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Method for extracting potassium by reaction of potassium feldspar in pipeline

A pipeline reactor and potassium feldspar technology, which is applied in the field of potassium feldspar extraction of potassium fertilizer, can solve the problems such as the inability to efficiently extract potassium in potassium feldspar, and achieve the effects of simple operation, low energy consumption, and low equipment investment.

Inactive Publication Date: 2015-11-18
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the technical problem that the prior art cannot efficiently extract the potassium element in potassium feldspar, and provide a method for extracting potassium from potassium feldspar by reacting in the pipeline, so as to overcome the deficiencies in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The raw material potassium feldspar contains potassium oxide 8.0wt%, and the particle size is 100 mesh; the concentration of sulfuric acid is: 98wt%; the concentration of fluorine in the fluoric acid is: 10wt%; the total amount of potassium feldspar is 1, and the potassium feldspar The stone and fluorine-containing acid are mixed in the mixing tank according to the weight ratio of 1.0:2.0, and stirred evenly; the potassium feldspar and sulfuric acid are mixed in the mixing tank according to the weight ratio of 0.0:1.0, and stirred evenly; the two streams of slurry are pumped into the The reaction is carried out in the pipeline reaction, and the reaction time of the reaction slurry in the pipeline reactor is 1 hour (the reaction time is controlled by controlling the flow rate of the slurry in the pipeline and the length of the reaction pipeline); the temperature of the slurry reaction in the pipeline reactor The range is 120°C, the reaction temperature is obtained by the ...

Embodiment 2

[0024] The raw material potassium feldspar contains potassium oxide 12.0wt%, the particle size is 200 mesh, the concentration of sulfuric acid is 60wt%, and the fluorine element concentration in the fluoric acid is 8wt%; the total amount of potassium feldspar is 1, and the potassium feldspar and the Fluoric acid is mixed in the mixing tank according to the weight ratio of 0.9:1.2, and stirred evenly; the potassium feldspar and sulfuric acid are mixed in the mixing tank according to the weight ratio of 0.1:1.0, and stirred evenly; the two slurries are pumped into the pipeline reaction To react, the reaction time of the reaction slurry in the pipeline reactor is 1 hour, which is controlled by controlling the flow rate of the slurry in the pipeline and the length of the reaction pipeline; the temperature range of the slurry reaction in the pipeline reactor is 80 ° C, The reaction temperature is obtained by directly feeding steam and sulfuric acid dilution heat into the pipe reacto...

Embodiment 3

[0026] The raw material potassium feldspar contains potassium oxide 10.0wt%, particle size is 250 mesh, sulfuric acid concentration is: 70wt%, fluorine element concentration is 20wt% in the fluoric acid; the total amount of potassium feldspar is 1, potassium feldspar and Fluorine-containing acid is mixed in the mixing tank according to the weight ratio of 1.0:4.0, and stirred evenly; the potassium feldspar and sulfuric acid are mixed in the mixing tank according to 0.0:0.5, and stirred evenly; the two raw materials are pumped into the pipeline reaction for reaction , the reaction time of the reaction slurry in the pipeline reactor is 3 hours, which is controlled by controlling the flow velocity of the slurry in the pipeline and the length of the reaction pipeline; the temperature range of the slurry reaction in the pipeline reactor is 30 ° C, and the reaction temperature It is obtained by dilution heat of sulfuric acid in the pipeline reactor; the flow velocity of the reaction ...

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Abstract

The invention relates to a method for reacting potassium feldspar in a pipeline to extract potassium. The method specifically comprises steps of conveying potassium feldspar powder, fluorine-bearing acid and sulfuric acid to a pipeline, and mixing and reacting therein under certain temperature, residence time and pressure until reaction is complete; removing water and fluorine of reacted slurry in a water and fluorine removal reactor to obtain reaction residue, which is a mixture of potassium sulfate, aluminum sulfate and silicon dioxide, and conducting such steps as leaching to obtain potassium salt, aluminum salt and like products. According to the method disclosed by the invention, a potassium extracting rate in the potassium feldspar can reach above 95%. The method disclosed by the invention is low in energy consumption, simple in process, low in investment, applicable to continuous production and easy in industrialization.

Description

technical field [0001] The invention belongs to the technical field of extracting potassium fertilizer from potassium feldspar, and relates to a method for extracting potassium by reacting potassium feldspar in a pipeline. Background technique [0002] Domestic soluble potassium resources are scarce, and insoluble potassium resources represented by potassium feldspar are spread all over the country. my country is a large agricultural country, and the use of potassium feldspar to extract potassium is of strategic importance to solve China's agricultural potassium fertilizer, and even the world's demand for potassium fertilizer. For a long time, there have been many studies on the extraction of potassium from potassium feldspar to produce potassium fertilizer. The main technical routes include high-temperature melting method, sintering method, blast furnace smelting method, hydrothermal method and low-temperature decomposition method. The production of potash fertilizers by ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01D5/02C01F7/74C01B33/12
Inventor 旷戈尚亚伟陈光炉孙加兴金冉胡松
Owner FUZHOU UNIV