Application of iturins sodium surfactin as oil displacement agent and oil displacement agent containing iturins sodium surfactin
A technology of sodium subtilisin and oil-displacing agent, which is applied in the field of oil-displacing agent containing sodium subtilisin as oil-displacing agent, can solve the problem that the oil-displacing ultra-low oil-water interfacial tension cannot be achieved , block formation pores, formation structure damage and other problems, to achieve the effect of improving oil recovery, reducing consumption and avoiding damage
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Embodiment 1
[0050] Example 1: Detection of the interfacial tension of different concentrations of subtilisin sodium
[0051] Test instrument: Model510 rotating drop interfacial tension meter (SY / T5370-1999);
[0052] Temperature: 55℃;
[0053] Crude oil: experimental standard crude oil (Ma 95 fault block in Renqiu Oilfield, North China);
[0054] Water: formation water (provided by the oilfield manufacturer, belonging to NaHCO 3 type);
[0055] Oil-displacing agent composition: different concentrations of subtilisin sodium;
[0056] The interfacial tension of different concentrations of subtilisin lipopeptide sodium was calculated, and the results are shown in Table 1.
[0057] Table 1 Interfacial tension
[0058] Concentration of subtilis lipopeptide sodium (ppm)
[0059] The results show that subtilisin lipopeptide sodium can reach 10% in a small concentration range (500ppm) when it is used alone without the addition of alkali and organic solvents and other oil-displacing substances. -3 The oil / w...
Embodiment 2
[0060] Example 2: Thermal stability of subtilis lipopeptide sodium
[0061] Under the conditions of the oil field simulated in the laboratory, add 500ppm of subtilisin sodium, then put it in an oven (105℃) for 60min, then transfer to the refrigerator to instantly drop below 5℃, observe the subtilisin The transparency of sodium in the beaker showed no precipitation. It shows that subtilis lipopeptide sodium has good thermal stability as an oil-displacing agent.
Embodiment 3
[0062] Example 3: The composite oil displacement agent of the present invention
[0063] A composite oil-displacing agent is composed of the following components by weight percentage: subtilisin sodium 5%, sodium dodecylbenzene sulfonate 20%, tetradecyl dimethyl betaine 20%, isopropanol 10% , Water 45%.
[0064] The preparation method is to fully stir the subtilisin sodium, sodium dodecylbenzene sulfonate, and tetradecyl dimethyl betaine under normal temperature and pressure for 45 minutes, and then mix with 50% water of the total water and stir for 30 minutes. Finally, add isopropanol and stir for 45 minutes, add the remaining 50% water, and stir well to get it.
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