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Variable-diameter dielectric barrier reactor for treating volatile organic pollutants

A volatile organic and dielectric barrier technology, applied in the chemical industry, can solve the problems of only low-concentration organic waste gas treatment, inability to mineralize waste gas, secondary pollution, etc., achieve reduction of arc discharge and spark discharge, and improve the phenomenon of coking, The effect of reducing by-products

Active Publication Date: 2016-06-01
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although this technology has been relatively mature in recent years, it is still limited to the treatment of low-concentration organic waste gas.
At the same time, the traditional plasma technology cannot fully mineralize the exhaust gas, so that some tar-like intermediate products are attached to the reactor wall and electrodes, causing corrosion of equipment and secondary pollution

Method used

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  • Variable-diameter dielectric barrier reactor for treating volatile organic pollutants
  • Variable-diameter dielectric barrier reactor for treating volatile organic pollutants
  • Variable-diameter dielectric barrier reactor for treating volatile organic pollutants

Examples

Experimental program
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Effect test

Embodiment 1

[0032] This embodiment relates to a variable-diameter dielectric barrier reactor for treating volatile organic pollutants, the structure of which is as follows figure 1 Shown in (b); described reactor is made of inner and outer discharge spaces (7,8) formed by outer electrode, inner electrode (ground electrode) 3 and inner and outer two-layer medium (4,5), and described outer The electrode is wrapped on the outer dielectric wall and connected to the ground wire; the inner electrode is fixed on the central axis of the reactor and connected to the high-voltage power supply; the polluted gas enters from the outer discharge space, and after preliminary purification, enters the inner The discharge space is thoroughly purified and finally forms CO 2 and H 2 O is discharged from the end of the inner discharge space.

[0033] Among them, 1 is the air inlet, 2 is the air outlet, 3 is the ground electrode, 4 is the inner dielectric, 5 is the outer dielectric, 6 is the high voltage ele...

Embodiment 2

[0043] This embodiment relates to a variable-diameter dielectric barrier reactor for treating volatile organic pollutants, the structure of which is as follows figure 1 as shown in (b);

[0044] This embodiment relates to the treatment of waste gas containing formaldehyde by using the variable-diameter dielectric barrier reactor for the treatment of volatile organic pollutants according to the present invention;

[0045] Air volume 500ml / L, concentration 2000mg / m 3 , relative humidity 40-50%, applied voltage 11.0kV. The implementation steps and conditions are the same as in Example 1. After the discharge is stable for 6 hours, take a sample and analyze it, measure the intake and output concentrations of styrene, the amount of carbon dioxide and carbon monoxide generated, and obtain the conversion rate and mineralization rate. The processing results are compared in the following table 2 express:

[0046] Table 2

[0047]

[0048] From the results in Table 2 above, it can...

Embodiment 3

[0050] This embodiment relates to a variable-diameter dielectric barrier reactor for treating volatile organic pollutants, the structure of which is as follows figure 1 as shown in (b);

[0051] This example involves the use of variable diameter dielectric barrier reactors to treat volatile organic pollutants under different applied voltages

[0052] The treatment object is styrene waste gas with a fixed concentration, the concentration is 2000mg / m 3 , gas volume 500ml / L, relative humidity 40-50%, the total discharge space of the reactor used is 44.2cm 3 .

[0053] Step is the same as embodiment 1, after discharge is stable 6 hours, sampling analysis is carried out, and the intake and output concentration of styrene are measured, the amount of carbon dioxide and carbon monoxide generated, conversion rate and mineralization rate are obtained, and the results are shown in table 3 below:

[0054] table 3

[0055]

[0056] As can be seen from the results in Table 3 above, d...

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Abstract

The invention provides a reducing type dielectric barrier reactor for treating volatile organic pollutants. The reactor is composed of an outer electrode, an inner electrode, and an inner discharge space and an outer discharge space, formed by an inner dielectric layer and an outer dielectric layer, wherein the outer electrode wraps an outer-layer dielectric wall and is connected with a grounding wire, the inner electrode is fixed on the central axis of the reactor and is connected with a high-voltage power supply, pollution gas enters through the outer discharge space, then is purified preliminarily, enters the inner discharge space to be thoroughly purified, and is finally transformed into CO2 and H2O, which are exhausted from the tail end of the inner discharge space. The reducing type dielectric barrier reactor has the advantages that the conversion rate and the mineralization rate are greatly improved compared with the traditional reactor by utilizing the principle that low-energy chemical bonds in pollution gas molecule are destroyed in the outer discharge space and high-energy chemical bonds are weakened, and besides, the reactor has high energy utilization efficiency under the same applied voltage.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a variable-diameter medium barrier reactor for treating volatile organic pollutants. Background technique [0002] In recent years, the emission of volatile organic pollutants (VOCs) has increased year by year. my country clearly stated in the 12th Five-Year Plan that "the prevention and control of volatile organic pollutants is fully carried out", which means that the development of an efficient and rapid method for VOCs control has been imminent. [0003] The traditional methods of treating organic waste gas mainly include absorption method, adsorption method, combustion method, biological method, photocatalytic method and plasma technology. Among them, adsorption method, combustion method and biological method are traditional organic waste gas treatment technologies, and they are also the most widely used VOCs treatment technologies at present, but they still have th...

Claims

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Application Information

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IPC IPC(8): B01D53/32
Inventor 孙同华张宏波孟祥龙
Owner SHANGHAI JIAO TONG UNIV