is the hydrophobic product.

[0029] (5) Use 2ml of a chloroform solution containing 20mg of polyethylene glycol monomethyl etherified-1,2-distearate-3-phosphatidylethanolamine (SDEDTC) and 1ml of the hydrophobic product in (4), after stirring for 2 hours, put The obtained product was placed in a rotary evaporator, vacuum-dried and spin-dried at room temperature, a...

Embodiment 2

[0033] (1) In a 50ml three-necked bottle, weigh 0.5mmol CuCl 2 2H 2 O and 10ml oleylamine, pass into N 2 Protected, heated to 170°C while stirring, and then kept at constant temperature for 1h.

[0034] (2) Take another 5ml of oleylamine in a test tube, add 0.5mmol (C 2 h 5 ) 2 NCSSNa·3H 2 O(SDEDTC), stirred and dissolved at 120°C.

[0035] (3) Inject the solution in (2) into (1) through a syringe pump at a rate of 30ml / h, and react at a constant temperature for 1h.

[0036] (4) Cool the obtained product to 60°C, centrifuge in a 10ml centrifuge tube, wash twice with cyclohexane, and finally disperse in 10ml chloroform, which is the hydrophobic product.

[0037] (5) Use 2ml of chloroform solution containing 20mg of polyethylene glycol monomethyl etherified-1,2-distearate-3-phosphatidylethanolamine (DSPE-PEG) and 1ml of the hydrophobic product in (4), after stirring for 2h , the obtained product was placed in a rotary evaporator, vacuum-dried and spin-dried at room tempe...

Embodiment 3

[0041] (1) In a 50ml three-necked bottle, weigh 0.5mmol CuCl 2 2H 2 O and 10ml oleylamine, pass into N 2 Protected, heated to 160°C while stirring, and then kept at constant temperature for 30min.

[0042] (2) Take another 5ml of oleylamine in a test tube, add 0.5mmol (C 2 h 5 ) 2 NCSSNa·3H 2 O(SDEDTC), stirred and dissolved at 120°C.

[0043] (3) Inject the solution in (2) into (1) at a rate of 30ml / h through a syringe pump and react at a constant temperature for 1.5h.

[0044] (4) Cool the obtained product to 60°C, centrifuge in a 10ml centrifuge tube, wash twice with cyclohexane, and finally disperse in 10ml chloroform, which is the hydrophobic product.

[0045] (5) Use 2ml of chloroform solution containing 20mg of polyethylene glycol monomethyl etherified-1,2-distearate-3-phosphatidylethanolamine (DSPE-PEG) and 1ml of the hydrophobic product in (4), after stirring for 2h , the obtained product was placed in a rotary evaporator, vacuum-dried and spin-dried at room t...

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Abstract

The invention discloses a reparation method of a copper sulfide nanowire, relating to a copper sulfide nanomaterial. The preparation method comprises the following steps: putting CuCl2.2H2O and oleylamine into a three-necked bottle, and under the protection of N2 atmosphere, heating and maintaining constant temperature, so that CuCl2.2H2O is entirely dissolved in oleylamine to obtain a solution A; dissolving (C2H5)2NCSSNa.3H2O into oleylamine to obtain a solution B; adding the solution B into the solution A for reacting, to obtain a copper sulfide solution with hydrophobic property, then performing centrifugal separation, washing with cyclohexane, then dissolving chloroform to obtain a hydrophobic nano copper sulfide product; mixing and stirring the obtained hydrophobic nano copper sulfide product together with polyethylene glycol monoethylether 1,2-distearoyl-sn-glycero-3-phosphoethanolamine (DSPE-PEG) and chloroform, putting the obtained product into a rotary evaporator, then performing vacuum drying and rotary drying, dispersing into H2O, to obtain the copper sulfide nanowire.

Description

technical field [0001] The invention relates to a copper sulfide nanometer material, in particular to a method for preparing a copper sulfide nanowire by a solvothermal method. Background technique [0002] With the development of nanotechnology in the 21st century, inorganic nanomaterials have attracted more and more people's attention due to their unique properties and wide application prospects, and have become a research hotspot today. As an extremely important P-type semiconductor material, copper sulfide nanomaterials are widely used in catalysis, solar cells, polymer surface conductive layers, optical filters and sensing (J.S.Chung, and H.J.Sohn, Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries[J].J Power Sources,2002,108,226-231; Fei Li,Wentuan Bi,Tao Kong,and Qinghua Qin,Optical,photocatalytic properties of novel CuS nanoplate-based architectures synthesized by a solvothermal route [J]. Cryst Res Technol, 2009, 44, 729-735). R...

Claims

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Application Information

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IPC IPC(8): C01G3/12B82Y30/00B82Y40/00
Inventor 陈小兰黄艺专
Owner XIAMEN UNIV
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