High-performance composite cable jacket material for cables

A composite cable and sheath material technology, applied in the direction of insulated cables, cables, circuits, etc., can solve the problems that the excellent properties cannot be fully exerted, the mechanical and mechanical properties of the polymer are reduced, and the outer layer of the cable is aging and dry, and the rubber is weakened. Aging process, improvement of physical and mechanical properties, effect of improving physical and mechanical properties

Inactive Publication Date: 2015-05-13
ANHUI HONGYI CABLE GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the rapid development of China's cable industry, the number of new companies is increasing, and the overall technical level of the industry has been greatly improved. In the line, the proportion of cables is gradually increasing. The outermost layer of cables is generally rubber or rubber synthetic sleeves. This The role of the insulation layer is to protect the cable from damage. However, during laying or operation, the sheath layer of the cable can be damaged or mechanically damaged, and the long-term overload operation will easily cause the sheath layer of the cable to age and dry out. , so that the sheath layer loses or reduces the protective performance
The performance of the rubber material of the sheath layer is directly related to the fillers added. Because kaolin is rich in raw materials, simple in processing technology, and low in cost, it is one of the commonly used inorganic mineral fillers in the rubber sheath layer. Kaolin is based on kaolinite and The clay ore with halloysite as the main mineral component has a dioctahedral structure consisting of 1:1 silicon-oxygen tetrahedron and aluminum-oxygen octahedron, which share oxygen atoms, but The particles are fine, the surface area is large, the surface is hydrophilic, the surface has high activity, and it is easy to agglomerate. At the same time, due to the different interface properties between kaolin and polymer, the compatibility is poor, and it is difficult to disperse evenly when filling the polymer itself. Separation reduces the mechanical and mechanical properties of the polymer to a certain extent, so that the excellent properties of this fine kaolin cannot be fully utilized. How to prepare a high-performance composite cable sheath material for cables with aging resistance, good mechanical properties, and low cost Become a current technical problem that needs to be solved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A high-performance composite cable sheath material for cables proposed by the present invention, its raw materials include by weight: 35 parts of EPDM rubber, 50 parts of EVA resin, 30 parts of modified nano-kaolin, and 2 parts of dibenzothiazole disulfide 1.5 parts of zinc oxide, 3 parts of zinc dimethyl dithiocarbamate, 1 part of antioxidant ODA, 55 parts of high wear-resistant carbon black, 25 parts of calcined clay, 30 parts of nano calcium carbonate, dioctyl phthalate 1 part of ester, 3 parts of stearic acid, 0.5 part of chlorinated paraffin, 4 parts of solid calcium zinc stabilizer, 1 part of anti-aging agent RD;

[0017] In the preparation process of modified nano-kaolin, 40 parts of nano-kaolin will be taken in parts by weight, and sodium hydroxide solution is added thereto so that the pH value of the material obtained is 8.2, and the weight-to-volume ratio of sodium hydroxide solution and nano-kaolin (g : ml) is 1:25, stir evenly, ultrasonically disperse for 15...

Embodiment 2

[0019] A high-performance composite cable sheath material for cables proposed by the present invention, its raw materials include by weight: 45 parts of EPDM rubber, 30 parts of EVA resin, 45 parts of modified nano-kaolin, 1 dibenzothiazole disulfide 2.5 parts of zinc oxide, 1 part of zinc dimethyl dithiocarbamate, 2 parts of antioxidant ODA, 45 parts of high wear-resistant carbon black, 35 parts of calcined clay, 20 parts of nano calcium carbonate, dioctyl phthalate 1.8 parts of ester, 1 part of stearic acid, 1.5 parts of chlorinated paraffin, 2 parts of solid calcium zinc stabilizer, 2.5 parts of anti-aging agent RD,

[0020]In the preparation process of modified nano-kaolin, 30 parts of nano-kaolin will be taken by weight, and sodium hydroxide solution is added thereto so that the pH value of the material obtained is 9.5, and the weight-to-volume ratio of sodium hydroxide solution and nano-kaolin (g : ml) is 1:22, stir evenly, ultrasonically disperse for 25 minutes to obtai...

Embodiment 3

[0022] A kind of high-performance composite cable sheath material for cables proposed by the present invention, its raw materials include by weight:

[0023] 41 parts of EPDM rubber, 36 parts of EVA resin, 41 parts of modified nano-kaolin, 1.5 parts of dibenzothiazole disulfide, 1.9 parts of zinc oxide, 1.6 parts of zinc dimethyl dithiocarbamate, 1.7 parts of anti-aging agent ODA 46 parts of high wear-resistant carbon black, 31 parts of calcined clay, 23 parts of nano calcium carbonate, 1.3 parts of dioctyl phthalate, 1.8 parts of stearic acid, 0.95 parts of chlorinated paraffin, 2.6 parts of solid calcium zinc stabilizer , anti-aging agent RD1.8 parts;

[0024] In the preparation process of modified nano-kaolin, 35 parts of nano-kaolin will be taken by weight, and sodium hydroxide solution is added thereto so that the pH value of the material obtained is 9, and the weight-to-volume ratio of sodium hydroxide solution and nano-kaolin (g : ml) was 1:24, stirred evenly, ultrason...

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Abstract

The invention discloses a high-performance composite cable jacket material for cables. The high-performance composite cable jacket material is prepared from the following raw materials in parts by weight: 35-45 parts of ethylene propylene terpolymer, 30-50 parts of EVA resin, 30-45 parts of modified nanokaolin, 1-2 parts of dibenzothiazyl disulfide, 1.5-2.5 parts of zinc oxide, 1-3 parts of zinc dimethyldithiocarbamate, 1-2 parts of anti-aging agent ODA, 45-55 parts of high abrasion furnace black, 25-35 parts of calcined clay, 20-30 parts of nano calcium carbonate, 1-1.8 parts of dioctyl phthalate, 1-3 parts of stearic acid, 0.5-1.5 parts of chlorinated paraffin, 2-4 parts of solid calcium-zinc stabilizer and 1-2.5 parts of anti-aging agent RD. The high-performance composite cable jacket material for cables disclosed by the invention has good ageing resistance, good mechanical properties and low cost.

Description

technical field [0001] The invention relates to the technical field of cable sheaths, in particular to a high-performance composite cable sheath material for cables. Background technique [0002] With the rapid development of China's cable industry, the number of new companies is increasing, and the overall technical level of the industry has been greatly improved. In the line, the proportion of cables is gradually increasing. The outermost layer of cables is generally rubber or rubber synthetic sleeves. This The role of the insulation layer is to protect the cable from damage. However, during laying or operation, the sheath layer of the cable can be damaged or mechanically damaged, and the long-term overload operation will easily cause the sheath layer of the cable to age and dry out. , so that the sheath layer loses or reduces the protective performance. The performance of the rubber material of the sheath layer is directly related to the fillers added. Because kaolin is ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08L23/08C08K13/06C08K9/06C08K9/04C08K3/34C08K3/04C08K5/47C08K3/22C08K5/39C08K5/09H01B7/17
CPCC08L23/0853C08L23/16C08L2203/202C08L2205/02C08L2205/03H01B7/17C08L91/06C08K13/06C08K9/06C08K9/04C08K3/346C08K3/04C08K5/47C08K2003/2296C08K5/39C08K5/09
Inventor 陶成富吴本长
Owner ANHUI HONGYI CABLE GROUP
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