A kind of method that prepares activated carbon to co-produce calcium chloride
A technology for preparing activated carbon and calcium chloride, which is applied in the direction of calcium/strontium/barium chloride, calcium/strontium/barium halide, etc., can solve the problems of preparing activated carbon, achieve less environmental pollution, save operating time, and economic benefits high effect
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Embodiment 1
[0028] A method for preparing activated carbon for co-production of calcium chloride, the steps are as follows:
[0029] (1) Raw material pretreatment: naturally dry the crab shells, pulverize them into powder, and pass through a 100-mesh sieve to obtain crab shell powder for subsequent use;
[0030] (2) Acidification treatment of raw materials: 800 mL of hydrochloric acid with a concentration of 4 wt% was added to 100 g of the crab shell powder obtained in step (1), stirred evenly, soaked for 6 hours to obtain a leachate;
[0031] (3) Preparation of calcium chloride: add milk of lime to the leachate obtained in step (2), adjust the pH to 9 of the solution, filter, heat, evaporate and dehydrate the filtrate at 270° C., cool and crystallize to obtain the calcium chloride product; add After milk of lime, iron and magnesium salts are precipitated in the form of hydroxides;
[0032] (4) Preparation of activated carbon: the solid residue obtained in step (2) was cleaned to pH 7 wi...
Embodiment 2
[0037] A method for preparing activated carbon for co-production of calcium chloride, the steps are as follows:
[0038] (1) Raw material pretreatment: dry the shrimp shells naturally, crush them into powder, and pass through a 200-mesh sieve to obtain shrimp shell powder, which is set aside;
[0039] (2) Acidification treatment of raw materials: 400mL of hydrochloric acid with a concentration of 3wt% was added to 100g of the shrimp shell powder obtained in step (1), stirred evenly, soaked for 2.0h to obtain a leachate;
[0040] (3) Preparation of calcium chloride: add milk of lime to the leachate obtained in step (2), adjust the pH to 9 of the solution, filter, heat the filtrate to evaporate and dehydrate at 300°C, cool and crystallize to obtain the calcium chloride product; add After milk of lime, iron and magnesium salts are precipitated in the form of hydroxides;
[0041] (4) Preparation of activated carbon: the solid residue obtained in step (2) was cleaned to pH 7 with ...
Embodiment 3
[0043] A method for preparing activated carbon for co-production of calcium chloride, the steps are as follows:
[0044] (1) Raw material pretreatment: dry the oyster shells naturally, pulverize them into powder, pass through a 40-mesh sieve to obtain oyster shell powder, and set aside;
[0045] (2) Acidification treatment of raw materials: adding 300 mL of hydrochloric acid with a concentration of 5 wt % to 100 g of the oyster shell powder obtained in step (1), stirring evenly, soaking for 4 hours to obtain a leachate;
[0046](3) Preparation of calcium chloride: add milk of lime to the leachate obtained in step (2), adjust the pH to 9 of the solution, filter, heat the filtrate to evaporate and dehydrate at 260° C., cool and crystallize to obtain the calcium chloride product; add After milk of lime, iron and magnesium salts are precipitated in the form of hydroxides;
[0047] (4) Preparation of activated carbon: wash the solid residue obtained in step (2) to pH 7 with deioni...
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