Method for recovering ethylene and hydrogen from refinery dry gases through cold oil absorption, pressure swing adsorption (PSA) and membrane separation
A pressure swing adsorption and refinery dry gas technology, which is applied in hydrogen separation, hydrocarbon purification/separation, chemical instruments and methods, etc., can solve the problems of low yield, inability to realize refinery dry gas, and low purity, and achieve High yield, reduced operating cost, and improved purity
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[0037] Example 1:
[0038] like figure 1 As shown, the method for absorbing, PSA, membrane separation and recovering ethylene and hydrogen in a refinery dry gas cooling oil described in this embodiment includes the following steps:
[0039] (1) Compression and boosting: refining the hydrogen content of 18.5%, the ethane content of 14.5%, the ethylene content of 16%, the methane content of 30%, the nitrogen content of 14.5%, the content of components above carbon 2 and 3.5%, and the acid gas content of 3%. After the dry gas (volume ratio) of the plant is compressed in the first stage and the second stage, the pressure is increased to 2.0MPa;
[0040](2) Cold oil absorption: the dry gas from the refinery that has been boosted in step (1) is cooled, and then sent to the absorption tower, the top of the absorption tower discharges non-condensable gas rich in methane, hydrogen and nitrogen, and the bottom of the absorption tower Effluent the absorbed carbon 2 and above components...
Example Embodiment
[0046] Example 2:
[0047] like figure 1 As shown, the method for absorbing, PSA, membrane separation and recovering ethylene and hydrogen in a refinery dry gas cooling oil described in this embodiment includes the following steps:
[0048] (1) Compression and boosting: refining the hydrogen content of 46.5%, the ethane content of 12.4%, the ethylene content of 6.0%, the methane content of 20%, the nitrogen content of 9.5%, the content of components above C2 2.2%, and the content of acid gas 3.2%. After the dry gas (volume ratio) of the plant is compressed in the first stage and the second stage, the pressure is increased to 2.8MPa;
[0049] (2) Cold oil absorption: the dry gas from the refinery that has been boosted in step (1) is cooled, and then sent to the absorption tower, the top of the absorption tower discharges non-condensable gas rich in methane, hydrogen and nitrogen, and the bottom of the absorption tower Effluent the absorbed carbon 2 and above components;
[0...
Example Embodiment
[0055] Example 3:
[0056] like figure 1 As shown, the method for absorbing, PSA, membrane separation and recovering ethylene and hydrogen in a refinery dry gas cooling oil described in this embodiment includes the following steps:
[0057] (1) Compression and boosting: refining the hydrogen content of 18.5%, the ethane content of 14.5%, the ethylene content of 16%, the methane content of 30%, the nitrogen content of 14.5%, the content of components above carbon 2 and 3.5%, and the acid gas content of 3%. After the dry gas (volume ratio) of the plant is compressed in the first stage and the second stage, the pressure is increased to 3.6MPa;
[0058] (2) Cold oil absorption: the dry gas from the refinery that has been boosted in step (1) is cooled, and then sent to the absorption tower, the top of the absorption tower discharges non-condensable gas rich in methane, hydrogen and nitrogen, and the bottom of the absorption tower Effluent the absorbed carbon 2 and above component...
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