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Permanent antistatic flame-retardant modified PC composite material

A composite material and antistatic technology, applied in the field of flame retardant modified PC composite materials, can solve the problems of spark generation, trouble in industrial production and daily life, fire or explosion, etc., achieving low cost, simple preparation process and excellent comprehensive performance. Effect

Inactive Publication Date: 2015-03-18
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since PC is easy to generate static electricity accumulation during production and use, it will cause electrostatic dust collection, electrostatic discharge and other adverse phenomena. The index is about 21% to 24%, and it can self-extinguish when it is away from the fire. The commercialized PCs on the market are evaluated according to the American UL94 standard for flame retardancy, and basically meet the requirements of V-2 grades, but it is difficult to meet the requirements of certain application fields. Therefore, it is necessary to carry out antistatic and flame retardant modification of PC to broaden its application range and meet market demand.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A permanent antistatic flame-retardant modified PC composite material, the composition of which is: PC resin 82%, polyethylene oxide (PEO) 2%, bisphenol A-bis(diphenyl phosphate) ester) (BDP) 10%, anti-dripping agent 0.5%, maleic anhydride grafted ABS (ABS-g-MAH) 4%, hindered phenolic antioxidant 1010 and phosphite antioxidant 168 by mass 1 : 2-ratio compound 0.3%, PETS 1.2%. Wherein, the PC resin is bisphenol A aromatic polycarbonate with a weight average molecular weight of 20,000-40,000 g / mol; the anti-dripping agent is polystyrene-acrylonitrile copolymer (AS)-coated Tetrafluoroethylene (PTFE) powder, PTFE content is 60% to 80%.

[0020] Preparation method: (1) Dry the PC resin in a blast dryer at 110°C-130°C for 3-4 hours, dry the flame retardant at 80°C-85°C for 30-45 minutes, and set aside; ( 2) Weigh the dry PC resin and other components according to the weight ratio, add them into the high-speed mixer respectively, stir for 5-30 minutes, and discharge the mate...

Embodiment 2

[0022] A permanent antistatic flame-retardant modified PC composite material, the composition of which is: 80% PC resin, 3% polyether ester amide (PEEA), bisphenol A-bis (diphenyl phosphate ) (BDP) 12%, anti-dripping agent 0.5%, maleic anhydride grafted polyethylene (PE-g-MAH) 3.5%, hindered phenolic antioxidant 1010 and phosphite antioxidant 168 by mass 1 : 2-ratio compound 0.3%, TAS-2A 0.7%. Wherein, the PC resin is bisphenol A aromatic polycarbonate with a weight average molecular weight of 20,000-40,000 g / mol; the anti-dripping agent is polystyrene-acrylonitrile copolymer (AS)-coated Tetrafluoroethylene (PTFE) powder, PTFE content is 60% to 80%.

[0023] Preparation method: (1) Dry the PC resin in a blast dryer at 110°C-130°C for 3-4 hours, dry the flame retardant at 80°C-85°C for 30-45 minutes, and set aside; ( 2) Weigh the dry PC resin and other components according to the weight ratio, add them into the high-speed mixer respectively, stir for 5-30 minutes, and dischar...

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PUM

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Abstract

The invention discloses a permanent antistatic flame-retardant modified PC composite material which comprises the following components by mass percent: 70-90% of PC resin, 1-3% of antistatic agent, 10-15% of fire retardant, 0.1-1% of anti-drip agent, 2-6% of compatilizer, 0.1-0.5% of complex antioxidant and 0.1-2% of lubricant. Compared with the prior art, the prepared permanent antistatic flame-retardant modified PC composite material has favorable flame retardant property and permanent antistatic property, the flame retardant level can be up to V-0 level, the comprehensive properties such as tensile strength and notch impact strength are excellent and the PC is ensured to be safely applied under the environmental conditions with high requirements for flame retardant property and antistatic property; and the permanent antistatic flame-retardant modified PC composite material is simple in preparation process, low in cost and preferably suitable for industrial production.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a permanent antistatic flame-retardant modified PC composite material. Background technique [0002] Polycarbonate (PC) is an engineering plastic with excellent comprehensive properties. Its impact resistance ranks first among thermoplastics. It has good dimensional stability and high heat distortion temperature (130°C~140°C). All excellent. It has been widely used in industries such as automobiles, electronics, home appliances, and construction. Since PC is easy to generate static electricity accumulation during production and use, it will cause electrostatic dust collection, electrostatic discharge and other adverse phenomena. The index is about 21% to 24%, and it can self-extinguish when it is away from the fire. The commercialized PCs on the market are evaluated according to the American UL94 standard for flame retardancy, and basically meet the requirements of V-...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08K5/523B29B9/06B29C47/92B29C48/92
CPCC08L69/00B29B9/06B29C48/92B29C2948/92704C08L2201/02C08L2201/04C08L2205/035C08L71/02C08L51/00C08L27/18C08K5/00C08K5/523C08L77/12C08L51/06
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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