Method for controlling nitrogen content in process of producing aluminium deoxidation high-carbon steel

A control method and technology for high carbon steel, applied in the improvement of process efficiency, furnace type, furnace and other directions, can solve the problems of reducing nitrogen content, limited control, unfavorable uniformity of molten steel temperature, etc., to prevent a large amount of nitrogen absorption , Improve efficiency and improve the effect of slag removal

Active Publication Date: 2014-08-27
ZENITH STEEL GROUP CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Patent 201110440322.4 uses low-nitrogen carburizer to calcined anthracite instead of pitch coke to increase carburization, and realizes the control of nitrogen content brought by the carburizer, but it is limited to this link and the control of nitrogen content is relatively limited, which cannot meet the requirements of Youte Steel. Nitrogen content requirements; patent 201110403472.8 reduces the nitrogen content in steel through the tapping process of the converter and does not blow argon before entering the argon station. Obviously, not blowing argon when tapping is not conducive to the melting of alloy and slag, and is also not conducive to the temperature of molten steel in the ladle The homogenization of nitrogen increases the difficulty of nitrogen control in the subsequent process, and there may also be cold steel at the bottom of the ladle; and patent 201210487536.1 discloses a tapping method that uses two-step addition of alloy deoxidation and does not use aluminum deoxidation to control steel. The amount of nitrogen added to the molten steel. Similarly, this method tends to only consider the nitrogen content control without considering the alloy recovery rate and deoxidation efficiency; -6 , and adding iron oxide balls to the ladle during vacuum treatment can effectively i

Method used

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Examples

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Effect test

Embodiment 1

[0027] A method for controlling nitrogen content in the process of producing aluminum-deoxidized high-carbon steel, using the process route of EAF-CONVERTER electric converter smelting→LF furnace refining→VD vacuum treatment→CCM continuous casting to produce aluminum-deoxidized high-carbon steel, the control method for nitrogen content as follows:

[0028] The charging capacity of the electric converter with a nominal capacity of 90t is 95.3t, including 85.6t of molten iron and 9.7t of steel scrap. The carbon content at the end of tapping is 0.57%, the tapping temperature is 1631°C, and the tapping amount is 85t.

[0029] Before tapping, blow argon at the bottom of the ladle in advance to remove the air in the ladle, so that the ladle is covered with argon, and avoid full contact with molten steel to cause nitrogen increase; during the tapping process, add 20kg of aluminum block and 40kg of low-nitrogen carburizer , a corresponding amount of ferroalloy, 90kg of low-nitrogen r...

Embodiment 2

[0036] A method for controlling nitrogen content in the process of producing aluminum-deoxidized high-carbon steel by an electric converter adopts the process route of EAF-CONVERTER electric converter smelting→LF furnace refining→VD vacuum treatment→CCM continuous casting to produce aluminum-deoxidized high-carbon steel.

[0037] The charging capacity of the electric converter with a nominal capacity of 90t is 102.2t, including 92.5t of molten iron and 9.7t of steel scrap. The carbon content at the end of tapping is 0.55%, the tapping temperature is 1631°C, and the tapping amount is 87t.

[0038] Before tapping, blow argon at the bottom of the ladle in advance to remove the air in the ladle, so that the ladle is covered with argon, and avoid full contact with the molten steel to cause nitrogen increase; during the tapping process, add 20kg of aluminum block and 50kg of low-nitrogen carburizer , a corresponding amount of ferroalloy, 100kg of low-nitrogen recarburizer, 70kg of a...

Embodiment 3

[0045] A method for controlling nitrogen content in the process of producing aluminum-deoxidized high-carbon steel adopts the process route of EAF-CONVERTER electric converter smelting→LF furnace refining→VD vacuum treatment→CCM continuous casting to produce aluminum-deoxidized high-carbon steel.

[0046] The charging capacity of the electric converter with a nominal capacity of 90t is 103.8t, including 93.6t of molten iron and 10.2t of steel scrap. The carbon content at the end of tapping is 0.65%, the tapping temperature is 1632°C, and the tapping amount is 87t.

[0047] Blow argon at the bottom of the ladle in advance before tapping to remove the air in the ladle so that the ladle is covered with argon to avoid nitrogen increase caused by full contact with molten steel; during the tapping process, add 15kg of aluminum block and 30kg of low-nitrogen carburizer , a corresponding amount of ferroalloy, 90kg of low-nitrogen recarburizer, 65kg of aluminum block, and 1.2t of top s...

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Abstract

The invention relates to a method for controlling the nitrogen content in the process of producing aluminium deoxidation high-carbon steel. The outlet steel temperature and the end point carbon content are controlled in the steel outlet process of an electric converter, deoxidizing agents are added in a step-by-step measurement mode in the steel outlet process, the slugging effect is improved, the outlet steel argon blowing pressure is controlled, foaming slag is manufactured in the refining process, the refining electricity conduction time, the outlet sulfur content and the aluminum content are controlled strictly, the vacuum nitrogen removal efficiency is improved, continuous casting protective casting is reinforced, and molten steel is prevented from absorbing massive nitrogen. The method effectively and quantitatively uses the double functions of nitrogen absorption and denitrification of surface-active elements in the molten steel, lays emphasis on nitrogen control in the key links of the whole smelting process, a single nitrogen control operating parameter takes the other links or other process indicators into consideration, and effectively reduces the nitrogen content of aluminium deoxidation high-carbon steel smelted by the electric converter to be below 40*10-6.

Description

technical field [0001] The invention relates to a method for controlling nitrogen content in a smelting process, in particular to a method for controlling nitrogen content in the process of producing aluminum-deoxidized high-carbon steel by an electric converter. Background technique [0002] In most cases, nitrogen is regarded as a harmful element in steel, and even in the case of very small nitrogen content, it has a significant impact on the mechanical properties of steel. The harm of nitrogen is mainly manifested in: free nitrogen in the steel forms a solid solution, causing solid solution strengthening, accompanied by aging, which reduces the toughness and plasticity of the steel; forms brittle inclusions with edges and corners with aluminum, titanium and other elements in the steel, reducing The hot and cold deformation processability of steel; when the residual nitrogen in the steel is high, it will lead to the loose macrostructure of the steel and even the formation ...

Claims

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Application Information

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IPC IPC(8): C21C5/52C21C7/076C21C7/10B22D11/18
CPCY02P10/20
Inventor 高宇波王日红华建民朱富强
Owner ZENITH STEEL GROUP CORP
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