Conductive polymer-supporter composite material, preparation method and applications
A conductive polymer and composite material technology, applied in the field of conductive polymer materials, can solve the problems affecting the efficiency of adsorption and reduction of metal ions, adhesion, etc., and achieve the effect of enrichment and reduction without energy consumption, increasing the specific surface area, and avoiding agglomeration
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Embodiment 1
[0047] In this embodiment, the conductive polymer-support composite material is composed of polyaniline and support material, polyaniline uses the support material as a carrier, and is dispersed on the surface of the support material, and the support material is sackcloth, forming polyaniline- Support composites.
[0048] The preparation method of this polyaniline-support body composite material is as follows:
[0049] (1) Dissolve 4.56g of ammonium persulfate in 80ml of 1M dilute hydrochloric acid solution, and refrigerate in an ice-water bath at 0°C for later use;
[0050] (2) Disperse 1ml of aniline monomer in 320ml of dilute hydrochloric acid solution with a concentration of 1M in an ice-water bath at 0°C and stir vigorously;
[0051] (3) Slowly add the dilute ammonium persulfate hydrochloric acid solution prepared in step (1) dropwise into the dilute aniline-hydrochloric acid solution obtained in step (2), stir at 0°C for one hour, then continue to stir and react for 24 ...
Embodiment 2
[0068] In this embodiment, the conductive polymer-support composite material is composed of polyaniline and support material. The polyaniline uses the support material as a carrier and is dispersed on the surface of the support material. The support material is cotton yarn, forming the polyaniline-support material. body composites.
[0069] The preparation method of the polyaniline-support composite material is basically the same as that in Example 1, except that cotton yarn is used instead of sackcloth as the support.
[0070] The polyaniline-support composite material obtained above can adsorb metal ions (such as gold, silver, platinum, palladium, mercury, copper, tin, hexavalent chromium, etc.) that can undergo electrochemical reduction reactions in acidic solutions, and will It is reduced to metal adsorption on the surface. Therefore, the polyaniline-support composite material can be used to recover these metal elements contained in waste. In order to verify this use, th...
Embodiment 3
[0074] In this embodiment, the conductive polymer-support composite material is composed of polyaniline and support material, polyaniline uses the support material as a carrier, and is dispersed on the surface of the support material, and the support material is sawdust, forming the polyaniline-support material. body composites.
[0075] The preparation method of the polyaniline-support composite material is basically the same as that in Example 1, except that sawdust is used instead of sackcloth as the support.
[0076] The polyaniline-support composite material obtained above can adsorb metal ions (such as gold, silver, platinum, palladium, mercury, copper, tin, hexavalent chromium, etc.) that can undergo electrochemical reduction reactions in acidic solutions, and will It is reduced to metal adsorption on the surface. Therefore, the polyaniline-support composite material can be used to recover these metal elements contained in waste. In order to verify this use, the follo...
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