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Thermoplastic styrene-butadiene rubber used in medical treatment field and preparation method of thermoplastic styrene-butadiene rubber

A styrene-butadiene rubber and thermoplastic technology, which is applied in the field of thermoplastic styrene-butadiene rubber and its preparation, can solve the problems of high energy consumption and high product cost, and achieve the effect of little loss of mechanical properties, no need for vulcanization, and good flexibility

Inactive Publication Date: 2015-01-28
NINGBO JENIUS PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the research and development of SBC in my country has made important progress, two sets of 10,000-ton SBS production equipment have been built using the complete set of technology developed by ourselves, and successfully realized the supply to Enichem Elastom Company of Italy and Taiwan Synthetic Rubber Co., Ltd. Complete set of technology transfer, but at present, compared with foreign advanced technology, there is still a certain gap between my country's SBS and its series of products (including SIS, SEBS, SPES and other varieties) complete set of technology in terms of material consumption, energy consumption and variety grades, resulting in product costs. high energy consumption

Method used

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  • Thermoplastic styrene-butadiene rubber used in medical treatment field and preparation method of thermoplastic styrene-butadiene rubber
  • Thermoplastic styrene-butadiene rubber used in medical treatment field and preparation method of thermoplastic styrene-butadiene rubber
  • Thermoplastic styrene-butadiene rubber used in medical treatment field and preparation method of thermoplastic styrene-butadiene rubber

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Experimental program
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Effect test

Embodiment

[0025] (1) First, according to the formula ratio, using naphthenic oil 4006 as the solvent, n-butyllithium as the initiator, tetrahydrofuran (THF) as the polarity regulator, using a three-step feeding synthesis process, first adding styrene monomer The polymerization reaction temperature and polymerization time are 50°C-70°C for one period, and the reaction time is 15-30 minutes; then add butadiene monomer and polymerize in the second stage, the temperature is less than 95°C, and the time is 40-45 minutes; after adding styrene monomer, carry out the third stage Polymerization, temperature 70°C-80°C, reaction time 15-30 minutes; obtain styrene-butadiene-styrene block copolymer; (three-stage styrene monomer in the above steps: butadiene monomer: styrene The molar ratio of the monomers is 1:13:1)

[0026] (2) Take by weighing the p-styrene-butadiene-styrene block copolymer prepared by the formula ratio step (1), and the metallocene catalyst of the formula ratio---titanocene dichl...

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Abstract

The invention discloses thermoplastic styrene-butadiene rubber used in the medical treatment field. The rubber is prepared from the following components in percentage by weight: 10-40 percent of styrene-butadiene-styrene segmented copolymer, 20-50 percent of naphthenic oil 4006, 0.5-10 percent of n-butyllithium, 1-6 percent of tetrahydrofuran, 0.1-3 percent of titanocene dichloride, 0.1-5 percent of antioxygen, 0.2-3 percent of UL327 and 0.1-0.5 percent of vinyl bistearic amide, the sum of the weight percentage of all components being 100 percent. The thermoplastic styrene-butadiene rubber has the advantages of high temperature tolerance, weather resistance and ultraviolet (UV) resistance, and is free of toxicity, good in flexibility, low in compression deformation and high in sealing performance; 120-DEG C steam sterilization and X-ray irradiation can be borne; the food and drug administration standard of elastic characteristics of styrene type thermoplastic elastomer is met so that the rubber conforms to the food and drug administration (FDA) and can be used for making medical rubber products such as injectors and transfusion instruments.

Description

technical field [0001] The invention relates to the technical field of hydrogenation of styrene-butadiene rubber, in particular to a thermoplastic styrene-butadiene rubber used in the medical field and a preparation method thereof. Background technique [0002] Thermoplastic styrene-butadiene rubber (TPE) has the characteristics of both plastic and rubber, and is known as "the third generation of synthetic plastics". Styrenic thermoplastic elastomer (SBC) occupies an important position in TPE, and is currently the world's largest and fastest-growing thermoplastic elastomer. Compared with other thermoplastic elastomers, SBC has the characteristics of softness, small permanent deformation, and rubber elasticity. It is suitable for adhesives and sealing materials for hot-melt processing, and is used in shoemaking, liquid sealing materials, wires, cables, automotive parts, There are a wide range of applications in areas such as medical device components, household appliances, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L53/02C08K5/00C08K5/134C08K5/526C08K5/20C08F297/00C08F8/04
Inventor 李喜莲张海城
Owner NINGBO JENIUS PLASTIC
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