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A low-odor high-resilience sponge for passenger car seats and preparation method thereof

A high-resilience, low-odor technology, applied in the sponge field, can solve the problems that the odor content and resilience performance cannot meet the environmental performance and mechanical properties of car seat sponges, the foaming volume is large, and the health is damaged. Suitable for large-scale industrial production, stable reaction rate and high foaming efficiency

Inactive Publication Date: 2016-05-04
ZHENGZHOU JINGYIDA AUTO PARTS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are mainly the following types of sponges for car seats: 1) TDI (dimethyl diisocyanate) system seat sponge: this type of seat sponge has low relative density, large foaming volume, and comfortable hand feeling; but its support Insufficient strength, insufficient resilience, highly toxic raw materials, and unbearable odors will be emitted during the production process, which will seriously damage people's health
2) TM (mixture of dimethyl diisocyanate and diphenylmethane diisocyanate) system seat sponge: this kind of sponge feels comfortable, has good resilience, and its foaming volume is inferior to that of TDI system; Poisonous TDI raw materials, the production workshop still smells great
3) MDI (diphenylmethane diisocyanate) system seat sponge: This type of seat sponge has good resilience, high indentation hardness, and low raw material odor, so it has been greatly developed; but the current MDI system automobile The smell, TVOC (total volatile organic compound) content and resilience performance of seat sponge products cannot meet people's requirements for the environmental performance and mechanical properties of car seat sponges

Method used

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  • A low-odor high-resilience sponge for passenger car seats and preparation method thereof
  • A low-odor high-resilience sponge for passenger car seats and preparation method thereof
  • A low-odor high-resilience sponge for passenger car seats and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The low-odor and high-resilience passenger car seat sponge of this embodiment is made of a combination material and a black material in a mass ratio of 100:60, wherein the combination material is composed of the following components by weight: polyether multi-component 50 parts of alcohol, 35 parts of grafted polyether, 0.3 part of amine catalyst, 0.35 part of early gel catalyst, 0.7 part of late gel catalyst, 3 parts of water, 1 part of diethanolamine, 0.5 part of silicone oil.

[0025] The black material is modified diphenylmethane diisocyanate. The modified diphenylmethane diisocyanate is prepared by the following method: the content of 4,4'-diphenylmethane diisocyanate is 40%, and the balance is 2,4'-diphenylmethane diisocyanate and The diphenylmethane diisocyanate of 2,2'-diphenylmethane diisocyanate is mixed and reacted with the first polyether with 90% ethylene oxide content and the second polyether with 25% ethylene oxide content to obtain A modified intermediate ...

Embodiment 2

[0032] The low-odor and high-resilience passenger car seat sponge of this embodiment is made of a combination material and a black material in a mass ratio of 100:55, wherein the combination material is composed of the following parts by weight: polyether multi-component 65 parts of alcohol, 20 parts of grafted polyether, 0.2 parts of amine catalyst, 0.5 parts of early gel catalyst, 0.6 parts of late gel catalyst, 4 parts of water, 1 part of triethanolamine, 0.7 parts of silicone oil.

[0033] The black material is modified diphenylmethane diisocyanate. The modified diphenylmethane diisocyanate is prepared by the following method: the content of 4,4'-diphenylmethane diisocyanate is 60%, and the balance is 2,4'-diphenylmethane diisocyanate and The diphenylmethane diisocyanate of 2,2'-diphenylmethane diisocyanate is mixed and reacted with the first polyether with 70% ethylene oxide content and the second polyether with 25% ethylene oxide content to obtain A modified intermediate w...

Embodiment 3

[0040] The low-odor and high-resilient passenger car seat sponge of this embodiment is made of a combination material and a black material in a mass ratio of 100:58, wherein the combination material is composed of the following components by weight: 80 parts of alcohol, 50 parts of grafted polyether, 0.25 parts of amine catalyst, 0.2 parts of early gel catalyst, 0.5 parts of late gel catalyst, 3.5 parts of water, 0.5 parts of diethanolamine, 0.5 parts of triethanolamine, and 0.6 parts of silicone oil.

[0041] The black material is modified diphenylmethane diisocyanate. The modified diphenylmethane diisocyanate is prepared by the following method: the content of 4,4'-diphenylmethane diisocyanate is 80%, and the balance is 2,4'-diphenylmethane diisocyanate and The diphenylmethane diisocyanate of 2,2'-diphenylmethane diisocyanate is mixed and reacted with the first polyether with 50% ethylene oxide content and the second polyether with 25% ethylene oxide content to obtain A modifi...

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Abstract

The invention discloses a low-smell high-rebound sponge for seats of a passenger car. The sponge is prepared from a composite material and a black material according to a mass ratio of 100: 55-60, wherein the composite material comprises, by weight, 50 to 80 parts of polyether polyol, 20 to 50 parts of grafted polyether, 0.2 to 0.3 part of an amine catalyst, 0.2 to 0.5 part of an early-stage gel catalyst, 0.5 to 0.7 part of a later-stage gel catalyst, 3 to 4 parts of a foaming agent, 1 part of a cross-linking agent and 0.5 to 0.7 part of a stabilizing agent. The invention also discloses a preparation method for the sponge. The low-smell high-rebound sponge for seats of the passenger car employs the black material with low smell and hypotoxicity and the polyether composite material with low smell and hypotoxicity, so the standard smell grade of the sponge is 3.0, TVOC is 13.9 mu g C / g, and the sponge has the characteristics of low smell and high rebound and accords with requirements of people for environmental protection performance and mechanical properties of sponge of automobile seats.

Description

Technical field [0001] The invention belongs to the technical field of sponges, and relates to a sponge for passenger car seats with low odor and high resilience and a preparation method thereof. Background technique [0002] Sponge is a kind of polyurethane foam and belongs to soft polyurethane foam. Because of its porous honeycomb structure, it has excellent softness, elasticity, water absorption and water resistance. It is widely used in sofas, mattresses, clothing, Flexible packaging and other industries. With the development of the automotive industry, sponges for car seats have also received more and more attention. [0003] Car seat sponges are mostly high-resilient sponges, which are cold-cured, molded, and foamed from polyether-type composite materials and isocyanate-based materials. At present, there are mainly the following types of sponges for car seats: 1) TDI (Dimethyl Diisocyanate) system seat sponge: This type of seat sponge has low relative density, large foam vo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/78C08G18/76C08G18/48C08G18/63C08G18/18C08J9/08
CPCC08G18/12C08G18/1833C08G18/4072C08G18/4837C08G18/4883C08G18/632C08G18/7671C08G18/797C08G2110/0008C08G2110/0083C08G18/6688
Inventor 秦开业李桂保魏永超杨广伟狄健楠石文奎黄兴超闫慧张福利李云李龙韩世虎
Owner ZHENGZHOU JINGYIDA AUTO PARTS
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