High-flowability high-glossiness no-surface-defect colored metallic-pearl-effect spraying-free polypropylene automobile material and preparation method thereof

A color metal and pearlescent effect technology, applied in the field of polymer materials, can solve the problems of affecting uniform plasticization, limited application range, lack of high flow and colored pearlescent effect, etc., and achieve the effect of improving gloss

Inactive Publication Date: 2015-06-10
蔡勤勤
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent only invented a polypropylene composition with paint luster and metallic texture, which does not have high flow and colorful pearl effect, and will be severely limited in practical application.
[0005] The disadvantage of this patented formula is that no compatibilizer, lubricating dispersant, or antioxidant is used in its formula system
This patent only invented a spray-free PP material, but in solving the problems of product weld lines and flow marks, it needs to cooperate with high-gloss mirror molds and higher mold temperature molding conditions, which have strict restrictions on molds and molding conditions. In practical applications will be severely restricted
[0007] The disadvantage of this patented formula is that it does not use high melt flow rate PP and compatibilizer in its formula system, and the melt flow rate in its formula system is 9-11g/10min, belonging to the range of low melt flow rate, will affect the uniform plasticization among the components, which will have a great impact on high gloss and appearance; not using compatibilizers will affect the effect pigments in the formula system Compatibility with polypropylene, which will have a greater impact on the metal or pearlescent effect. In summary, the surface gloss, metallic or pearlescent effect and appearance of the PP material are far behind the

Method used

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  • High-flowability high-glossiness no-surface-defect colored metallic-pearl-effect spraying-free polypropylene automobile material and preparation method thereof
  • High-flowability high-glossiness no-surface-defect colored metallic-pearl-effect spraying-free polypropylene automobile material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The high-flow, high-gloss, non-surface-defect colored metallic pearlescent effect spray-free polypropylene automobile material of the present embodiment is composed of the following materials by weight percentage:

[0046] Polypropylene is high melt flow rate polypropylene, and the melt flow rate of polypropylene is 60g / 10min, 71.8%;

[0047] Toughening agent is ethylene-octene copolymer, 3%;

[0048] The mineral masterbatch is talc masterbatch, 5%;

[0049] The compatibilizer is maleic anhydride grafted polypropylene, 5%;

[0050] Antioxidants are 1010, 0.2%, 168, 0.2%;

[0051] Light stabilizer is 944, 0.6%;

[0052] The lubricant is polyethylene wax, 1.2%;

[0053] Surface modifier, 6%;

[0054] Color metal pigment masterbatch is color zinc powder pigment masterbatch, 3%;

[0055] The pearlescent masterbatch is a mica-coated pearlescent pigment masterbatch, 4%.

[0056] The specific preparation method includes the fo...

Embodiment 2

[0060] The high-flow, high-gloss, non-surface-defect colored metallic pearlescent effect spray-free polypropylene automobile material of the present embodiment is composed of the following materials by weight percentage:

[0061] Polypropylene is high melt flow rate polypropylene, and the melt flow rate of polypropylene is 70g / 10min, 63.9%;

[0062] Toughening agent is ethylene-octene copolymer, 4%;

[0063] The mineral masterbatch is calcium carbonate masterbatch, 10%;

[0064] The compatibilizer is maleic anhydride grafted polyethylene, 6%;

[0065] Antioxidants are 1010, 0.3%, 168, 0.2%;

[0066] Light stabilizers are 944, 0.2%, 770, 0.4%;

[0067] The lubricant is polyethylene wax, 0.4%, calcium stearate, 0.6%;

[0068] Surface modifier, 7%;

[0069] The color metal pigment masterbatch is a commercially available silver powder pigment masterbatch, 4%;

[0070] Pearlescent masterbatch is silica-coated pearlescent pigment maste...

Embodiment 3

[0073] The high-flow, high-gloss, non-surface-defect colored metallic pearlescent effect spray-free polypropylene automobile material of the present embodiment is composed of the following materials by weight percentage:

[0074] Polypropylene is high melt flow rate polypropylene, and the melt flow rate of polypropylene is 120g / 10min, 55.7%;

[0075] Toughening agent is ethylene-propylene copolymer, 2%;

[0076] The mineral masterbatch is talc masterbatch, 15%;

[0077] The compatibilizer is maleic anhydride grafted polypropylene, 8%;

[0078] Antioxidants are 1010, 0.2%, 168, 0.3%;

[0079] Light stabilizers are 944, 0.4%, 770, 0.2%;

[0080] The lubricant is polyethylene wax, 0.4%, calcium stearate, 0.4%, ethylene bis-stearate amide, 0.4%;

[0081] Surface modifier, 8%;

[0082] Color metal pigment masterbatch is color zinc powder pigment masterbatch, 4%;

[0083] Pearlescent masterbatch is mica coated pearlescent pigment mast...

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Abstract

The invention discloses a high-flowability high-glossiness no-surface-defect colored metallic-pearl-effect spraying-free polypropylene automobile material and a preparation method thereof. The material is composed of the following components in percentage by weight: 40.8-74.4% of polypropylene, 2-4% of toughener, 5-20% of mineral master batch, 5-10% of compatilizer, 0.4-0.6% of antioxidant, 0.4-0.6% of light stabilizer, 0.8-2% of lubricant, 6-10% of surface modifier, 3-6% of colored metallic pigment master batch and 3-6% of pearl color master batch. By using the high-melt-flow-rate polypropylene resin, compatilizer, surface modifier, mineral master batch, colored metallic pigment master batch and pearl color master batch, all the components can be uniformly dispersed, so that the material has the advantages of favorable glossiness, favorable pearl effect, favorable metallic sensation and no surface defect, and the appearance effect is infinitely approximate to the painting effect. The material can solve the problem of surface flow mark, tiger skin or fusion wire in the thin-wall complex-structure large-size product without especially customizing the ultrahigh-glossiness mirror surface mold or harsh injection molding technique, and can implement direct color-bearing injection molding of the part.

Description

technical field [0001] The invention belongs to the field of macromolecular materials, and relates to a high-fluidity, high-gloss, non-surface-defect colored metal pearlescent effect spray-free polypropylene automotive material and a preparation method thereof. Background technique [0002] In recent years, the automobile industry has developed rapidly, especially the output and social ownership of cars have maintained a relatively high growth rate. Plastics for automobiles play an irreplaceable role in satisfying aesthetics, safety, and lightweight. At the same time, new technologies for automobiles are also It is developing towards a more environmentally friendly, safer, more comfortable and personalized direction. Among the varieties of plastics used in automobiles, modified polypropylene materials have become the most used variety in plastic materials used in automobiles, and are also the focus of the development and application of plastics used in automobiles. Polypr...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/08C08L23/16C08L51/06C08K13/06C08K9/10C08K3/26C08K3/34C08K5/098C08K5/20C08K3/08C08K3/36C08J3/22
CPCC08L23/12C08J3/226C08J2323/12C08J2423/12C08K2201/003C08K2201/014C08L2205/025C08L2205/035C08L2205/08
Inventor 蔡勤勤
Owner 蔡勤勤
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