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Liquefied gas organic sulfur conversion catalyst

A catalyst and organic sulfur technology, which is applied in chemical instruments and methods, gas mixture processing, hydrocarbon oil treatment, etc., can solve the problems of odor of alkali residue, air pollution, hidden danger of unsafe operation, etc., and achieve simple production technology, no The effect of secondary pollution and elimination of potential safety hazards

Active Publication Date: 2017-05-10
CHONGQING DIZHIJING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But this technology has following problems: 1) can produce a large amount of alkali slag, and alkali slag has serious stench smell, can cause environmental problem; Harmful substances exceed the standard); 3) It takes a lot of manpower and material resources to deal with alkali slag, and there is secondary pollution. Discharging sulfur into the atmosphere in the form of oxides will cause air pollution; 4) There are hidden dangers in operation, When mixing lye, caustic soda and lye are easy to hurt people, and when unloading lye residue, it is easy to cause leakage of liquefied petroleum gas

Method used

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  • Liquefied gas organic sulfur conversion catalyst
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  • Liquefied gas organic sulfur conversion catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Example 1: Preparation of organic sulfur conversion catalyst for liquefied petroleum gas

[0040] Liquefied petroleum gas organic sulfur conversion catalyst, composed of the following components in weight percentage: Ni: 10-20%, Na 2 O: 5~10%, the balance is γ-Al 2 O 3 Carrier; the Ni comes from nickel nitrate, Na 2 O is derived from sodium hydroxide.

[0041] The preparation method of the above-mentioned liquefied gas organic sulfur conversion catalyst operates according to the following steps:

[0042] 1) Preparation of dipping solution: preparing nickel solution: dissolving nickel nitrate to prepare dipping solution A; preparing sodium solution: preparing dipping solution B with sodium hydroxide.

[0043] 2) Impregnation: the dried γ-Al 2 O 3 The carrier is immersed in immersion solution A for 2-6 hours, then drained and dried; the dried carrier is placed in immersion solution B for immersion for 2-6 hours, drained and dried.

[0044] 3) Activation: the carrier obtained by dry...

Embodiment 2

[0045] Example 2: Preparation of liquefied gas organic sulfur conversion catalyst

[0046] Liquefied petroleum gas organic sulfur conversion catalyst, composed of the following components in weight percentage: Ni: 10-20%, Na 2 O: 5~10%, the balance is γ-Al 2 O 3 Carrier; the Ni comes from nickel nitrate, Na 2 O is derived from sodium carbonate.

[0047] The preparation method of the above-mentioned liquefied gas organic sulfur conversion catalyst operates according to the following steps:

[0048] 1) Preparation of dipping solution: preparing nickel solution: dissolving nickel nitrate to prepare dipping solution A; preparing sodium solution: preparing dipping solution B with sodium carbonate.

[0049] 2) Impregnation: the dried γ-Al 2 O 3 The carrier is immersed in immersion solution A for 2-6 hours, then drained and dried; the dried carrier is placed in immersion solution B for immersion for 2-6 hours, drained and dried.

[0050] 3) Activation: the carrier obtained by drying in step 2 ...

Embodiment 3

[0051] Example 3: Preparation of liquefied gas organic sulfur conversion catalyst

[0052] Liquefied petroleum gas organic sulfur conversion catalyst, composed of the following components in weight percentage: Ni: 10-20%, Na 2 O: 5~10%, the balance is γ-Al 2 O 3 Carrier; the Ni is derived from nickel sulfate, Na 2 O is derived from sodium carbonate.

[0053] The preparation method of the above-mentioned liquefied gas organic sulfur conversion catalyst operates according to the following steps:

[0054] 1) Preparation of dipping solution: preparing nickel solution: dissolving nickel sulfate to prepare dipping solution A; preparing sodium solution: preparing dipping solution B with sodium carbonate.

[0055] 2) Impregnation: the dried γ-Al 2 O 3 The carrier is immersed in immersion solution A for 2-6 hours, then drained and dried; the dried carrier is placed in immersion solution B for immersion for 2-6 hours, drained and dried. 3) Activation: the carrier obtained by drying in step 2 is...

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Abstract

The invention relates to an organic sulfur conversion catalyst for liquefied gas and belongs to the technical field of liquefied gas refining. The organic sulfur conversion catalyst for liquefied gas disclosed by the invention comprises the following components in percentage by weight: 10-20 percent of Ni, 5-10 percent of Na2O and the balance of a carrier, wherein the carrier refers to gamma-Al2O3. According to the catalyst disclosed by the invention, the organic sulfur conversion rate in the liquefied gas is high, namely the thiol conversion rate is more than or equal to 95 percent, the carbonyl sulfide conversion rate is more than or equal to 98 percent, and the carbon disulfide conversion rate is more than or equal to 90 percent.

Description

Technical field [0001] The invention relates to the technical field of liquefied gas refining in the petroleum processing process, and particularly relates to a catalyst for converting organic sulfur contained in the liquefied gas. Background technique [0002] Liquefied petroleum gas is one of the products in the petroleum processing process, and it is also an important raw material for further processing into other products. The refined raw material liquefied petroleum gas is mainly liquefied petroleum gas after hydrogen sulfide removal by alcohol amine method. The main components of liquefied petroleum gas from the alcohol amine method desulfurization unit are C3 and C4 components, containing a small amount of hydrogen sulfide and organic sulfur (mainly mercaptans). , Carbonyl sulfide, carbon disulfide). [0003] At present, the liquefied gas mercaptan conversion catalysts on the market mainly include sulfonated cobalt phthalocyanine and or polyphthalocyanine cobalt catalysts, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/78B01D53/86B01D53/48C10G70/00
Inventor 王喜平顾法明黄代红张远征曾荣丽刘江
Owner CHONGQING DIZHIJING TECH
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