Water-based acrylate adhesive for reflective coatings and preparation method thereof

A technology of water-based acrylate and reflective coatings, which is applied in the direction of reflection/signal coatings, coatings, etc., can solve the problems of no description of the synthesis method of water-based acrylic resin, no technical disclosure of the synthesis method of acrylate adhesive, etc., and achieve long-lasting Effective reflective effect, good bonding fastness, good environmental protection effect

Active Publication Date: 2014-09-03
LIAONING FIXED STAR FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The water-based acrylic resin introduced in this patent is one or more of water-based phenyl acrylic resin, water-based pure acrylic resin, and water-based silicone acrylic resin, and its composition ratio in reflective coatings is ...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Raw material ratio by weight:

[0035] (1) Perfluoroalkyl phosphate amine salt 8, isomeric tridecyl alcohol polyoxyethylene (40) ether 1.5, diacetone acrylate amine 6, ethyl acrylate 155, methyl methacrylate 30, acrylic acid 2.5 , deionized water 120, add in the emulsification kettle, carry out emulsification, form pre-emulsion;

[0036] (2) Take 15% pre-emulsion by weight and mix with vinyl functional silicone oil (BD-32L) 1 and stir evenly, set aside;

[0037] (3) Mix and dissolve ammonium persulfate 1 and deionized water 20 evenly to make an aqueous solution of ammonium persulfate for use;

[0038] (4) Dissolving adipic acid dihydrazide 3 in deionized water 20 to prepare an aqueous solution of adipic acid dihydrazide for use;

[0039] (5) Add deionized water 120 into the reaction kettle, heat up to 75-80°C, at 75-80°C, add one-third of the weight of ammonium persulfate aqueous solution in step 3, and then add dropwise the The pre-emulsion and the remaining ammoniu...

Embodiment 2

[0043] Raw material weight ratio:

[0044] (1) Perfluoroalkyl phosphate amine salt 8.5, isotridecyl alcohol polyoxyethylene (40) ether 1.3, diacetone acrylate amine 6.2, ethyl acrylate 153, methyl methacrylate 32, acrylic acid 2 , deionized water 125, add in the emulsification kettle, carry out emulsification, form pre-emulsion;

[0045] (2) Take the pre-emulsion with a weight ratio of 15% and vinyl-containing functional silicone oil (BD-32L) 1.2, mix and stir evenly, and set aside;

[0046] (3) Mix and dissolve ammonium persulfate 1.1 and deionized water 20 evenly to make an aqueous solution of ammonium persulfate for use;

[0047] (4) Dissolve adipic acid dihydrazide 3.1 in 20°C deionized water to prepare an aqueous solution of adipic acid dihydrazide for use;

[0048] (5) Add deionized water 115 into the reaction kettle, heat up to 75-80°C, at 75-80°C, add the ammonium persulfate aqueous solution which is one-third of the weight of step 3, and then add dropwise the The p...

Embodiment 3

[0052] Raw material weight ratio:

[0053] (1) Perfluoroalkyl phosphate amine salt 9, isomeric tridecyl alcohol polyoxyethylene (40) ether 1.1, diacetone acrylate amine 6.4, ethyl acrylate 150, methyl methacrylate 36, acrylic acid 3 , deionized water 130, add in the emulsification kettle, carry out emulsification, form pre-emulsion;

[0054] (2) Take 15% pre-emulsion by weight and vinyl-containing functional silicone oil (BD-32L) 1.4, mix well, and set aside;

[0055] (3) Mix and dissolve ammonium persulfate 1.2 and deionized water 20 evenly to make an aqueous solution of ammonium persulfate for use;

[0056] (4) Dissolve adipic acid dihydrazide 3.2 in 20°C deionized water to prepare an aqueous solution of adipic acid dihydrazide for use;

[0057] (5) Add deionized water 110 into the reaction kettle, heat up to 75-80°C, at 75-80°C, add one-third of the weight of ammonium persulfate aqueous solution in step 3, and then dropwise add the The pre-emulsion and the remaining ammo...

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PUM

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Abstract

The invention discloses a water-based acrylate adhesive for reflective coatings and a preparation method thereof. The water-based acrylate adhesive comprises the raw materials in parts by weight: 8-10 parts of perfluoroalkyl phosphate amine salt, 0.5-1.5 parts of heterogeneous tridecyl alcohol polyoxyethylene (40) ether, 6-7 parts of diacetone acrylamide, 3-4 parts of adipic dihydrazide, 1-2 parts of vinyl-containing functional silicon oil, 145-155 parts of ethyl acrylate, 30-40 part of methyl methacrylate, 2-4 parts of acrylic acid, 1-1.4 parts of ammonium persulfate and 280 parts of deionized water. An emulsion is obtained through semicontinuous emulsion polymerization; the adhesive and the inorganic material are in high binding firmness, and the adhesive is abrasion-proof, weather-resistant, stain-proof and high in film-forming transparency.

Description

technical field [0001] The invention relates to an adhesive for reflective paint, in particular to a water-based acrylate adhesive for reflective paint and a preparation method thereof. Background technique [0002] The road surface markings of expressways generally have reflective functions, so as to provide safety protection for vehicles driving on these highways at night. This type of sign is made by coating the road surface with reflective paint. Reflective coatings can be divided into two types: water-based and solvent-based. With the enhancement of people's awareness of environmental protection and safety and the implementation of relevant national policies and regulations, the use of solvent-based reflective coatings is becoming less and less, and water-based reflective coatings with environmental protection characteristics are gradually gaining popularity. attention and application. [0003] Water-based reflective coatings are generally composed of reflective mater...

Claims

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Application Information

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IPC IPC(8): C08F299/00C08F220/18C08F220/14C08F220/58C08F2/26C08F2/30C08F8/30C09D133/08C09D5/33
Inventor 王冠中木其尔孙继昌
Owner LIAONING FIXED STAR FINE CHEM
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