Preparation method of zinc selenide nanometer photocatalyst and application of zinc selenide nanometer photocatalyst

A nano-photocatalyst, zinc selenide technology, applied in the direction of physical/chemical process catalysts, chemical instruments and methods, chemical/physical processes, etc., can solve problems such as difficult to recycle, limit wide application, narrow absorption range, etc., and achieve environmental pollution The effect of small size, low energy consumption and simple operation

Inactive Publication Date: 2015-03-25
JILIN NORMAL UNIV
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Problems solved by technology

However, at the same time, problems such as narrow spectral absorption range of nano-zinc oxide, difficulty in recycling, and difficulty in repeated reuse limit its wide application.
[0006] Although semiconductor photocatalytic technology has made some remarkable progress in its development for decades, it has not yet reached industrialization, industrialization, and commercial application.
Although a large number of researchers are committed to the field of photocatalysis, the research on the application of ZnSe semiconductor materials in the field of photocatalysis is not perfect.

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  • Preparation method of zinc selenide nanometer photocatalyst and application of zinc selenide nanometer photocatalyst

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[0020] 1. Preparation of ZnSe nano photocatalyst

[0021] The following materials are proportioned by mass Zn(NO 3 ) 2 ·6H 2 O: deionized water: sodium hydroxide: triethanolamine is equal to 7.437: 100: 32: 225, weigh Zn (NO 3 ) 2 ·6H 2 O 1.4875 grams, 20 milliliters of deionized water, 6.4 grams of sodium hydroxide, 40 milliliters of triethanolamine, Zn(NO 3 ) 2 ·6H 2 O mixed with deionized water, then stirred to make it a colorless transparent solution, then added sodium hydroxide, continued to stir, it was still a colorless transparent solution, then added triethanolamine, stirred magnetically for 1 hour to obtain a mixed solution, and then with Zn(NO 3 ) 2 ·6H 2 The mol ratio of O is that 0.3948 gram of selenium powder of 1:1 joins in the mixed solution, then the above-mentioned mixed solution that adds selenium powder is transferred in the autoclave with polytetrafluoroethylene liner, the filling degree of autoclave 75%-80%, seal the autoclave and place it in a...

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Abstract

The invention discloses a preparation method of a zinc selenide nanometer photocatalyst and application of zinc selenide nanometer photocatalyst. A solvothermal method is adopted for preparing the ZnSe nanometer photocatalyst in a high pressure reactor, and the ZnSe nanometer photocatalyst is obtained through the control of the volume ratio of solvent to deionized water and the filling degree of the high pressure reactor, and then Rhodamin B solution containing the ZnSe nanometer photocatalyst is irradiated by an ultraviolet lamp to be subjected to photocatalytic degradation. The method has the advantages that the operation is simple, the energy consumption is low and the environment pollution is low; besides, the used raw materials and the solvent for preparation are low in cost and have low toxicity, and large-scale production can be realized in the preparation process; the photocatalysis technology is a novel environment-friendly technology, semiconductor photocatalysis has attractive application prospect in the aspects of degradation of organic dyestuffs, wastewater treatment and the like, and great social and economic benefits can be generated.

Description

technical field [0001] The invention relates to a preparation method of a zinc selenide nanometer photocatalyst, and also relates to the application of the zinc selenide nanometer photocatalyst for photocatalytic degradation of rhodamine B solution. Background technique [0002] In recent years, the pollution caused by human production and life has far exceeded the self-degradation ability of nature, so it has become an urgent problem to find ways to degrade pollutants with high efficiency and low energy consumption. Photocatalytic treatment technology is a new technology with easy operation, low energy consumption, no secondary pollution and broad application prospects. However, its practical application is still limited by the low photocatalytic efficiency. Therefore, finding high-efficiency photocatalysts has become an important research topic. [0003] ZnSe is an important direct band gap II-VI semiconductor light-emitting material, with a band gap of 2.67 eV and an exc...

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/057C02F1/32
CPCY02W10/37
Inventor 韩东来曹健冯博杨景海
Owner JILIN NORMAL UNIV
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