A kind of multifunctional anion polymer compound additive and its preparation process

A technology of composite additives and negative ions, applied in building components, building insulation materials, buildings, etc., can solve the problems of not very considerable physical modification, no polymer chains, etc.

Active Publication Date: 2017-04-05
SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Styrene and divinylbenzene are widely used monomers for making microcapsules, and they are highly controllable, but they do not have polymer chains that can form a cross-linked phase with the outside world, so physical modification is not very impressive

Method used

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  • A kind of multifunctional anion polymer compound additive and its preparation process
  • A kind of multifunctional anion polymer compound additive and its preparation process
  • A kind of multifunctional anion polymer compound additive and its preparation process

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preparation example Construction

[0038] A kind of preparation method of multifunctional negative ion macromolecule compound additive is characterized in that comprising following processing steps:

[0039] a) Add the initiator and polar solvent in the above parts by weight to the organic solution of 1,3-butadiene under the condition of nitrogen flow, and react at a temperature of 20-70° C. for 60-300 minutes;

[0040] B) adding the nano-anion additive of above-mentioned parts by weight and stirring;

[0041] c) heating up to 50-100°C, adding the above-mentioned parts by weight of styrene and divinylbenzene, and reacting for 100-300 minutes;

[0042] D) adding the chain terminator reaction of above-mentioned parts by weight;

[0043] e) cooling to normal temperature, and pumping to constant weight in a vacuum oven;

[0044] F) adding the nano-anion additive and ethylene dichloride of the above-mentioned parts by weight to the product and stirring;

[0045] g) adding carbon tetrachloride and anhydrous alumin...

Embodiment 1

[0057] The following experiments were all carried out under the condition of nitrogen protection. A certain mass of polar solvent and n-butyllithium were added to 200ml of cyclohexane solvent and stirred evenly. The temperature was raised to 50°C, and 60.021g of 1,3- Butadiene, reacted for 180 minutes, added 50.276g of nano-anion additives with a particle size of 5nm-100nm, stirred evenly, raised the temperature to 70°C, added 10.191g of styrene and 15.121g of divinylbenzene, reacted for 180 minutes, added 1.095 g of ethanol, reacted for 60 minutes, cooled to normal temperature, put the product in a vacuum oven, baked at 90°C for 12 hours to constant weight to obtain 131.731 g of product, dissolved the product in a certain quality of dichloroethane, and added 60.984 Add a certain amount of carbon tetrachloride and anhydrous aluminum trichloride, and react at 30°C for 13 hours, then use acetone, dilute hydrochloric acid and water to dissolve It is washed, the product is put in ...

Embodiment 2

[0064] Use a grinder to grind the additive into 350-500 mesh particles, 500 grams of No. 90 bitumen from Sinopec as the base bitumen, add 12.5 grams of petroleum fractions with an aromatic content of 90.27% into the base bitumen, and stir at 160 degrees Celsius For 30 minutes, heat the base asphalt to 190 degrees Celsius, add 30 grams of additive particles, and shear at a high speed of 4500 rpm for 25 minutes by a high-speed shearer, then add 4.5 grams of sulfur powder, and then shear at a speed of 4500 rpm for 30 minutes , to obtain the final modified asphalt.

[0065] Use the national standard GB / T 4509-2010 method to test its penetration, use the national standard GB / T 4508-2010 method to test its ductility, use the national standard GB / T 4507-1999 method to test its softening point (ring and ball method), the test results are as follows :

[0066]

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Abstract

The invention discloses a multifunctional anionic polymer composite additive and a preparation technology thereof, and relates to the field of additives. The additive is prepared from the following raw materials in parts by weight: 1-100 parts of a 1,3-butadiene-styrene-divinyl benzene (B-sty / DVB) terpolymer and 0-50 parts of a nano anion additive. The multifunctional anionic polymer composite additive has the beneficial effects that (1) the polymer product contains a polybutadiene polymer block chain, so that the polymer product can form an interface phase together with partial organic interface; (2) the polymer product contains the polybutadiene polymer block chain, so that the chain length can be regulated by adding a monomer and an initiator; (3) a capsule formed by the product wraps partial anion additive in the product, so that the partial anion additive is not easily separated in the modification process; (4) the mixture wraps the anion additive, so that all characteristics of the anion are included; and (5) the mixture is polymer and inorganic nonmetal blend, so that the mixture has physical characteristics of the polymer and the inorganic nonmetal.

Description

technical field [0001] The invention relates to the field of additives, in particular to a multifunctional anion polymer composite additive which is a mixed product of a terpolymer and anion and a preparation process thereof. Background technique [0002] Negative ion additives have important applications in asphalt, ceramics, rubber and other materials. Negative ions have an inactivation effect on microorganisms, bacteria, and viruses, and can achieve the purification effect of air or material surfaces. General anion additives are physically blended in colloids and asphalt, and a single anion additive exists in the blend, which has no obvious change in the physical properties of the original. [0003] Microcapsule technology has been used in many fields: 1) used in sachets to slowly emit fragrance; 2) used in textiles for antibacterial and deodorizing; 3) used in special paints to improve fire resistance. [0004] Microcapsules can be obtained by emulsion polymerization, s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L53/02C08F293/00C08F212/08C08F212/36C08F2/38C08L95/00
Inventor 刘昭洋王进春何俊淅叶子刘江涛董树强康静
Owner SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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